• 한국연초학회지
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• 제27권1호
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• pp.51-58
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• 2005

The objective of this study was to evaluate the effect of cigarette filter on in vitro cytotoxicity of cigarette mainstream smoke from the cigarette. In this work, we used 3 types of cigarettes included non-filtered 2R4F cigarette, cellulose acetate-filtered 2R4F cigarette, and carbon dual-filtered 2R4F cigarette which was made from original 2R4F by replacing with an acetate filter containing carbon. The cytotoxicity of both the cigarette smoke condensate (CSC), which was collected in Cambridge filter pad, and the gas/vapor phase (GVP), which was bubbled through in phosphate-buffered saline in a gas-washing bottle, was determined using a neutral red uptake assay with CHO-K1 cells. With regard to cytotoxicity when calculated on an equal puff basis, the cytotoxicity of CSC from the filtered cigarettes was lower than that of the non filtered cigarette. Also, $EC_{50}$ vlaue of GVP from carbon filter cigarette was 40.9 puff/L, indicating the cytotoxicity to be $20\%$ lower than that of the CA filter cigarette. The cytotoxicity of the GVP was correlated to the several vapor phase components (formaldehyde, acetaldehyde, acetone, acrolein, crotonaldehyde and MEK). In conclusion, carbon filter, which significantly reduced the amount of carbonyl compounds in mainstream cigarette smoke, results in significant reductions in the cytotoxicity potential of the smoke.

• 한국연초학회지
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• 제24권1호
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• pp.46-52
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• 2002

This study was carried out to investigate the transfer rate of I-menthol constituent into cigarette case and delivery rate to cigarette smoke. Test sample was used a light-type standard brand cigarette made in Korea. I-Menthol contents was measured according to A.O.A.C(1990) method by G.C and smoking conditions was a puff volume of 35$m\ell$ and 2.0s duration, taken once per minute to filter tipping paper plus 3mmwith 20 cigarettes. Migration rate of menthol into cigarette case had an interrelation with triacetin contents into filter and 6% triacetin level was most suitable. I-Menthol transferred to filter part from tobacco sheet by 20.2% in one month after cigarette manufacture, and the transfer was continued subsequently. Maximum menthol transfer in five months was 4.1% to foils and other packing materials and the loss outside of cigarette pack was also 3.9% below. The migration balance of menthol into cigarette pack and the delivery to cigarette smoke were the optimum condition when menthol was added at the ration of 30% in filter to 70% in the other parts into cigarette.

• 한국연초학회지
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• 제24권2호
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• pp.107-112
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• 2002

There are many combination with the porosity of tipping paper and plug wrap for a design of ventilation rate of cigarette. This study was carried out to determine the effect of a design of permeability of tipping paper and inner or outer of plug wrap on the ventilation rate of cigarette with constant pressure drop in column part and filter part. Our results indicated that the higher the plugwrap porosity, the higher the ventilation rate and the less variable of cigarette in case of mono filter. But, in case of duel filter, the ventilation rate of cigarette was depended on the manufacturing method of filter plug, even though using the same porous plug wrap on inner and outer of filter. We also found that the porosity of outer plug wrap was more effect on the ventilation rate than the porosity of inner plug wrap. As the high porosity of inner plug wrap compared with the porosity of outer plug wrap, the less variable of ventilation rate of cigarette in any combination of the porosity of plug wrap. When we used the higher porous outer plug wrap than inner plug wrap, the ventilation rate of cigarette was high. Also, the higher the inner plug wrap porosity, the less variable of ventilation rate of cigarette.

• 한국연초학회지
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• 제21권2호
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• pp.136-143
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• 1999

This study was conducted to evaluate the degradation characteristics of waste cigarette filters under 0, 5, 10, and 15cm in depth from soil surface by environmental conditions. Weather was the most important factor during degradation of waste cigarette filters in this study. Bulking of cellulose acetate filaments exposed on soil surface was observed after 2 months, but the form of filter was kept up after 12 months. The treated cigarette filters in soil landfill revealed a little different degradation pattern at each soil landfill depth, The sample in 5cm depth of soil was more degraded then other site. A fluffy appearance of cellulose acetate filaments in the control filter rods was also developed more strongly in soil landfill then on soil surface. From the observation of waste cigarette filters by scanning electron microscopy, much degradation of the fiber of waste cigarette filters could be ascertained in soil landfill. The weight of waste cigarette filters under 5cm from soil surface was reduced about 50%, and the tensile strength of the samples in soil surface and under 5cm from soil surface were reduced 66.0% and 92.4%, respectively. The microbial experiment date that the viable cell number in microbial population and cellulolytic microorganisms showed the maximum values under 5cm from soil surface, suggest that microorganisms in soil play an important roll in the degradation of acetate cigarette filters.

