• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2008년도 추계학술대회 논문집
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• pp.583-584
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• 2008

• 한국재료학회지
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• 제28권1호
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• pp.6-11
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• 2018

There are various manufacturing processes for pure $SiO_2$ that is used as abrasives, chemicals, filters, and glasses, and in metallurgy and optical industries. In the optical fiber industry, to produce $SiO_2$ preform, $SiCl_4$ is utilized as a raw material. However, the combustion reaction of $SiCl_4$ has caused critical environmental issues, such as ozone deficiency by chlorine compounds, the greenhouse effect by carbon dioxide and corrosive gas such as hydrochloric acid. Thus, finding an alternative source that does not have those environmental issues is important for the future. Octamethylcyclotetrasiloxane (OMCTS or D4) as a chlorine free source is recently promising candidate for the $SiO_2$ preform formation. In this study, we first conducted a vaporizer design to vaporize the OMCTS. The vaporizer for the OMCTS vaporization was produced on the basis of the results of the vaporizer design. The size of the primary particle of the $SiO_2$ formed by OMCTS was less than 100 nm. X-ray diffraction patterns of the $SiO_2$ indicated an amorphous phase. Fourier-transform infrared spectroscopy analysis revealed the Si-O-Si bond without the -OH group.

• 한국가스학회지
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• 제11권4호
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• pp.98-103
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• 2007

발생가능성 분석은 염소공정의 염소투입설비에서 누출 가능성을 교정하는데 자주 사용되고 있다. 그리고 이러한 시설은 전형적으로 압력용기, 기화기, 배관, 측량장비, 안전장치로 등으로 구성되어 있다. 이 논문에서는 가능성 분석절차와 기계적 요소들의 고장률에 대하여 사건 시나리오를 만들 인적오류도 고려하였다. 논문의 주된 목적은 결정된 각각의 시나리오의 발생가능성을 계산하는 것으로 발생가능성분석 방법에 근거하여 기계요소의 고장률과 인적오류를 포함하여 계산하였다. 그 결과, 주요 $Cl_2$ 취급공정에서 누출이 발생할 가능성이 $5.73{\times}10^{-5}$로 예측되었으며 세정시스템의 고장확률은 $4.11{\times}10^{-2}$로 나타났다.

• 한국가스학회:학술대회논문집
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• 한국가스학회 2007년도 춘계학술발표회 논문집
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• pp.180-185
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• 2007

Likelihood analysis was used for the revision of release probability/frequency in chlorine Injection facilities used in chlorine process. Typically these facilities consist of pressure cylinder, vaporizer, pipeline, measuring equipment and safety equipment. This paper described the incident scenarios considered, likelihood analysis procedure and the selection and application of basic events and for failure rates of mechanical components. Human errors were also considered. The major objective of this paper is to estimate the likelihood of each determined incident scenarios. We estimated failure rates of mechanical components based on likelihood analysis procedure. Human errors were also considered. It was estimated to have $5.73{\times}10^{-5}\;Cl_2$ leak per year during the major $Cl_2$ handling process. The probability of failure in scrubber system was $4.11{\times}10^{-2}/demand$.