• Journal of the Korean Geosynthetics Society
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• v.18 no.3
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• pp.33-44
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• 2019

Clinker layer is a stratum structure distributed in volcanic area such as Jeju Island. The clinker layers were formed in between the repetitive action of eruption and solidification of lava flows. Since the clinker layer contains a large amount of voids accompanied by the lava gas ejection process, there is a possibility of inducing overall stability of the ground due to the low stiffness and strength of the clinker layer. Therefore, in this study, site investigation was carried out at both ends of the 00 bridge where the clinker layers exist. And, based on the ground survey results, the behavior of shallow foundations was analyzed numerically. In addition, the improved shallow foundation behavior in grouting substitution using the chemical injection method of the clinker layer was compared with the shallow foundation behavior in the ground, and the grouting substitution efficiency of each layer was analyzed. As a result, the bearing capacity, the replacement efficiency and elastic settlement were different according to the presence or absence of the sediment layer. This is because the sediment layer has a lower stiffness and density than the clinker layer.

• Cement
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• s.66
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• pp.12-15
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• 1977

석회석과 고로수재 slag을 1.6 : 1로 혼합 분쇄한 원료를 1,450$^{\circ}C$에서 소결하여 고$C_3A$ clinker를 얻었다. 이 clinker 중에는 $C_3S$ 40$\%$, $C_2S$ 31$\%$, $C_3A$ 22$\%$, $C_4AF$ 2$\%$를 함유하고 있으며 보통 크링카 보다 $C_3A$ 함량이 2$\~$3배 정도 높고, clinker 색은 연두색을 띄는 것이 특색이다. 이와 같이 $C_3A$ 함량이 높은 시멘트의 특성 및 제조 가능성을 검토한 결과는 다음과 같다. 1) 석회석과 slag를 1.6 : 1(61.5$\%$ : 38.5$\%$)로 사용할 경우 보통 시멘트 제조시 석회석 사용량 보다 약 28$\%$ 정도 절감되나 고품위의 석회석이 요구된다. 2) 동일 free CaO 0.4$\%$를 기준으로 소성할 경우 고$C_3A$ clinker가 보통 clinker 보다 소성 시간이 20분 단축된다. 3) carbonate 분해열을 비교하면 고$C_3A$ 시멘트 원료가 보통 시멘트 원료보다 116Kcal/$\cal{kg}$-cl 절감된다. 4) $C_3A$ 함량이 높아 가소성이 저하되고 표준연도의 시멘트 paste를 얻기 위하여서는 보통 시멘트 보다 많은 물량이 요구되며 응결시간도 빠르다. 5) Blaine 3,000$cm^3$/g으로 분쇄한 고$C_3A$ 시멘트의 3 일강도는 보통 시멘트 보다 40$\~$50$\cal{kg}$/$cm^3$ 더 높으나 28 일 강도는 다소 저하되는 경향이며 Blaine 5,000$cm^2$/g으로 분쇄한 고$C_3A$ 시멘트는 조강 시멘트와 같은 강도 수준이다.

• Journal of the Korean Ceramic Society
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• v.30 no.1
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• pp.7-16
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• 1993

Effect of sulfate on the reactionof C3S formation in presence of clinker melt and its appearance in clinker were investigated, using (NH4)2SO4 and CaSO4 as sulfate sources. When (NH4)2SO4 and CaSO4 were added, both showed the similar results, 1.0wt% of sulfate could promoted the reaction of C3S formation, however for its content of more than 2.0wt%, the formation of C3S was prevented. Residual limit of sulfate to C3S formation is about 1.4wt%. Appearances of sulfate were C4A3l and CaSO4 in interstitial phase. For the addition of (NH4)2SO4 or CaSO4 of 20wt%~4.0wt%, C3S grains showed the hypertrophic growth. We might consider that, because sulfate reduced the surface tension and viscosity of the clinker melt, C3S crystals were precipitated below 140$0^{\circ}C$, and the crystlas of C3S were coalesced and linked in the same crystallographical direction with increasing temperature becuase of their rapid growth rate.

• Journal of the Korean Ceramic Society
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• v.44 no.9
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• pp.483-488
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• 2007

The influence of $P_2O_5$ on clinker mineral composition and the cement quality was investigated. When the sewage sludge was used as a raw material in place of clay, the presence of $P_2O_5$ in sewage sludge affects the mineral composition and the clinker quality. As the $P_2O_5$ concentration in raw mix increases, the burnability of clinker becomes worse and the alite decomposes into belite and free-CaO, so belite increases with the decrease of alite. The early strength of mortar decreases with the increase of $P_2O_5$ concentration. On the other hand, later-age strength increases with the increase of belite content. The setting time of cement was delayed with the $P_2O_5$ concentration above 0.6 wt%.