• 한국연초학회지
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• 제20권2호
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• pp.205-209
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• 1998

This study was conducted to evaluate the effect of triacetin(TA) treatment during manufacturing carbon dual filter for the adsorption of cigarette smoke components by activated carbons. The measurements were carried out by separation of activated carbon from carbon dual filter, and the specific surface area analyzed. The specific surface area of activated carbon from the domestic cigarette filter and from the foreign cigarette filter by degassing at 9$0^{\circ}C$ was 163$\pm$32$m^2$/g, and 16.6$\pm$1.9$m^2$/g, respectively. Those values were very lower than that of degassing at 35$0^{\circ}C$ (Domestic brand: 952$\pm$30$m^2$/g, and Foreign brand: 847$\pm$73$m^2$/g). By comparing the adsorption capacity of acetone and benzene with and without triacetin treated activated carbon, there was a 20% reduction of adsorption capacity by 5% triacetin treatment. Also, from the cilia toxicity test with carbon dual filter treated 0 % TA and 8 % TA, the cilia survival time was 706$\pm$74sec. and 603$\pm$64sec. for 0% TA and 8% TA, respectively. The delivery rate of vapour phase of cigarette smoke, which consists of main components of cilia toxicity, was higher at 8% TA filter than 0 % TA filter. Our results indicate that the treated TA covered the micro-pore of activated carbon, and then reduced specific surface area, finally, decreased the adsorption of vapour phase from cigarette smoke.

• 한국연초학회지
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• 제22권2호
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• pp.151-156
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• 2000

The variability of a ventilated filter cigarette depends on the details of its construction and on the variabilities of its components. Variations in filter ventilation arise from many sources, including variations in tobacco rod pressure drop, filter tip pressure drop, tipping paper permeability, and plugwrap permeability. To reduce the filter ventilation variability, the variability of filter ventilation levels in ventilated cigarettes is studied by Monte Carlo Analysis. For each trials a value is selected for tobacco rod pressure drop, filter tip pressure drop, tipping paper permeability, and plugwrap permeability. These values are selected randomly from a normal distribution based on the target and coefficient of variation for each input variable. The results of this analysis for filter ventilation variation suggest that the variations of filter ventilation are dependent on the details of cigarette designs studied and reducing the variability of any cigarette component will reduce filter ventilation variability. For typical cigarettes, variation in the permeability of tipping paper is usually the most significant contributor to filter ventilation variability. Results of a Monte Carlo Analysis could provide both general insights and specific practical guidance about the design of ventilated filter cigarettes.

• 한국연초학회지
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• 제23권1호
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• pp.60-64
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• 2001

The variability of a ventilated filter cigarette depends on the details of its construction and one properties of its components and the variations in filter ventilation is effected by many factors such as tobacco column pressure drop, filter pressure drop, tipping paper and plug wrap permeability, and vent position. In this study, the effects of combination of tipping paper and plug wrap on filter ventilation of cigarettes were studied for the target ventilation level under the specific tobacco column and filter tip in order to reduce the variation of filter ventilation. When Nicolas Baskevitch\`s equation on filter ventilation was used to try out Monte Carlo Simulation, at the combination where tipping paper permeability is high and plug wrap permeability is low, even the small change in tipping paper and plug wrap permeability showed high variation of target ventilation level. Also, according to the analysis data of filter ventilation in cigarettes designed at the level of 45% filter ventilation by the combinations with tipping paper and plug wrap, the variation in cigarette filter ventilation was increased as increasing tipping paper permeability and decreasing plug wrap permeability. As the results of this study, the variation of filter ventilation can be reduced by increasing plug wrap permeability/tipping paper permeability ratio in the cigarette design, considering 2-3% of tipping paper permeability variation(%CV) and about 10% of plugwrap permeability variation.

