• Title/Summary/Keyword: combustion flue gases

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Simultaneous Removal Characteristics of NOx, SOx from Combustion Gases using Plasma Chemical Reaction (플라즈마 화학반응에 의한 연소가스 중 NOx. SOx 동시제거 특성)

  • 박재윤;고용술;이재동;손성도;박상현;고희석
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.406-409
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    • 1999
  • Experimental Investigations were carried out to remove NOx, SOx simultaneously from simulated flue gas[NO(0.02%)-SO$_2$(0.08%)-$CO_2$-Air-$N_2$] by using a plasma chemical reaction. Ammonia gas(14.81%) balanced by argon was diluted by all and was Introduced to mall simulated flue gas duct through NH$_3$ Injection system which is in downstream of reactor. The NH$_3$ molecular ratio(MR) was determined based on (NH3) to [NO+S0$_2$]. MR is 1, 1.5, 2.5. The NOx removal rate significantly increased with increasing NaOH bubble quantity. The SO$_2$ removal rate was not significantly effected by applied voltage, however it fairly Increased with increasing NH$_3$ molecule ratio. By-product aerosol particle was observed by XRD(X-ray diffraction) after sampling, The NOx, SOx removal rates, when H2O vapour bubbled by dry all was injected to plasma reactor, were better than those of other cases. When aqueous NaOH solution(20%) bubbled by 2.5( ι /min) of $N_2$ and 0.5 ( ι /min) NH$_3$(MR=1.5) were injected to simulated flue gas, The NOx. SOx removal rate was 95 ~ 100[%]

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Study on the Separation of CO2 from Flue Gas Using Polysulfone Hollow Fiber Membrane (폴리설폰 중공사막을 이용한 연소 배기가스 중 이산화탄소 분리에 관한 연구)

  • Kim, Seongcheon;Chun, Jeonghyeon;Chun, Youngnam
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.2
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    • pp.147-152
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    • 2014
  • In this research, polysulfone hollow fiber membrane was used to recover $CO_2$ which is one of greenhouse gases from flue gas stream being emitted after the combustion of fossil fuels. The prerequisite requirement is to design the membrane process producing high-purity $CO_2$ from flue gas. For separation of $CO_2$, a membrane module and flue gas containing 10% carbon dioxide was used. The effects of operating conditions such as pressure, temperature, feed gas composition and multi-stage membrane on separation performance were examined at various stage cuts. Higher operating pressure and temperature increased carbon dioxide concentration and recovery ratio in permeate. Recovery ratio and separation efficiency increased if a higher content of $CO_2$ injection gas composition. Three-stage membrane system was producing a 95% $CO_2$ with 90% recovery from flue gas. The separation efficiency of three-stage membrane system was higher than one-stage system.

Combined De-NOx Process with $NH_3$ SCR and Non-thermal Plasma Process for Removing NOx and Soot from Diesel Exhaust Gases

  • Chung, Kyung-Yul;Song, Young-Hoon;Oh, Sang-Hoon
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.5
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    • pp.657-665
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    • 2003
  • Combined De-NOx Process in which $NH_3$ SCR (Selective Catalytic Reduction) and non-thermal Plasma Process are simultaneously used, has been investigated with a pilot test facility. The pilot test facility treats the combustion flue gases exhausted from a diesel engine that generates 240 kW of electrical power. Test results show that up to 80 % of NOx (NO and NO2) can be removed at 100 - $200^{\circ}C$. None of conventional De-NOx techniques works under such low temperature range. In addition to NOx. the Pilot test results show that soot can be simultaneously treated with the present non-thermal plasma technique. The present pilot test shows that the electrical power consumption to operate the non-thermal plasma reactor is equivalent to 3 - 4 % of the electrical power generated by the diesel engine.

