• Journal of Pharmaceutical Investigation
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• v.4 no.4
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• pp.38-45
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• 1974

Sulfur had been used for the medical fields as fungacidal bacteriocides and gelatolytic agent from ancient B. C 700, their prepartiones contained the sulfur are restrict to freely medication, the restrutive reasones are the it's preparation stabilized sparing solubility, and limit to pharmaceutical development of colloidal sulfur-self. Anthors prepared white lotion, registered on U.S.P XIII from the colloidal sulfur, by the method midified buku zawa make the stabilized lotion by the various fatty alkyl sulfates, and the result obtained are as follows the suspending agents for stabilize to the colloidal sulfur are the fatty alcohol sulfates than natural clay on the imbibition appeareuce and usefulnss. The adequate quantities of stearic acid in lotion base are $1.5{\sim}2.0$ percent for refluidity and pourability. The carbon numbers in alkyl radical used fatty alcohol sulfates as anionic surfactants are maxture of $12{\sim}18$ about efficiency, as possible as, the electrolyte is removed from the white lotion.

• Journal of Ceramic Processing Research
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• v.13 no.spc1
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• pp.78-81
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• 2012

Colloidal titania nanoparticles were synthesized by a simple sol-gel process. The obtained nanoparticles showed high crystallinity and were of the anatase type. These crystalline colloidal titania nanoparticles were organically modified using methyl- and glycidyl-grafted silanes in order to enhance their stability and solution processability. The stabilized colloidal titania nanoparticles could be dispersed homogeneously without aggregation and converted into silica-titania hybrid films with the heterogeneous Si-O-Ti bonds by a low-temperature solution process. The fabricated silica-titania hybrid films showed high transparency (~ 90%) in the visible range, and low RMS roughness (<1 nm). Therefore, the organosilane-modified crystalline colloidal titania nanoparticles can be used in solution-processable functional coatings for electro-optical devices.

• Journal of Applied Reliability
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• v.14 no.1
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• pp.11-19
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• 2014

A colloidal silica slurry has been manufactured by mixing nano silica powders having different grain size to improve the reliability of Sapphire wafer CMP process. The main reliability problem of CMP process such as the breaking of wafer can be prevented by reducing the size of particles in a slurry. While existing commercial colloidal silica slurries are usually made of single grain size silica powder of about 120nm, in the present study 40nm and 100nm silica powders are mixed to achieve a similar removal rate. The new colloidal silica slurry showed wafer removal rate of $3.04{\mu}m/120min$ while that of a commercial colloidal silica slurry was $3.03{\mu}m/120min$. The roughness was less than $4{\AA}$ and scratch was 0. It is also expected that the reduction of the size of nano silica particles can improve the dispersion stability and prolong the useful life of the slurry.

• Bulletin of the Korean Chemical Society
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• v.31 no.7
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• pp.1891-1896
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• 2010

Submicron-sized polymeric colloidal particles can self assemble into 3-dimensional (3D) opal structure which is a useful template for photonic crystal. Narrowly dispersed polymer microspheres can be synthesized by emulsion polymerization in water using water-soluble radical initiator. In this report, we demonstrate a facile and reproducible emulsion polymerization method to prepare various polymeric microspheres within 200 - 400 nm size ranges which can be utilized as colloidal photonic crystal template. By controlling the amount of monomer and surfactant, monodisperse polymer colloids of polystyrene (PS) and acrylates with various sizes were successfully prepared without complicated synthetic procedures. Such polymer colloids self-assembled into 3D opal structure exhibiting bright colors by reflection of visible light. The colloidal particles and the resulting opal structures were rigorously characterized, and the wavelength of the structural color from the colloidal crystal was confirmed to have quantitative relationship with the size of constituting colloidal particles as predicted by Bragg equation. The tunability of the structural color was achieved not only by varying the particle size but also by infiltration of the colloidal crystal with liquids having different refractive indices.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.06a
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• pp.422-422
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• 2009

Photocurable inorganic-organic hybrid materials were prepared from colloidal-silica nanoparticles synthesized through the solgel process and using acryl resin. The synthesized colloidal-silica nanoparticles had uniform diameters of around 20 nm, and they were organically modified, using methyl and methacryl functional silanes, for efficient hybridization with acryl resin. The organically modified and stabilized colloidal-silica nanoparticles could be homogeneously hybridized with aeryl resin without phase separation. The successfully fabricated hybrid materials exhibit efficient photocurability and simple film formation due to the photopolymerization of the organically modified colloidal-silica nanoparticles and acryl resin upon UV exposure. The fabricated hybrid films exhibit an excellent optical transmission of above 90% in the visible region as well as an enhanced surface smoothness of around 1 nm RMS roughness. In addition, the hybrid films exhibit improved thermal and mechanical characteristics, much better than those of acryl resin. More importantly, these photocurable hybrid materials fabricated through the synergistic combination of colloidal-silica nanoparticles with acryl resin are candidates for optical and electrical applications.