• 한국연초학회지
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• 제20권1호
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• pp.115-123
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• 1998

The semi-volatile fraction of cigarette mainstream smoke contains the most important aroma and taste that enhance smoke flavor. The components in mainstream smoke were analysed for commercially available cigarettes. To compare the semi-volatile components delivered from mainstream smoke of domestic cigarette with imported cigarette, we analyzed three types of filter cigarettes such as cellulose acetate mono filter, carbon dual filter and slim filter cigarette. Mainstream smoke was collected with a combination of Cambridge filter pad and liquid trap containing a small amount of acetone cooled by dry ice-methanol. We have identified 43 components from mainstream smoke by GC and GC/MS and found that benzene, toluene, 4-hydroxy-4-methyl-2-pentanone, 5-methyl-2-furaldehyde, acetic acids nicotine and triacetin were the main peaks in mainstream smoke. Also we have compared the relative amounts of semi-volatile compounds delivered from the domestic and imported cigarettes with three different filters. From the results of this study, the relative amounts of limonene, acetic acid, 5-methyl-Lfuraldehyde delivered from the imported cigarettes were generally higher than those of the domestic one's.

• 펄프종이기술
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• 제33권1호
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• pp.64-72
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• 2001

The cigarette ventilation affects not only the amount of tar and nicotine delivery by a cigarette, but also the composition of the smoke. Therefore, it is important to stabilize of variability in cigarette ventilation that would be affected by changes in cigarette components. This work was conducted to determine the major factors that influence the cigarette ventilation and also to provide fundamental informations for improving the uniformity of cigarette performances. To evaluate the effect of cigarette ventilation as a dependant variable, the three independent factors were the air permeability of plugwrap, tipping paper and the filter pressure drop. We determined the effect of paper permeability on ventilation variability and the optimum condition in combinations of independent factors. The mean of cigarette ventilation was increased as plugwrap permeability increases, particularly at 26,000 CU. However, it was exhibited that standard deviation and coefficient of variation of the cigarette ventilation were decreased with increasing plugwrap permeability. At the 600 CU and 1,200 CU of tipping paper permeability, process capability index (Cp) of the cigarette ventilation increased as plugwrap permeability increases. Following the optimum condition of cigarette ventilation induced by fitted regression equation, one was to optimize 50% ventilation level is by combination with plugwrap permeability of 16,000 CU, tipping paper permeability of 810 CU, filter pressure drop of 319 mm$H_2O$, respectively.

• 한국연초학회지
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• 제24권1호
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• pp.38-45
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• 2002

This study was conducted to determine the smoke component concentration and the smoke distribution in the cambridge filter pad and cigarette filter with stalk position and grade of Korean leaf tobaccos. 12 grades of flue-cured and burley leaf tobaccos which were taken from the Kim-cheon and Ock-cheon leaf tobacco processing factory were used for this study. Six kinds of smoke components such as tar, nicotine, water, carbon monoxide(CO), carbon dioxide($CO_2$) puff No. collected in the cambridge filter pad and cigarette filter were analyzed. Also, nicotine/tar, CO/tar ratio were calculated from the analytical data. Puff no., CO, and $CO_2$ concentration of flue-cured and burley tobacco leaves at high stalk position were higher than those of low stalk position, and these components were increased in high grade of leaf tobacco. Compared with flue-cured tobacco, burley tobacco showed a little values of puff no., nicotine, and tar concentration. The pH range of burley tobaccos was broader than that of flue-cured tobaccos, and the ammonia concentration of burley tobaccos was significantly higher than that of flue-cured tobaccos. The pH value and ammonia concentration of burley tobaccos were decreased as stalk position of leaf tobaccos decreased. The distribution of smoke components collected in the cambridge filter pad and cigarette filter was different with a different grade and stalk position of tobacco leaves. In high stalk position of tobacco leaves, the portion of smoke components collected in the cambridge filter pad was also increased. The average nicotine, water, and tar removal efficiency by a cigarette filter in a flue-cured tobacco were 37%, 64%, and 48%, respectively. Compared with flue-cured tobaccos, smoke components of burley tobaccos had high nicotine and low water removal efficiency by a cigarette filter. The average ratio of nicotine/tar and CO/tar of flue-cured tobaccos and burley tobaccos were 0.097, 1.22, 0.094, and 0.97, in order. Nicotine/tar ratio was decreased and CO/tar ratio was increased in low stalk position.