• Title/Summary/Keyword: chloride diffusion coefficient

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Evaluation of Chloride and Chemical Resistance of High Performance Mortar Mixed with Mineral Admixture (광물성 혼화재료를 혼입한 고성능 모르타르의 염해 및 화학저항성 평가)

  • Lee, Kyeo-Re;Han, Seung-Yeon;Choi, Sung-Yong;Yun, Kyong-Ku
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.5
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    • pp.618-625
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    • 2018
  • With the passing of time, exposed concrete structures are affected by a range of environmental, chemical, and physical factors. These factors seep into the concrete and have a deleterious influence compared to the initial performance. The importance of identifying and preventing further performance degradation due to the occurrence of deterioration has been greatly emphasized. In recent years, evaluations of the target life have attracted increasing interest. During the freezing-melting effect, a part of the concrete undergoes swelling and shrinking repeatedly. At these times, chloride ions present in seawater penetrate into the concrete, and accelerate the deterioration due to the corrosion of reinforced bars in the concrete structures. For that reason, concrete structures located onshore with a freezing-melting effect are more prone to this type of deterioration than inland structures. The aim of this study was to develop a high performance mortar mixed with a mineral admixture for the durability properties of concrete structures near sea water. In addition, experimental studies were carried out on the strength and durability of mortar. The mixing ratio of the silica fume and meta kaolin was 3, 7 and 10 %, respectively. Furthermore, the ultra-fine fly ash was mixed at 5, 10, 15, and 20%. The mortar specimens prepared by mixing the admixtures were subjected to a static strength test on the 1st and 28th days of age and degradation acceleration tests, such as the chloride ion penetration resistance test, sulfuric acid resistance test, and salt resistant test, were carried out at 28 days of age. The chloride diffusion coefficient was calculated from a series of rapid chloride penetration tests, and used to estimate the life time against corrosion due to chloride ion penetration according to the KCI, ACI, and FIB codes. The life time of mortar with 10% meta kaolin was the longest with a service life of approximately 470 years according to the KCI code.

Blood-Brain Barrier Experiments with Clinical Magnetic Resonance Imaging and an Immunohistochemical Study

  • Park, Jun-Woo;Kim, Hak-Jin;Song, Geun-Sung;Han, Hyung-Soo
    • Journal of Korean Neurosurgical Society
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    • v.47 no.3
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    • pp.203-209
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    • 2010
  • Objective : The purpose of study was to evaluate the feasibility of brain magnetic resonance (MR) images of the rat obtained using a 1.5T MR machine in several blood-brain barrier (BBB) experiments. Methods : Male Sprague-Dawley rats were used. MR images were obtained using a clinical 1.5T MR machine. A microcatheter was introduced via the femoral artery to the carotid artery. Normal saline (group 1, n = 4), clotted autologous blood (group 2, n = 4), triolein emulsion (group 3, n = 4), and oleic acid emulsion (group 4, n = 4) were infused into the carotid artery through a microcatheter. Conventional and diffusion-weighted images, the apparent coefficient map, perfusion-weighted images, and contrast-enhanced MR images were obtained. Brain tissue was obtained and triphenyltetrazolium chloride (TTC) staining was performed in group 2. Fluorescein isothiocyanate (FITC)-labeled dextran images and endothelial barrier antigen (EBA) studies were performed in group 4. Results : The MR images in group 1 were of good quality. The MR images in group 2 revealed typical findings of acute cerebral infarction. Perfusion defects were noted on the perfusion-weighted images. The MR images in group 3 showed vasogenic edema and contrast enhancement, representing vascular damage. The rats in group 4 had vasogenic edema on the MR images and leakage of dextran on the FITC-labeled dextran image, representing increased vascular permeability. The immune reaction was decreased on the EBA study. Conclusion : Clinical 1.5T MR images using a rat depicted many informative results in the present study. These results can be used in further researches of the BBB using combined clinical MR machines and immunohistochemical examinations.

Case Study on the Mixing Proportions of 100 Year Life Time Concrete (내구수명 100년 해양 콘크리트의 배합사례)

  • Jang, Bong-Seok;Ahn, Jeong-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.1073-1076
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    • 2008
  • This study shows some results of concrete mixing design has 100 years life time. The ratios of ternary blended cement are 4 types. the ratios of blast furnace slag cement are 3 types. In this case study, 40%, 50% and 60% replacement ratio of blast furnace slag(BSF) to OPC are used, also 35:45:20, 30:35:35, 30:40:30 and 35:40:25 ratio of OPC:BSF:FA are used. The mixing design tests include slump, air content, compressive strength and thermal properties of concrete. The compressive strength tests are executed at the age of 3, 7, 28, 56, and 91 days. The coefficient of chloride diffusion is determined by NT Build 492 method. The purpose of this study is to shows the results of case studies as the ratio of blended cement varies.

