• Title/Summary/Keyword: chlorine removal

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Removal of Ammonia Nitrogen and Reduction of THMs in Low Temperature by BAC Pilot Plant (BAC Pilot Plant 를 이용한 겨울철 암모니아성 질소 제거 및 THMs 변화)

  • Kang, Eun-Jo;Seo, Young-Jin;Lee, Won-Kwon;Chun, Pyoung-Hee;Lee, Ji-Hyung;Yoon, Jung-Hyo;Kim, Dong-Youn
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.4
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    • pp.107-114
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    • 1995
  • The raw drinking water quality is getting worse because of the winter drought and the conventional treatment system is'nt suitable to obtain the satisfied quality of water. So, the advanced water system, BAC(Biological Activated Carbon) process is said to be effective to remove dissolved organics and ammonia nitrogen. In our study, the BAC pilot plant using Nak-dong river water is tested in low temperature. Following results are found from the study. The ammonia nitrogen removal rate of BAC system using wood-based carbon (PICABIOL) was 99% in $6^{\circ}C$ temperature. Chlorine dosage in wood-based BAC effluent was reduced to 67% of that in sand filtered wate. It resulted from the removal of ammonia nitrogen. Also, THM formed by chlorine addition in wood-based BAC effluent was decreased to 65% of that in sand filtered water. In the case of dual-filter, the removal efficiency of ammonia nitrogen was increased 30% more than in conventional sand filter. According to this result, the ammonia nitrogen load to BAC system could be lessened by the use of dual-filter.

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Bacterial attachment on granular activated carbon and effect of chlorine disinfection (입상활성탄 부착세균과 염소소독 연구)

  • Baek, Youngae;Joe, Woohyun;Hong, Byungeui;Choi, Youngjune;Ahn, Seoungkoo
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.3
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    • pp.339-344
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    • 2009
  • The authors investigated the bacterial community attached to granular activated carbon(GAC) particles and the susceptibility of the community to chlorine disinfection. The study was carried out at the G Water Treatment Plant in Seoul, which was in full-scale operation. Bacteria attached to the surface of GAC increased gradually with treatment from $0.4{\times}106{\sim}8.5{\times}106 CFU/g$. TOC removal was under 1.0 mg/L due to increased bacterial community on the surface of GAC. It was found that TOC removal was closely related with physical and biological parameters such as pore volume and the number of attached bacteria. When the washed and the attached cells were disinfected with 1.0mg/L of chlorine for 1 hour, the washed cells with chlorination could be controlled, but the number of the attached cells increased gradually. The results suggest a possibility that the treatment and disinfection barriers can be penetrated and pathogenic bacteria may break into the drinking water supplying system.

The Thermal Behavior and Removal of Chloride in EAF Dust (EAF Dust중 염화물의 거동과 제거에 관한 연구)

  • 김영환;김종학;고인용;문석민;이대열;신형기;오재현
    • Resources Recycling
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    • v.6 no.1
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    • pp.35-39
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    • 1997
  • This study was carried out to find the existing forms of chlorlnc in EM dust and to understand the valaliliratian behavior and the removal of chlorine from EAF dust with lemperalure and heating almosphere The chemical compositions of dust A are 27.3%Fe. 21.8%3Zn, 3 15%Pb, 3 51%C1 and that of dust B BE 33.92%Fe, 15.94%Zn, 2.73% Pb, 3.98%Cl. The XRD analysis and water leaching test shows that chlorlne in EM dust exist mainly as NaCI, KCI, Pb (0H)Cl. Above 99% of chlorine was volatilized when dust was hentcd in alr atmosphere at 1100$^{\circ}$C h r 1 hour and that was 96% when heated in reduction atmosnherc at 1100$^{\circ}$C for 1 hour.

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A Basic Study for Tasted and Odors Treatment and Optimum Chemical Feed in Existing Water Treatment Processes (기존 정수처리공정에서 이취미처리 및 최적 약품투입을 위한 기초연구)

  • Lim, Bong-Su;Bae, Byung-Uk;Jun, Hang-Bae
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.4
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    • pp.94-102
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    • 1996
  • This study was accomplished to get the basic data for the optimum chemical feed, evaluating interference between tastes and odors chemicals and coagulants in existing water treatment processes. During the tastes and odors occurs at D intaking tower area in 1995, PAC(Powdered Activated Carbon) feed with coagulants was PAC feed only and with coagulant simultaneously were appeared TON removal efficiency about 84%-87% within 20 min reaction time, but feed with time intervals was about 98% TON removal efficiency. Therefore in the case of PAC feed with coagulant, it is effective to feed coagulant on some time intervals in removing tastes and odors. It is not effective to feed PAC with chlorine dioxide($ClO_2$) or chlorine simultaneously in removing tastes and odors, because these chemicals were reduced the adsorption capacity of PAC.

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The CT values Comparisons for Antibiotic Resistant Bacteria and Resistant Genes by Chlorination (항생제 내성균 및 유전자제거를 위한 염소 CT 값 비교)

  • Oh, Jun-Sik;Kim, Sungpyo
    • Journal of Wetlands Research
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    • v.16 no.2
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    • pp.269-274
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    • 2014
  • The purpose of this study is to compare CT (disinfectant concentration * time) values in removing the antibiotic resistance bacteria, antibiotic resistance gene and transfer of antibiotic resistance genes. Different concentration of chlorine(C) and contact time(T) according to the removal of antibiotic resistance was calculated for each. As a result, for the 90% removal of antibiotic resistant bacteria, around 176~353 mg min/L CT values are needed. For the removal of the antibiotic resistance gene, 195~372 mg min/L CT values are required. For the 90% reduction of antibiotic resistance gene transfer by chlorine disinfection, 187~489 mg min/L CT values are needed. Based on our results, higher CT value was required for removing antibiotic resistant genes rather than antibiotic resistance bacteria.