• Korean Chemical Engineering Research
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• v.55 no.6
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• pp.754-761
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• 2017

UV-curable hydrophilic coating solutions were prepared by mixing colloidal silica dispersed in alcohol with an acrylic monomer, pentaerythritol triacrylate (PETA). Hydrophilic coating films were also prepared by spin coating the hydrophilic coating solutions on PC substrates and UV curing for 10 minutes subsequently. The effect of the amount of colloidal silica in the coating solutions, which was varied from 10 g to 50 g, was investigated on the hydrophilic properties of UV-cured coating films. The results showed that the amount of colloidal silica had a great influence on the hydrophilic properties of UV-cured coating films and the coating film prepared with 30 g of colloidal silica showed a lowest contact angle of $37^{\circ}$ and an excellent pencil hardness of H.

• Bulletin of the Korean Chemical Society
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• v.30 no.1
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• pp.129-132
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• 2009

Monodisperse ZnS colloidal particles with precisely specified diameters over a broad size range were synthesized by controlled aggregation. Sub-10nm ZnS seed crystals were first nucleated at ambient temperature and then grown at an elevated temperature, which produced large polydisperse colloidal particles. Subsequent rapid thermal quenching and heating processes induced a number of secondary nucleations in addition to growing the large polydisperse microparticles which were finally removed by centrifugation and discarded at the completion of the reaction. The secondary nuclei were then aggregated further at elevated temperatures, resulting in colloidal particles which exhibited a nearly monodisperse size distribution. Particle diameters were controlled over a wide size range from 50 nm to 1 μm. Mie simulations of the experiment extinction spectra determined that the volume fraction of the ZnS is 0.66 in an aggregated colloidal particle and the colloidal particle effective refractive index is approximately 2.0 at 590 nm in water. The surface of the colloidal particles was subsequently coated with silica to produce ZnS@silica core-shell particles.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.07a
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• pp.35-37
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• 2005

100, 200nm 크기의 colloidal silica 각각에 나노 ceria 입자를 수열합성법으로 코팅하였다. Colloidal silica 입자에 ceria를 코팅 시 slurry의 pH조절과 수열처리에 이용하여 silica에 ceria가 코팅됨을 TEM과 zeta-potential을 이용하여 확인하였다. 연마 슬러리의 분산 안정성과 연마효율을 높이기 위하여 슬러리의 pH 는 9로 하였으며, 이때의 zeta-potential 값은 -25 mV이었다. 1 wt%로 제조된 연마슬러리를 이용하여, 4 inch $SiO_2$, $Si_3N_4$ wafer를 압력변화에 따른 연마특성을 관찰 하였다. Ceria coated colloidal silica 100 nm, 200 nm와 commercial한 $CeO_2$입자를 연마압력 6 psi로 oxide film을 연마한 결과 연마율이 각각 2490 ${\AA}/min$, 4200 ${\AA}/min$, 4300 ${\AA}/min$으로 측정되었다. 또한 $SiO_2$, $Si_3N_4$ film의 6 psi압력에서 ceria coated colloidal silica 100 nm, 200 nm와 commercial 한 $CeO_2$입자의 선택비는 3, 3.8, 6.7 이었다. 입자크기가 클수록 연마율이 높으며, Preston equation을 따라 연마 압력과 연마율이 비례하였다.

• Journal of the Korean Ceramic Society
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• v.39 no.10
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• pp.981-987
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• 2002

Monodispersed colloidal silica was prepared by Stober process. We have synthesized monodispersed colloidal silica of carious sizes (100 nm, 200 nm, 300 nm) by controlling volume ratios of TEOS(Tetraethylorthosilicate), $NH_4OH$, Ethanol and D. I. water. Shape and monodispersity of the synthesized colloidal particles were observed by Scanning Electron Microscopy(SEM) and laser light scattering particle analyzer. Self-assembled monolayer of monodispersed colloids was achieved by dipping Si substrate into a well-dispersed silica suspension. It was determined that uniformity and spatial extent of the self-assemble monolayer of monodispersed colloids are significantly influenced by the experimental parameters such as concentration, pH and surface tension of the colloidal suspension. We have observed a hexagonally well-ordered packing colloidal monolayer in a relatively large area (1.5 mm ${\times}$ 1.5 mm) as confirmed by SEM.

• Membrane Journal
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• v.21 no.1
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• pp.84-90
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• 2011

We studied the effects of induction of natural convection instability flow (NCIF) according to the gravitational orientation (inclined angle) of the membrane cell on the reduction of membrane fouling in ultrafiltration (UF) of colloidal silica solutions. Five colloidal silica solutions with different silica size (average size = 7, 12, 22, 50 and 78 nm) were used as UF test solutions. The silica particles in colloidal solutions form cakes on the membrane surface thereby causing severe reduction in the flux. The UF performance according to the gravitational orientation of the membrane cell (from 0 to $180^{\circ}$ inclined angle), was examined in an unstirred dead-end cell. We evaluate the effects of NCIF on membrane performance as the flux enhancement ($E_i$). In the dead-end UF of smaller size (7, 12 and 22 nm) silica colloidal solutions, changing the gravitational orientation (inclined angle) of the membrane cell induces NCIF in the membrane module and higher inclined angle and smaller size silica colloidal solution offer more stronger NCIF. This induced NCIF enhances back transport of the deposited silica solutes away from the membrane surface, therefore gives for the improvement of permeate flux. But in UF of more larger size (50 and 78 nm) silica colloidal solutions, NCIF effects are not appearing. These results suggest that the size of colloidal particle affects the extent of NCIF occurrence.