Simultaneous Removal of SOx and NOx in Flue Gas of Oxy-fuel Combustion by Direct Contact Condenser (직접접촉식 응축기를 통한 가압순산소 연소 배가스 내 SOx, NOx 동시저감 연구)

  • Choi, Solbi;Mock, Chinsung;Yang, Won;Ryu, Changkook;Choi, Seuk-Cheon
    • Clean Technology
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    • v.25 no.3
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    • pp.245-255
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    • 2019
  • Pressurized oxy-fuel combustion is a promising technology for $CO_2$ capture with a benefit of improving power plant efficiency compared with atmospheric oxy-fuel combustion. Prior to $CO_2$ compression in this process, a flue gas condenser (FGC) is used to remove $H_2O$ while recovering the latent heat. At the same time, the FGC has a potential for high-efficiency removal of $SO_x$ and $NO_x$ by exploiting their good solubility in water. In this study, experiments were carried out in a lab-scale, direct contact FGC under different pressures varying between 1 and 20 bar to evaluate the removal efficiency of $SO_2$ and $NO_x$ for individual gases and their mixture. In the tests for individual gases, 20% and 76% of $NO_x$ was removed at 1 bar and 10 bar, respectively. Even higher removal efficiencies were achieved for $SO_2$, and also these were maintained for longer as the pressure increased. In the tests for $SO_2$ and $NO_x$ mixture, the removal efficiency of $NO_x$ increased from 13% at 1 bar to 56% at 20 bar because of higher solubility at elevated pressures. $SO_2$ in the mixture was initially dissolved almost completely and then increased by 1,219 ppm at 1 bar and by 165 ppm at 20 bar. Overall, the removal efficiency of $SO_2$ and $NO_x$ was increased at elevated pressures, but it was lower in the mixture compared with individual gases at identical conditions because of a lower pH and associated chemical reactions in water.

The Characteristics of Sour Gas Decomposition by Microwave (Microwave에 의한 산성가스 분해 특성)

  • Kim, Dong-Sik;Kim, Jae-Surl;Lee, Dong-Kyu
    • Applied Chemistry for Engineering
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    • v.7 no.6
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    • pp.1027-1033
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    • 1996
  • Under the Irradiation of the radiofrequency wave, the dipole materials vibrate as microwavic phase change. This causes friction between adjacent molecules and enables an unique charateristics of interior heating of the materials. When dipole gases are adsorbed inside of a solid radiofrequency wave absorber, the gases can be decomposed easily by the microwave energy. The decomposition of sour gases was successfully tested in this manner to develop a sour gas removal process from the combustion flue gas. The standard gas bearing NO and $SO_2$ was passed through and microwave was applied on the calcined char bed as the wave absorber and the gas adsorbent. It was found that more then 95% of NO and 70 % of $SO_2$ was decomposed to the environmentally clean elements during the passage through the 20 gram char bed under the microwave impingement. The surface area and the porosity of char increased because the oxygen radicals produced from decomposed gas attacked carbon in the char capillaries and formed $CO_2$. For a lower concentration of sour gas, general cases in the commercial combustion processes, almost complete decomposion is believed possible and this method is surely expected to be useful for the prevention of air pollutions.

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Research Investigations at the Municipal (2×35) and Clinical (2×5 MW) Waste Incinerators in Sheffield, UK

  • Swithenbank, J.;Nasserzadeh, V.;Ewan, B.C.R.;Delay, I.;Lawrence, D.;Jones, B.
    • Clean Technology
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    • v.2 no.2
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    • pp.100-125
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    • 1996
  • After recycle of spent materials has been optimised, there remains a proportion of waste which must be dealt with in the most environmentally friendly manner available. For materials such as municipal waste, clinical waste, toxic waste and special wastes such as tyres, incineration is often the most appropriate technology. The study of incineration must take a process system approach covering the following aspects: ${\bullet}$ Collection and blending of waste, ${\bullet}$ The two stage combustion process, ${\bullet}$ Quenching, scrubbing and polishing of the flue gases, ${\bullet}$ Dispersion of the flue gases and disposal of any solid or liquid effluent. The design of furnaces for the burning of a bed of material is being hampered by lack of an accurate mathematical model of the process and some semi-empirical correlations have to be used at present. The prediction of the incinerator gas phase flow is in a more advanced stage of development using computational fluid dynamics (CFD) analysis, although further validation data is still required. Unfortunately, it is not possible to scale down many aspects of waste incineration and tests on full scale incinerators are essencial. Thanks to a close relationship between SUWIC and Sheffield Heat&Power Ltd., an extended research programme has been carried out ar the Bernard Road Incinerator plant in Sheffield. This plant consists of two Municipal(35 MW) and two Clinical (5MW) Waste Incinerators which provide district heating for a large part of city. The heat is distributed as hot water to commercial, domestic ( >5000 dwelling) and industrial buildings through 30km of 14" pipes plus a smaller pipe distribution system. To improve the economics, a 6 MW generator is now being added to the system.