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Experimental Study on the Penetration Depth and Concentration of Corrosion Inhibitor Using Press-in Method Into the Inside of Concrete (콘크리트 내부로의 압입공법을 사용한 방청제의 침투깊이 및 농도에 관한 실험적 연구)

  • Cho, Hyeong-Kyu;Yoo, Jo-Hyeong;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.5 s.57
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    • pp.160-168
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    • 2009
  • After steel bar was corroded it removes concrete contaminated, it does steel bar corrosion protection, repairing method and corrosion inhibitor spreading method are difficult to secure corrosion protection performance. Accordingly, in this research before Research and Development to penetrate corrosion inhibitor to high pressure by steel bar position, it measures penetration depth through corrosion inhibitor high pressure penetration experiment and amount of nitrite by position and then it predicts penetration depth in accordance with water-cement ratio, pressure, pressure time and it computed water-cement ratio, pressure, pressure time to be more than 0.6 mol ratio of chloride ion and nitrite to have outstanding corrosion protection performance. As a result of experiment, water-cement ratio gives the biggest influence to penetration of corrosion inhibitor and also the more depth of specimen becomes deep, concentration of penetrated corrosion inhibitor does not equal and becomes low.

Evaluation of Durability Performance in Concrete Incorporating Low Fineness of GGBFS (3000 Grade) (저분말도 고로슬래그 미분말(3000급)을 혼입한 콘크리트의 내구성능평가)

  • Lee, Seung-Heun;Cho, Sung-Jun;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.96-102
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    • 2019
  • When GGBFS(Ground Granulated Blast Furnace Slag) with high blaine is incorporated in concrete, compressive strength in the initial period is improved, but several engineering problems arise such as heat of hydration and quality control. In this paper, compressive strength and durability performance of concrete with 3,000 Grade-low fineness slag are evaluated. Three conditions of concrete mixtures are considered considering workability, and the related durability tests are performed. Although the strength of concrete with 3,000 Grade slag is slightly lower than the OPC(Ordinary Portland Cement) concrete at the age of 28 days, but insignificant difference is observed in long-term compressive strength due to latent hydration activity. The durability performances in concrete with low fineness slag show that the resistances to carbonation and freezing/thawing action are slightly higher than those of concrete with high fineness slag, since reduced unit water content is considered in 3,000 Grade slag mixture. For the long-term age, the chloride diffusion coefficient of the 3000-grade slag mixture is reduced to 20% compared to the OPC mixture, and the excellent chloride resistance are evaluated. Compared with concrete with OPC and high fineness GGBFS, concrete with lower fineness GGBFS can keep reasonable workability and durability performance with reduced water content.

The Evaluation of Durability Performance in Mortar Curbs Containing Activated Hwangtoh (활성 황토를 혼입한 모르타르 기반 경계석의 내구성능 평가)

  • Kwon, Seung-Jun;Kim, Hyeok-Jung;Yoon, Yong-Sik
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.520-527
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    • 2020
  • Hwangtoh is the rich resource that accounts for about 15.0% of the domestic soil, and can be used as the admixture of concrete with Pozzolan characteristics if activated by rapidly freezing after burning with high temperature. In this study, the mortar curbs containing active hwangtoh were produced, based on the mixture for the mortar curbs sold on the market. The substitution rate of active hwangtoh were considered 10.0% and 25.0%, and the test items were selected to compressive and flexural strength tests, freezing/thawing resistance tests, accelerated carbonation tests, and accelerated chloride diffusion tests. In the results of the mechanical performance, it was showed that the highest strength was evaluated in OPC mixture, and the increase in strength was small by the increase of age, which was believed to be due to the fact that most of the strength in each mixture was created in three days of steam curing. The results of the freezing/thawing tests for 28 aged days showed the reduction rate of compressive strength was 85.0% or higher for all specimen, meeting the criteria presented. The accelerated carbonation tests were carried out on the specimen at 28 days of age, and the results showed that the mortar with active hwangtoh had lower carbonation resistance performance than mortar with OPC. The passed charge of each mixture was assessed in accordance with ASTM C 1202 on 28 and 91 aged days. The OPC mixture had "Low" rate and the mortar with active hwangtoh had "Moderate" rate. So it was thought that the mortar with active hwangtoh had appropriate resistance performance for chloride attack.