• 한국대기환경학회지
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• 제19권5호
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• pp.595-610
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• 2003

The statistical indexes such as RMSE (Root Mean Square Error), Mean Bias error, and IOA (Index of agreement) are used to evaluate 3 Dimensional wind and temperature fields predicted by operational meteorological model RAMS (Regional Atmospheric Meteorological System) implemented in CARIS (Chemical Accident Response Information System) for the dispersion forecast of hazardous chemicals in case of the chemical accidents in Korea. The operational atmospheric model, RAMS in CARIS are designed to use GDAPS, GTS, and AWS meteorological data obtained from KMA (Korean Meteorological Administration) for the generation of 3-dimensional initial meteorological fields. The predicted meteorological variables such as wind speed, wind direction, temperature, and precipitation amount, during 19 ∼ 23, August 2002, are extracted at the nearest grid point to the meteorological monitoring sites, and validated against the observations located over the Korean peninsula. The results show that Mean bias and Root Mean Square Error are 0.9 (m/s), 1.85 (m/s) for wind speed at 10 m above the ground, respectively, and 1.45 ($^{\circ}C$), 2.82 ($^{\circ}C$) for surface temperature. Of particular interest is the distribution of forecasting error predicted by RAMS with respect to the altitude; relatively smaller error is found in the near-surface atmosphere for wind and temperature fields, while it grows larger as the altitude increases. Overall, some of the overpredictions in comparisons with the observations are detected for wind and temperature fields, whereas relatively small errors are found in the near-surface atmosphere. This discrepancies are partly attributed to the oversimplified spacing of soil, soil contents and initial temperature fields, suggesting some improvement could probably be gained if the sub-grid scale nature of moisture and temperature fields was taken into account. However, IOA values for the wind field (0.62) as well as temperature field (0.78) is greater than the 'good' value criteria (> 0.5) implied by other studies. The good value of IOA along with relatively small wind field error in the near surface atmosphere implies that, on the basis of current meteorological data for initial fields, RAMS has good potentials to be used as a operational meteorological model in predicting the urban or local scale 3-dimensional wind fields for the dispersion forecast in association with hazardous chemical releases in Korea.

• 한국산학기술학회논문지
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• 제14권5호
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• pp.2544-2549
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• 2013

고성능 고분자/클레이 나노 복합재료의 제조 과정에는 친수성을 보이는 클레이 원료 물질인 $Na^+$-MMT (sodium monmorilonite)를 친유성을 갖도록 유기화된 계면활성제로처리하여 개질하는 과정이 필수적이다. 이를 위하여 이 연구에서는 VDAC (vinylbenzyldimethyl-dodecylammonium chloride)를 간단한 화합물로부터 합성하였고 이를 이용하여 양이온 교환반응에 의하여 $Na^+$-MMT를 개질한 후 $VDA^+$-MMT를 제조하였다. 이를 스티렌과 혼합하여 in-situ 중합에 의하여 나노복합재료를 제조하였고 클레이의 분산성 및 차단특성을 연구하였다. 연구 결과 PS/$VDA^+$-MMT 나노 복합재료의 경우 클레이의 분산이 $Na^+$-MMT와 비교할 때 현저히 증가함을 확인하였고 이로 인해 유기 용매에 대한 차단 특성이 매우 우수함을 확인하였다.

• 한국대기환경학회지
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• 제24권1호
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• pp.1-15
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• 2008

Chemical Accident Response Information System (CARIS) which has been designed for the efficient emergency response of chemical accidents produces the real-time atmospheric fields through the Regional Atmospheric Modeling System, RAMS. The previous studies were emphasized that improving an initial input data had more effective results in developing prediction ability of atmospheric model. In a continuous effort to improve an initial input data, we replaced the land-use dataset using in the RAMS, which is a high resolution USGS digital data constructed in April, 1993, with the latest land-use data of the Korea Ministry of Environment over the South Korea and simulated atmospheric fields for developing a real-time prediction in dispersion of chemicals. The results showed that the new land-use data was written in a standard RAMS format and shown the modified surface characteristics and the landscape heterogeneity resulting from land-use change. In the results of sensitivity experiment we got the improved atmospheric fields and assured that it will give more reliable real-time atmospheric fields to all users of CARIS for the dispersion forecast in associated with hazardous chemical releases as well as general air pollutants.

• 한국가스학회:학술대회논문집
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• 한국가스학회 2003년도 추계학술발표회 논문집
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• pp.164-167
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• 2003

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2002년도 추계학술대회 논문집
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• pp.103-104
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• 2002

산업의 발달에 따라 국내에 유통되는 화학물질의 종류 및 취급량이 최근 급증하고 있으며 이에 비례해서 유해화학물질과 연관된 사고 사례도 매년 증가하고 있다(산업자원부, 2001). 이러한 화학사고의 체계적인 대응을 위해 국립환경연구원의 화학물질안전관리센터에서는 2002년 초부터 주요 화학 공단을 중심으로 국가차원의 실시간 화학물질 사고대응 정보시스템 (CARIS : Chemical Accident Response Information System)을 구축하여 유해화학물질을 체계적으로 관리·운영하고 있다 (국립환경 연구원, 2002). (중략)

• 한국마이크로전자및패키징학회:학술대회논문집
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• 한국마이크로전자및패키징학회 2002년도 춘계 기술심포지움 논문집
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• pp.274-278
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• 2002

