• Title/Summary/Keyword: chlorine vaporizer

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Formation of Optical Fiber Preform Using Octamethylcyclotetrasiloxane (Octamethylcyclotetrasiloxane를 이용한 광섬유 클래드 프리폼 형성)

  • Choi, Jinseok;Lee, Tae Kyun;Park, Seong Gyu;Lee, Ga Hyoung;Jun, Gu Sik;An, Sung Jin
    • Korean Journal of Materials Research
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    • v.28 no.1
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    • pp.6-11
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    • 2018
  • There are various manufacturing processes for pure $SiO_2$ that is used as abrasives, chemicals, filters, and glasses, and in metallurgy and optical industries. In the optical fiber industry, to produce $SiO_2$ preform, $SiCl_4$ is utilized as a raw material. However, the combustion reaction of $SiCl_4$ has caused critical environmental issues, such as ozone deficiency by chlorine compounds, the greenhouse effect by carbon dioxide and corrosive gas such as hydrochloric acid. Thus, finding an alternative source that does not have those environmental issues is important for the future. Octamethylcyclotetrasiloxane (OMCTS or D4) as a chlorine free source is recently promising candidate for the $SiO_2$ preform formation. In this study, we first conducted a vaporizer design to vaporize the OMCTS. The vaporizer for the OMCTS vaporization was produced on the basis of the results of the vaporizer design. The size of the primary particle of the $SiO_2$ formed by OMCTS was less than 100 nm. X-ray diffraction patterns of the $SiO_2$ indicated an amorphous phase. Fourier-transform infrared spectroscopy analysis revealed the Si-O-Si bond without the -OH group.

Likelihood Estimation of Release Incidents in Chlorine$(Cl_2)$ Facility (염소$(Cl_2)$시설에 대한 누출사고 가능성 추정)

  • Baek, Jong-Bae
    • Journal of the Korean Institute of Gas
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    • v.11 no.4
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    • pp.98-103
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    • 2007
  • Likelihood analysis was used for the revision of release probability/frequency in chlorine Injection facilities used in chlorine process. Typically these facilities consist of pressure cylinder, vaporizer, pipeline, measuring equipment and safety equipment. This paper described the incident scenarios considered, likelihood analysis procedure and the selection and application of basic events and for failure rates of mechanical components. Human errors were also considered. The major objective of this paper is to estimate the likelihood of each determined incident scenarios. We estimated failure rates of mechanical components based on likelihood analysis procedure. Human errors were also considered. It was estimated to have $5.73{\times}10^{-5}$ $Cl_2$ leak per year during the major $Cl_2$ handling process. The probability of failure in scrubber system was$4.11{\times}10^{-2}$/demand.

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Likelihood Estimation of Release Incidents in Chlorine$(Cl_2)$ Facility (염소$(Cl_2)$시설에 대한 누출가능성 예측)

  • Lee, Jae-Jun;Kim, Tae-Su;Lee, Dae-Hee;Yoo, Byung-Tae;Baek, Jong-Bae;Ko, Jae-Wook;An, Hyung-Hwan
    • 한국가스학회:학술대회논문집
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    • 2007.04a
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    • pp.180-185
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    • 2007
  • Likelihood analysis was used for the revision of release probability/frequency in chlorine Injection facilities used in chlorine process. Typically these facilities consist of pressure cylinder, vaporizer, pipeline, measuring equipment and safety equipment. This paper described the incident scenarios considered, likelihood analysis procedure and the selection and application of basic events and for failure rates of mechanical components. Human errors were also considered. The major objective of this paper is to estimate the likelihood of each determined incident scenarios. We estimated failure rates of mechanical components based on likelihood analysis procedure. Human errors were also considered. It was estimated to have $5.73{\times}10^{-5}\;Cl_2$ leak per year during the major $Cl_2$ handling process. The probability of failure in scrubber system was $4.11{\times}10^{-2}/demand$.

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