Recovery of Zirconium and Removal of Uranium from Alloy Waste by Chloride Volatilization Method

  • Sato, Nobuaki;Minami, Ryosuke;Fujino, Takeo;Matsuda, Kenji
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.179-182
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    • 2001
  • The chloride volatilization method for the recovery of zirconium and removal of uranium from zirconium containing metallic wastes formed in spent fuel reprocessing was studied using the simulated alloy waste, i.e. the mixture of Zr foil and UO$_2$/U$_3$O$_{8}$ powder. When the simulated waste was heated to react with chlorine gas at 350- l00$0^{\circ}C$, the zirconium metal changed to volatile ZrCl$_4$showing high volatility ratio (Vzr) of 99%. The amount of volatilized uranium increases at higher temperatures causing lowering of decontamination factor (DF) of uranium. This is thought to be caused by the chlorination of UO$_2$ with ZrCl$_4$vapor. The highest DF value of 12.5 was obtained when the reaction temperature was 35$0^{\circ}C$. Addition of 10 vol.% oxygen gas into chlorine gas was effective for suppressing the volatilization of uranium, while the volatilization ratio of zirconium was decreased to 68% with the addition of 20 vol.% oxygen. In the case of the mixture of Zr foil and U$_3$O$_{8}$, the V value of uranium showed minimum (44%) at 40$0^{\circ}C$ with chlorine gas giving the highest DF value 24.3. When the 10 vol.% oxygen was added to chlorine gas, the V value of zirconium decreased to 82% at $600^{\circ}C$, but almost all the uranium volatilized (Vu=99%), which may be caused by the formation of volatile uranium chlorides under oxidative atmosphere.ere.

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Effect of post-annealing on single-walled carbon nanotubes synthesized by arc-discharge

  • Park, Suyoung;Choi, Sun-Woo;Jin, Changhyun
    • Journal of Ceramic Processing Research
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    • v.20 no.4
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    • pp.388-394
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    • 2019
  • In this study, high-purity single-walled carbon nanotubes (SWCNTs) were prepared by removing the unreacted metal constituents and amorphous carbon impurities using a post-annealing process. Unlike conventional thermal processing techniques, this technique involved different gas atmospheres for efficient removal of impurities. A heat treatment was conducted in the presence of chlorine, oxygen, and chlorine + oxygen gases. The nanotubes demonstrated the best characteristics, when the heat treatment was conducted in the presence of a mixture of chlorine and oxygen gases. The scanning electron microscopy, transmission electron microscopy, ultraviolet absorbance, and sheet resistance measurements showed that the heat treatment process efficiently removed the unreacted metal and amorphous carbon impurities from the as-synthesized SWCNTs. The high-purity SWCNTs exhibited improved electrical conductivities. Such high-purity SWCNTs can be used in various carbon composites for improving the sensitivity of gas sensors.

Ozone Effect on the Formation of Chlorine Disinfection Byproducts in Water Treatment Process (정수처리공정상 염소소독부산물형성에 미치는 오존의 영향)

  • Seong, Nak Chang;Park, Hyeon Seok;Lee, Seong Sik;Lee, Yong Hui;Lee, Jong Pal;Yun, Tae Gyeong
    • Journal of Environmental Science International
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    • v.13 no.1
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    • pp.55-59
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    • 2004
  • The effect of ozone on the formation and the removal of disinfection byproducts(DBPs) of chlorination process was studied to elucidate the performance of water treatment process. The samples of raw water, prechlorination process, and preozonation process were analyzed quantitatively according to the Standard Methods for the Examination of drinking water. As a result, most of total trihalomethanes(THMs) which were formed in prechlorine treatment process was not removed in the preozonation process. Most of haloacetic acids(HAAs), haloacetonitriles(HANs), and chloral hydrate(CH) was removed in sedimentation and biological activated carbon(BAC) filtration processes. However, DBPs were increased more or less by postchlorine step. In particular, the formation of THMs and HAAs depends on ozone more than chlorine, but, the formation of HANs and CH depends on chlorine more than ozone. The seasonal variation of DBPs concentration for the year needs to be investigated to study the temperature effect because DBPs strongly depend on temperature among various efficient factors.

The Adsorption Removal Characteristics of Trace Organic By-Products in Disinfection of Drinking Water by Biological Activated Carbon(BAC) (음용수 소독 미량 유기오염물질 생성에 대한 생물활성탄(Biological Activated Carbon)의 흡착제거 특성)

  • Ok, Chi-Sang;Kim, Jeong-A;Bae, Gi-Cheol
    • Journal of Environmental Science International
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    • v.1 no.1
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    • pp.53-68
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    • 1992
  • In order to research the adsorption removal characteristics of trace organic by-products in disinfection of drinking water by biological activated carbon(BAC), water samples disinfect- ted with $Cl_2$, $O_3$ and $ClO_2$ after treatment by fluidized-bed system with water added with humic acid(10mg/L) were investigated the formation and the removal of trihalomethanes (THMs), and the trace organic by-products by gas chromatography(GC) II gas chromatography/mass selective detector(GC/MSD). Control was used by activated carbon(AC) and water added with humic acid(HA). The results were summarized as follow : The THMs removal effect of BAC by chlorination was in lower 90 % than that of control(HA), the sorts of oxidants formed by $Cl_2$ , $O_3$ and $ClO_2$ were that $O_3$ was very fewer than $Cl_2$ or $ClO_2$, and that $ClO_2$ was fewer than $Cl_2$. The trace organic by-products were esters and phthalates etc. Based on results above, it is concluded that BAC was appeared the more desirable adsorbtion-degradation removal characteristics than that of AC.

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