The purpose of this study was to characterize the reaction of Cu surface with Cu slurry and CMP performance as a function of additives in CMP slurry. The polish rate of Cu was dependent on the kind of organic acids added in slurry. It was considered that polish rate of Cu was dependent on the concentration of carboxylates and mean particle size. When the etchant and oxidant were added in slurry, the highest removal rate and lower etch rate were measured at neutral pH. The addition of etchant, oxidant and pH adjustor played key roles of CMP ability in slurry. As the pH increased, polish rate of Cu was increased by the enhanced the mechanical effects due to effective dispersion of slurry particles. Alumina abrasives was more desirable for 1st step slurry because of high removal rate of Cu and high selectivity ratio among TaN and Cu.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2009년도 춘계학술발표대회
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• pp.14.1-14.1
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• 2009

We found a high yield synthetic route to organic-soluble metal nanoparticles in the concentrated organic phase. The organic phase contains metal salt, amines, fatty acids, nonpolar solvent, and reducing agent. Even using only generic chemicals, organic-soluble silver and copper nanoparticles could be easily obtained by this simple and rapid reaction scheme at large scale. The hydrocarbon-protected metal nanoparticles showed excellent dispersion properties and were successfully printed onto polymer substrates. The printed pattern was heated at $200^{\circ}C$, which showed very low specific electrical resistance (< 10 uOhm$\cdot$cm), sufficient for conducting line of various printable devices.

• Korean Chemical Engineering Research
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• 제58권3호
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• pp.438-449
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• 2020

본 연구는 화학 및 석유화학 플랜트 등의 장치산업에서 사업장 외부로 유해화학물질이 누출·확산되어 발생할 수 있는 배상책임 위험도에 대한 산정 방식을 개선하고자 하였다. 이를 위해 환경부 사고대비 물질(14종)에 대해 누출·확산 시뮬레이션, 화학물질 누출사고 사례 분석, 식물피해 영향 자료 분석 등을 통하여 화학물질 누출사고 배상책임 위험도와의 상관관계인자를 도출하였고, 도출된 결과를 바탕으로 화학물질 배상 책임 위험도 산정 방법을 수정·보완하였다. 14종의 화학물질의 Probit 값과 EURAM 배상책임 위험도의 상관계수는 -0.526로 나타났고, 수정된 화학물질 누출사고 배상책임 위험도와의 상관계수는 0.319로 상관성이 있는 것으로 분석되었다. 수정된 산정 방법론으로 97종에 대한 배상책임 위험도와 ERPG-2 값의 상관계수는 -0.494로 분석되었고, 이는 기존 배상책임 위험도와의 상관관계보다 약 19배 높은 상관관계를 보였고, 부식위험도 값과의 상관계수는 0.91로 분석되었다. 위험도의 증가와 감소에 영향을 미친 상관관계 인자의 표준화 회귀계수(β) 값은 Corrosion Index (0.713), ERPG-2 (0.400), NFPA_Health Index (0.068) 크기 순서로 도출되었다. 이러한 연구결과는 기존과 신규 화학물질의 합리적인 배상책임 위험도 산정이 가능하게 하고, 사업장에서 정량적인 배상책임 위험관리 지표로 활용하는데 도움이 되리라 판단된다.

• 접착 및 계면
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• 제12권4호
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• pp.117-124
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• 2011

본 연구는 보호콜로이드로 PVA를 사용한 PVAc 에멀젼 폴리머와 VAE 에멀젼 폴리머 블렌드에 관한 것으로 보호콜로이드로 사용된 PVA는 블렌드 전의 각각의 에멀젼 폴리머 필름과 블렌드 후의 필름에서도 연속상으로 존재하였다. 이는 블렌드를 구성하는 입자사이에서 뛰어난 접착력을 예상하게 한다. Tg가 서로 다른 에멀젼 폴리머 블렌드는 중요한 관심 대상이며 PVAc/VAE 에멀젼 폴리머 블렌드는 이 중 간단하면서도 또 다른 뛰어난 연구 방향을 제시하였다. 혼합 결과, PVAc 증가에 따라 신율이 저하되었고, PVAc 제조에 사용된 가소제가 혼합물의 Tg에 영향을 미쳐 PVAc 가소제의 VAE 에멀젼 폴리머으로의 이행으로 인하여 VAE 에멀젼 폴리머의 Tg를 저하시켰고, 인장강도 및 내열성, 접착력에서 두 혼합물의 상승효과가 나타났다.

• 약학회지
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• 제57권4호
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• pp.282-288
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• 2013

Zinc oxide nanoparticles (ZnONPs) are widely used in a variety of products and cosmetic products including paper, paints, plastics and sunscreen. However, information on the safety of ZnONPs are not enough and many publications suggest possible toxic effects on environmental and human health. Furthermore, physico-chemical characteristics of nanoparticles makes it hard to test toxicity using the test guidelines of chemicals adopted by regulatory bodies. In this study, stability of ZnONPs was investigated using different types of isotonic solution, which is important in the toxicity study of intravenous route. Precipitation, aggregation, size, zeta potential and morphology of ZnONPs were evaluated with different times and concentrations. Precipitation of ZnONPs were observed in ionic isotonic solution including phosphate-buffered saline, Kreb's-Ringer solution, physiological salt solution and cell culture media of DMEM (Dulbecco's Modified Eagle's Medium) with 10% fetal bovine serum. On the other hand, they were stable without precipitation in non-ionic isotonic solution such as 5% glucose and 2% glycerol, respectively, which are biocompatible for intravenous injection. The average size of ZnONPs in 5% glucose and 2% glycerol was stably maintained, which is less than 30 nm and very similar as that in water dispersion of ZnONPs, provided by the manufacturer. The stability was maintained during the experimental period of 5 days and diluted state up to 15,000 ppm. These data suggest that 5% glucose and 2% glycerol solution can be used for the vehicles of ZnONPs in the toxicity study of intravenous injection route.