• Elastomers and Composites
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• v.37 no.4
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• pp.224-233
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• 2002

This study has investigated the flame retardant properties of EPDM rubber with the addition of various flame retardants. Carbon black, stearic acid, zinc oxide cross-linking agent were mixed with EPDM rubber to produce the base rubber E0 without the addition of flame retardants. Phosphorus flame retardant Tricrecyl phosphate(TCP) was added to E0 in 0.5, 1, 1.5, 2 phr to make E1~E4 samples and red phosphorus was added in 3, 6, 9, 12 phr to make E5~E8 samples. A flame retardant of the bromine family Decabromodiphenyloxide(DBDPO), and a chlorinated paraffin retardant of the chlorine family was added to E0 in 3, 6, 9, 12 phr to make E9~E12 and E13~E16 samples, repectively. Basic physical properties such as tensile strength, tear strength and hardness were measured for all the rubber samples with various flame retardant additions. There was no substantial differences. On the other hand, Oxygen index and UL94 were measured to study flame retardant properties. From oxygen index measurements E0 sample showed a value of 23.5%, indicating the improvement of flame retardant properties. Also from UL94 measurements, it was found that addition of red phosphorus resulted in maximum flame retardant effect. It was found that increasing the amount of addition resulted in decreasing combustion rate and improving flame retardant effect regardless of the kind of flame retardant.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.3A
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• pp.341-347
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• 2008

Among coating systems used for steel bridge coatings on highway such as red lead-pigmented alkyd, chlorinated rubber, waterborne inorganic zinc, inorganic zinc/epoxy/urethane and inorganic zinc/epoxy/fluororesin, evaluation of deterioration degree and prediction of lifetime through regression analysis were carried out for coating systems widely used and grossly degraded. For evaluation of deterioration degree, 75 bridges on highway were selected, and evaluations were carried out according to point offering method regulated by Guideline of maintenance coating for steel bridges used in Korea Expressway Corporation. Lifetime prediction results showed 13.0~13.3 years for the whole nation, 11.8 years for urban and industrial region in the metropolitan area, 13.2 years for rural region except the metropolitan area, 13.5~13.7 years for chlorinated rubber coating systems, and 12.86 years for red lead-pigmented alkyd systems. For prediction of the rest life of coating, we tried to execute parallel translations of standard deterioration curve to current life and deterioration degree for both x and y axes, and it was thought that parallel translation for x axis corresponded to deterioration aspects in actual environment. Maximum and minimum equations were derived from standard deterioration equation by adding and subtracting error values deduced in regression analysis to/from each coefficient in order to establish maintenance coating criteria for overall steel bridges on highway. Whole domain was divided into 8 parts in order to predict the rest life of coating and optimum time of maintenance coating, and maintenance coating criteria for each 8 domains were presented.

• Journal of Korean Society of Steel Construction
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• v.28 no.5
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• pp.325-335
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• 2016

To predict service life of coating systems registered in Korean specifications for steel bridge coatings, field deterioration evaluation and accelerated weatherproof test were carried out, and deterioration models were drawn through regression analysis for evaluation results. For the coating systems that have not been used in field, regression analyses were carried out for the virtual evaluation results drawn by applying coordination factor to the field evaluation results for chlorinated rubber and urethane topcoat system. Service life prediction results showed that application of thermal sprayed coating (TSC) could extend service life of coatings to more than twice of general coatings.

• Carbon letters
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• v.10 no.3
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• pp.190-197
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• 2009

Various silanes, amino silane, vinyl silane, sulfur silane (TESPD), and ZS (TESPD/zinc soap complex), are added into chlorinated isobutylene-isoprene copolymer (CIIR)/soft clay/carbon black (CB) and CIIR/hard clay/CB compounds and they are investigated with respect to the vulcanization characteristics, the processability, and the mechanical properties. Comparing hard clay and soft clay filled compounds, hard clay (Suprex) filled system shows a higher die C tear than the soft clay (GK) filled one. The other properties (Mooney, extrusion torque/pressure, torque rise ($M_H-M_L$), modulus at 300%) are close to each other. Among various silanes, the ZS treated hard clay (Suprex) compound shows the highest mechanical property following hard clay(S)/vinyl silane(V) and soft clay(GK)/vinyl silane(V) compounds. The TESPD and the ZS effectively helps a formation of a strong 3-dimensional network structure between silica and CIIR via coupling reaction due to bifunctional nature of TESPD. In addition to that, the ZS added compounds show both a better processability and mechanical properties compared to the S2 ones at low concentration due to improved compatibility between zinc soap and CIIR matrix. Only the ZS added compound shows both improved processabilities (Mooney, Extrusion torque-& pressure) and improved mechanical properties (degree of crosslinking, elongation modulus, tear, and fatigue to failure counts) on both CIIR/hard clay/CB and CIIR/soft clay/CB compounds.

• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.698-703
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• 1998

The pervaporation experiments of aqueous solutions of trichloroethylene (TCE) and chlorobenzene (CB) through the silicone rubber (polydimethylsiloxane, PDMS) membrane were carried out and the effect of concentration polarization on the separation characteristics was investigated. The resistance-in-series model was used to explain the boundary layer resistance. It was clear that the concentration polarization phenomenon had a significant effect on the permeation behavior in the pervaporation separation of the trace organic chlorides from aqueous solutions. With the same membrane thickness, the permeation of TCE, which has a stronger affinity for the PDMS, appeared to be more influenced by the boundary layer resistance than that of CB. The effect of boundary layer resistance was reduced and the membrane resistance became dominant with increasing membrane thickness at a given hydrodynamic condition. The separation factor was increased to approach the intrinsic separation factor of the membrane with its thickness.