• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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• 1999.11b
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• pp.34-42
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• 1999

The present investigation has focused up on the study of the adsorption of three different molecular mass fractions of a polyDiMethylDiAllylAmmoniumChloride (DMDAAC) (8750(LM\ulcorner), 48000(MM\ulcorner) and 1200000(HM\ulcorner)) on bleached chemical fibres. Both kinetics of adsorption and equilibrium adsorption measurements have been conducted and each adsorption has been measured by polyelectrolyte titration. The results show that the LM\ulcorner polymer can reach all of the charges in the fibre wall whereas the MM\ulcorner and HM\ulcorner can only reach the external surfaces of the fibres. It is also shown that the kinetics of adsorption of the LMw polymer is not at all affected by the presence of a saturated layer of HMw polymer on the surface of the fibres. Finally, the results from the investigation show that it is possible to have full coverage of the external surface of the fibres by a high molecular mass polymer and a full coverage of the internal surface of the fibres with a low molecular mass polymer. This is true if the high molecular masspolymer is added first followed by addition of the low molecular masspolymer.

• Carbon letters
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• v.6 no.3
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• pp.141-147
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• 2005

The carbon sample "O", phosphoric acid-activated carbon "OP", zinc chloride-activated carbon "OZ", and two steam activated carbons "OS" and "OS2" with different burn-off of 25% and 58% respectively, were prepared from olive stones. The textural properties were determined from the results of nitrogen adsorption at 77 K and by analyzing these results through the application of different adsorption models. The chemistry of the carbon surfaces was determined from the base neutralization capacities, acid neutralization capacity and surface pH. The sorption of $Pb^{2+}$ ions on to the carbons prepared was followed under dynamic and equilibrium conditions. The differences between the values of the textural parameters were attributed to the inapplicability of some adsorption models and to the heterogeneity of the microporous carbons. The sorption of $Pb^{2+}$ ions is favored on carbon and activated carbons. However, chemically activated carbons are more effective compared with steam-activated ones. The sorption of $Pb^{2+}$ ions were related to the chemistry of the surface rather than to the textural properties.

• Journal of the Korean Electrochemical Society
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• v.11 no.3
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• pp.159-164
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• 2008

We investigated chloride ion effects on anodic dissolution of copper using potentiodynamic method, cyclic voltammtery, chronoamperometry and chronocoulometry. The anodic dissolution reaction of copper in NaCl solution under argon atmosphere is $Cu+2Cl^{-}{\rightleftharpoons}{CuCl_2}^{-}+e^-$ and chloride ion adsorption process in copper surface can be explained by Temkin isotherm.

• Journal of environmental and Sanitary engineering
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• v.10 no.1
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• pp.132-141
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• 1995

The objectives of this study was to find the effect of zinc salt treated with coconut activated carbon and the effect of humic substance. The bottle- Point technique was used in determining the Freundlich isotherm equation. The adsorptive capacity of granular activated carbon was reduced when humic substance are present. Coconut activated carbon was coated with 0.0001 N zinc chloride decreased the BET surface area but increased the adsorptive capacity more than coconut activated carbon not coated with zinc chloride. The adsorptive capacity of TCE in coconut activated carbon coated with higher concentration of zinc chloride was reduced but increased in the solution containing humic substance when the coconut activated carbon was coated with 0.01 N- zinc chloride. The zinc salt coated with coconut activated carbon did not Increase the adsorptive velocity of coconut activated carbon.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.04a
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• pp.149-154
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• 1997

In order to predict the onset of the corrosion of steel bars in the concrete, a mathematical model including the diffusion of chloride ion in aqueous phase of pores, the adsorption and desorption of chloride ions to and from the surface of solid phase of concrete, and the chemical reaction of chloride ions with solid phase was established. Finite element method was employed to carry out numerical analysis. The chlorides penetrating through the wall of concrete structure from the external environment and the chlorides contained in the concrete admixture were confirmed to be two important factors to determine the onset of corrosion of steel bars.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.35 no.2
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• pp.18-25
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• 2003

The adsorption of co-cationic dual polymer system was investigated as was the fiber dispersion stability of a paper stock suspension. Polyaluminum chloride(PAC) and polyamidoamine epichlorohy-drin(PAE) polymers were used as wet-end additives. The adsorbed amounts of PAE polymer in a wet stock were measured by using polyelectrolytic PCD titration. The sheet forming experiments were carried out in a standard handsheet machine. Fiber dispersion stability and relative retention were evaluated in terms of M/K non-uniformity index and sheet basis weight, respectively. The PAE polymer adsorption of Langmuir-isothermal type decreased with increasing PAC addition level. The combination of the two cationic polymers presumably exerts a site-blocking effect by the low molecular weight PAC which gives a partial charge neutralization at a minimum level of addition. From a thermodynamic view point of PAE adsorption, an increase in adsorption entropy and a decrease in train number suggests that the PAR polymer has an extended conformation structure that potentially leads to an enhancement of the fiber dispersion stability. This conclusion is supported by handsheet experiments that examined the PAC-PAE dual polymer effects on the sheet formation and retention.