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The Figures for the Alstom Power Pressurized Fluidized Bed Combustion Combined Cycle System (Alstom Power의 가압유동층 복합발전 시스템 특성)

  • 이윤경;주용진;김종진
    • Journal of Energy Engineering
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    • v.12 no.1
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    • pp.1-10
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    • 2003
  • Pressurized fluidized bed combustion unit is operated at pressures of 1~1.5 MPa with combustion temperatures of 850~87$0^{\circ}C$. The pressurized coal combustion system heats steam, in conventional heat transfer tubing, and produces a hot gas supplied to a gas turbine. Gas cleaning is a vital aspect of the system, as is the ability of the turbine to cope with some residual solids. The need to pressurize the feed coal, limestone and combustion air, and to depressurize the flue gases and the ash removal system introduces some significant operating complications. The proportion of power coming from the steam : gas turbines is approximately 80:20%. Pressurized fluidized bed combustion and generation by the combined cycle route involves unique control considerations, as the combustor and gas turbine have to be properly matched through the whole operating range. The gas turbines are rather special, in that the maximum gas temperature available from the FBC is limited by ash fusion characteristics. As no ash softening should take place, the maximum gas temperature is around 90$0^{\circ}C$. As a result a high pressure ratio gas turbine with compression intercooling is used. This is to offset the effects of the relatively low temperature at the turbine inlet.

Research on Desulfurization and Dust Removal Characteristics in Oxy-PC Combustion system (순산소 석탄연소 시스템에서의 탈황·집진 기초 특성)

  • Min, Tai Jin;Keel, Sang In;Yun, Jin Han;Roh, Seon Ah;Han, Bang Woo;Lee, Hyung Keun;Kim, Sang Soo;Lee, Kang Soo;Seo, Sang Il;Kim, Young Ju
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.116-120
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    • 2010
  • $CO_2$ is regarded as one of the greenhouse gases(GHG), which is the main reason of climate change. In order to achieve lower $CO_2$ emissions, several efforts have been conducted worldwide. $CO_2$ capture & storage(CCS) technology development is needed for a coal-fired combustion power plant because of huge $CO_2$emission. Oxy fuel combustion, one of the CCS technologies has been considered as a primary concern, nowadays. Oxy-fuel combustion needs flue gas recirculation(FGR) for stable operation and enrichment of $CO_2$ concentration in the flue gas. FGR adoption for oxy-fuel combustion requires development of effective desulfurization and dust removal technology. In this study, desulfurization characteristics of lime and dust removal technology have been researched in the laboratory scale coal combustor.

Development of a 20 kW pulse modulator for industrial application of pulse corona process (배가스 펄스코로나 처리공정 실험설비용 20 kW급 자기펄스압축형(MPC) 펄스 모듈레이터 개발)

  • Son, Y.G.;Jang, S.D.;Oh, J.S.;Cho, M.H.;Kim, M.H.;Han, B.W.
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1781-1783
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    • 2004
  • Flue gas from fossil fuel combustion is the main source of air pollution. It is recognized that $SO_2$ and $NO_x$, (sum of NO and $NO_2$) react with $H_2O$ and $O_2$ in atmosphere and convert precursors of acid rain. Streamer corona process using pulse power is one of the effective methods to remove these gases from stack. For this, pulse generator with 160 kV of output peak voltage, 0.3 ${\mu}s$ of pulse width and 120Hz of pulse repetition rate is developed. This paper shows the pulse compression characteristics to obtain optimum parameters for basic system design.

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Performance Analysis of Supercritical Coal Fired Power Plant Using gCCS Simulator

  • Tumsa, Tefera Zelalem;Mun, Tae-Young;Lee, Uendo;Yang, Won
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.37-40
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    • 2014
  • Capturing the carbon dioxide emitted from coal-fired power plants will be necessary if targeted reduction in carbon emissions is to be achieved. Modelling and simulation are the base for optimal operation and control in thermal power plant and also play an important role in energy savings. This study aims to analyze the performance of supercritical coal fired power plant through steady and dynamic simulation using a commercial software gCCS. A whole power plant has been modeled and validated with design data of 500 MWe power plant, base and part load operations of the plant were also evaluated, consequently it had been proven that the simulated result had a good agreement with actual operating data. In addition, the effect of co-firng on the plant efficiency and flue gases were investigated using gCCS simulator.

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