• Cement Symposium
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• no.30
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• pp.132-138
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• 2003

시멘트 kiln용 염기성 벽돌의 시멘트 coating 부착성과 고온 강도 특성 향상을 위하여 $Fe_2O_3$함유 magnesia clinker을 적용하였다. $Fe_2O_3$ 함유 magnesia clinker가 사용된 Magnesia-Chromite질 벽돌은 통기율이 크게 저하되었고 상온 및 고온 꺽임강도가 증가되었다. 특히, $Fe_2O_3$ 함유 magnesia clinker를 적용하여 약 1$\%$의 $Fe_2O_3$ 함량을 가지는 Magnesia-Spinel질 벽돌은 고온에서 높은 꺽임 강도, 열충격 저항성, 향상된 시멘트 coating 부착성을 나타내었다.

• Journal of the Korean Ceramic Society
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• v.12 no.2
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• pp.21-25
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• 1975

As the major alumina source, domestic alunite was applied to synthesize the clinker for rapid hardening cement. The main minerals of the clinker were found to be C3S, C11A7-CaF2 and some C4AF by means of chemical treatment, x-ray diffraction analysis and microscopic observation. Rapid hardening cement was made of the clinker by adding suitable amount of hemi-hydrite and anhydrite. The setting time of the cement was regulated with citric acid as setter.

• Journal of the Korean Ceramic Society
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• v.27 no.2
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• pp.195-200
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• 1990

For the development of low energy cement, the belite cement clinker of calcium sulphoaluminate ferrite type was synthesized at 130$0^{\circ}C$ and containing C2S, C4A3S as the major minerals along with C3A, C4AF, CS by using limestone, dolomite, clay, iron ore, gypsum and alumina as raw materials. At over 130$0^{\circ}C$, C4A3S was decomposed and thus C3A was increased. When hydrated, this cement was hardened, producing ettringite, CSH, etc.

• The Korean Journal of Ceramics
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• v.2 no.3
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• pp.147-151
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• 1996

By adding borax into the raw mix, Modified Belite Cement clinker and cements were prepared. Clinkerization and hydration reactions were investigated in order to better understand. Borax-bearing MBC clinker sintered at 1300℃ for 1 hour showed excellent burnability. Borax stabilized α'and β-C2S at room temperature. In the hydration of the cement prepared with the borax-bearing clinker, ettringite, monosulphate, C-S-H hydrates and CH were formed. The hydration of calcium sulphoaluminate was less reactive than the cement prepared with the controlled clinker at early hydration time. But, as hydration time elapsed, this cement showed more active hydraulicity and higher compressive strength development.

• Journal of the Korean Ceramic Society
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• v.37 no.5
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• pp.459-465
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• 2000

3CaO.3Al2O3.CaSO4(C4A3)clinker was prepared by solid state reaction and then its hydration property was investigated. C4A3 clinker was fired at various temperatures in the range of 700~135$0^{\circ}C$. The hydration of it was studied by XRD, DSC, Solid-state 27Al MAS NMR and SEM. According to the results, the Ca4A3 clinker was produced by reacting calcium aluminates with CaSO4 and Al2O3 and C4A3 was formed as a main phase after calcining at 120$0^{\circ}C$. The hydration products were mainly calcium monosulfoaluminate hydrate and Al(OH)3, and they were produced after 2hrs of hydration. However the hydration rate was about 74% at 3days.

• Journal of the Korean Ceramic Society
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• v.22 no.1
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• pp.25-34
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• 1985

The states of alkali occuring in Portland cement clinker were studied. Potassium was added to raw mixture by there kinds ; $K_2SO_4$, $K_2CO_3$ and KOH. In case of $K_2CO_3$ and KOH addition the new state of unstable alkali was found when alkakli content is high and $SO_3$ content is low in the clinker. Unstable state of highly basic free 4K_2O$ causes lowering burnability much more than alkali sulfate especially at the early stage of burning. Lowered burnability by 4K_2O$ became more serious with higher LSF. Unstable free-4K_2O$ which is readily soluble with water reacts with gypsum to form $Ca(OH)_2$ and syngenite as soon as water is added. As a results the liberation rate of heat of hydration at the early hydration process(1st peak) was increased.