• Proceedings of the Korean Nuclear Society Conference
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• 1995.05b
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• pp.769-774
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• 1995

In this study, a transport model was developed in order to analyze and predict the transport behaviors of radionuclides mediated by pseudo-colloid in the fractured rock media. It was resulted that the transport of Pu-239 was faster than Ni-63 because pseudo-colloid formation constant of Pu-239 was greater than that of Ni-63. Also, the effect of pseudo-colloid formation on the transport of a radionuclide was shown to be very significant when the apparent pseudo colloid formation constant, $K_{ap}(m^{3}/kg)$, was greater than 100. Thus, it can be concluded that acceleration of radionuclide migration may be occurred because the pseudo-colloid formation of radionuclides increases the amount of mobile components in the solution and consequently decreases the amount of radionuclides adsorbed on the stationary solid medium.

• Nuclear Engineering and Technology
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• v.27 no.4
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• pp.532-543
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• 1995

In this study, a transport model was developed in order to analyze and predict the transport behaviors of radionuclides mediated by pseudo-colloid in the fractured rock media. The effect of pseudo-colloid formation on the transport of a radionuclide was shown to be tory significant when an ap-parent pseudo-colloid formation constant, $A_{ap}$ (㎥/kg), os greater than 100. It was resulted from example calculations that the transport of Pu-239 was faster than Ni-63 because pseudo-colloid formation constant of Pu-239 was venter than that of Ni-63. Thus, it can be concluded that acceleration of radionuclide migration may be occurred because the pseudo-colloid formation of radionuclides increases the amount of mobile components in the solution and consequently decreases the amount of radionuclides adsorbed on the stationary solid medium.

• Korean Journal of Environmental Agriculture
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• v.21 no.2
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• pp.130-135
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• 2002

Water-dispersible colloids are suspected to facilitate transport of contaminants to groundwater. This study evaluated some soil chemical properties in relation to the stability of colloids in soils of Jeju citrus orchards. Thirty surface soil samples were collected, and pH, organic matter content oxalate-extractable Al and Fe contents, and water-dispersible colloid content were measured. In soils of higher pH, water-dispersible colloid contents were higher. The stability of colloids was found to be significantly promoted at pH above 5$\sim$6. Since organic matter can act as a flocculant organic matter content significantly enhanced the colloid stability. In soils of less than 5% organic C, water-dispersible colloid content was expected to be significantly higher. In soils of higher oxalate-extractable Al and Fe contents, colloids remaining in suspension were lower. This indicated that amorphous oxides and hydroxides play important stabilizing roles in soil structure and can stabilize soil clay against dispersion. Therefore in soils of higher pH, lower organic matter, and lower amorphous clay minerals, the stability of water-dispersible colloids and the potential of colloid-mediated transport of organic chemicals to groundwater could be higher.

• Journal of Korea Water Resources Association
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• v.50 no.11
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• pp.715-723
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• 2017

Extracellular Polymeric Substances (EPS) in the water environment assemble fine, colloidal particles, such as clays, microorganisms and biomass, in large flocs, which are eventually subject to sedimentation and deposition and determine water/sediment quality and quantity. This study hence aimed to investigate the way that water and colloidal chemistry affects EPS-mediated flocculation of colloidal particles, using a jar-test experiment. Especially, ionic strength, divalent cation and humic substances concentrations were selected as experimental variables in the jar-test experiments, to elucidate their effects on EPS-mediated flocculation. A higher ionic strength increased flocculation capability, reducing electrostatic repulsion between EPS-attached colloidal particles and enhancing particle aggregation. 0.1 M NaCl ionic strength had higher flocculation capability, with 3 times larger floc size and 2.5 times lower suspended solid concentration, than 0.001 M NaCl. Divalent cations, such as $Ca^{2+}$, built divalent cationic bridges between colloidal particles and EPS (i.e., $colloid-Ca^{2+}-EPS$ or $EPS-Ca^{2+}-EPS$) and hence made colloidal particles to build into large, settelable flocs. A small $Ca^{2+}$ concentration enhanced flocculation capability, reducing suspended solid concentration 20 times lower than the initial dosed concentration. However, humic substances, adsorbed on colloidal particles, reduced flocculation, because they blocked EPS adsorption on colloidal particles and increased negative charges and electrostatic repulsion of colloidal particles. Suspended solid concentration in the tests with humic substances remained as high as the initial dosed concentration, indicating stabilization rather than flocculation. Findings about EPS-mediated flocculation in this research will be used for better understanding the fate and transport of colloidal particles in the water environment and for developing the best management practices for water/sediment quality.