• Carbon letters
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• v.8 no.2
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• pp.101-107
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• 2007

Activated carbons were prepared by impregnation of crushed clean date pits in concentrated solutions of phosphoric acid or zinc chloride followed by carbonization in absence of air at $600^{\circ}C$. Steam-activated carbon was prepared by gasifying $600^{\circ}C$-carbonization product at $950^{\circ}C$ to a burn-off = 50%. KOH- activated carbon was prepared by impregnating date pitscarbonization product obtained at $450^{\circ}C$ in concentrated KOH solution followed by carbonization at $840^{\circ}C$. Textural properties of these carbons were determined from nitrogen adsorption at $-196^{\circ}C$ and the chemistry of the carbon surface was investigated by determination and of the surface carbon-oxygen (C-O) groups using bases of variable strength and dilute HCl. The adsorption of endosulphan at $27^{\circ}C$ on all the carbons prepared was undertaken. Adsorption of this pesticide at 32 and $37^{\circ}C$ was also undertaken for steam-activated and KOH-activated carbons. Phosphoric acid-activated carbons and steamactivated carbons are mainly microporous and have high surface concentration of C-O groups of acidic nature. Steamactivated and KOH-activated carbons exhibited surface areas > 1000 $m^2/g$ and contain micro and non-micrpores. The adsorption of endosulphan was related to the surface area of non-micropores and was retarded by the high concentration of surface C-O groups. The thermodynamic properties indicated the feasibility of the adsorption process and the possible regeneration of the carbon for further use.

• Membrane and Water Treatment
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• v.10 no.2
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• pp.139-148
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• 2019

In this study, the removal of MB from saline solutions was evaluated by two methods by adsorption and electrodialysis; the adsorption of the mixture dye/salt on dried orange peel waste (OPW) was studied in batch method. In this study the biosorption of cationic dye by OPW was investigated as a function of initial solution pH, and initial salt (sodium chloride) concentration. The maximal dye uptake at $pH{\geq}3.6$ in the absence and in the presence of salt and the dye uptake diminished considerably in the presence of increasing concentrations of salt up to 8 g/L. The Redlich Peterson and Langmuir were the most suitable adsorption models for describing the biosorption equilibrium data of the dye both individually and in salt containing medium. As well, this work deals with the electrodialysis application to remove the dye. Synthetic solutions were used for the investigation of the main operational factors affecting the treatment performance; such as applied voltage, pH, initial dye concentration and ionic strength. The experimental results for adsorption and electrodialysis confirmed the importance of electrostatic interactions on the dye. The electrodialysis process with standard ion exchange membranes enabled efficient desalination of cationic dye solutions; there are two main factors in fouling: electrostatic interaction between cations of dyes and the fixed charged groups of the CEM, and affinity interactions.

• Journal of the Korean Wood Science and Technology
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• v.12 no.3
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• pp.15-24
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• 1984

The $3{\times}3{\times}30\;cm^3$ sized specimens of Douglas-fir(Pseudotsuga menziesii) and western hemlock(Tsuga heterophylla) in this study were soaked in four fire-retardant solutions of ammonium sulfate, monoammonium phosphate, diammonium phosphate, and aluminium chloride for 1, 24, 72, 168, and 336 hours. Subsequently they were air-dried and burned at high temperature of ca. $1,800^{\circ}C$ and for short time of 5 minutes. This study estimated the relationship between the adsorbed chemicals and the residual weight ratio or residual bending strength of these partly burned lumbers. The results were as follows; 1) In average amount of chemical adsorption, diammonium phosphate showed the largest and aluminium chloride the smallest regardless of species but monoammonium phosphate was larger in Douglas-fir than that of western hemlock. 2) The amount of chemical adsorption was larger in western hemlock than Douglas-fir on the whole. 3) The amount of chemical adsorption was increased with the increase of soaking time but the rate of increase began to decrease at 200hrs. 4) Residual weight ratios showed no difference between species but showed differences among the chemicals treated i.e. monoammonium phosphate, diammonium phosphate, ammonium sulfate and aluminium chloride in turn from the largest to the smallest. 5) MOR values showed linear increase with the increase of residual weight ratios but showed no difference in species and chemicals respectively. 6) In the relationship between amount of chemical adsorption and MOR, only diammonium phosphate showed the curve of secondary degree with significance in Douglas-fir. 7) The MOE value of burned Douglas-fir lumber increased and showed significance of 99% as the adsorbed chemical amount increased, but among the chemicals only monoammonium phosphate showed significance. The MOE value of burned western hemlock lumber didn't show significance. 8) In only Douglas-fir, the correlation between adsorbed chemical amount and work to proportional limit showed significance in only monoammonium phosphate. And in both Douglas-fir and western hemlock, the correlation between adsorbed chemicals and work to maximum load showed significance in monoammonium phosphate.

• Membrane and Water Treatment
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• v.15 no.3
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• pp.139-152
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• 2024

Mixed matrix membranes have gained significant recognition in the wastewater treatment industry for their effectiveness in removing dyes, proteins, and heavy metals from water sources. Researchers have developed an innovative technique to enhance properties of these membranes by incorporating amine-functionalized carbon nanotubes into the polymer matrix. This approach introduces amine functional groups onto the membrane surface, which are then modified with trimesoyl chloride and cyanuric chloride. The modified membranes are characterized by XPS to confirm successful bonding of amines with the trimesoyl chloride and cyanuric chloride. The surface charge of the modified membrane also plays a role in the modification process; the membrane modified with trimesoyl chloride has a negative surface charge, while the one modified with cyanuric chloride has a more positive charge. At the same acidic pH, the positive or negative charge of the mixed matrix membranes assists in enhancing the rejection of heavy metals. This results in improved antifouling properties for both modified membranes. The heavy metal rejection for all modified membranes is higher than for unmodified membranes, due to both adsorption and complexation abilities of the functional groups on the membrane surface with heavy metal ions. As the membrane surface functionalities increase through modification, the separation due to complexation also increases. The bulk morphology of the membrane remains unchanged, while roughness slightly increases due to the surface treatment.