• Title/Summary/Keyword: chemical-recycled

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100KW DC Arc Plasma of CVD System for Low Cost Large Area Diamond Film Deposition

  • Lu, F.X.;Zhong, G.F.;Fu, Y.L.;Wang, J.J.;Tang, W.Z.;Li, G.H.;Lo, T.L.;Zhang, Y.G.;Zang, J.M.;Pan, C.H.;Tang, C.X.;Lu, Y.P.
    • The Korean Journal of Ceramics
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    • v.2 no.4
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    • pp.216-220
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    • 1996
  • In the present paper, a new type of DC arc plasma torch is disclosed. The principles of the new magnetic and fluid dynamic controlled large orifice long discharge tunnel plasma torch is discussed. Two series of DC Plasma Jet diamond film deposition equipment have been developed. The 20kW Jet equipped with a $\Phi$70 mm orifice torch is capable of deposition diamond films at a growth rate as high as 40$\mu\textrm{m}$/h over a substrate area of $\Phi$65 mm. The 100kW high power Jet which is newly developed based on the experience of the low power model is equipped with a $\Phi$120 mm orifice torch, and is capable of depositing diamond films over a substrate area of $\Phi$110 mm at growth rate as high as 40 $\mu\textrm{m}$/h, and can be operated at gas recycling mode, which allows 95% of the gases be recycled. It is demonstrated that the new type DC plasma torch can be easily scaled up to even higher power Jet. It is estimated that even by the 100kW Jet, the cost for tool grade diamond films can be as low as less than $4/carat.

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Recycling Plan for Waste Concrete Fine Aggregate as Materials of Anti-Frost Layer and Sub-Base Layer (도로의 동상방지층 및 보조기층재로서 폐콘크리트 잔골재의 재활용 방안)

  • Lee, Dong-Wook;Yun, Jung-Mann
    • Journal of the Korean Geosynthetics Society
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    • v.11 no.3
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    • pp.19-25
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    • 2012
  • In this study, a recycling plan for waste concrete fine aggregate as fill material was researched by investigating environmental engineering properties. It is noted that the environmental influence of waste concrete fine aggregate is little since chemical level is satisfied the waste management standard. Waste concrete fine aggregate is not suitable for materials of anti-frost layer and sub-base layer since the particle-size distribution and engineering properties are not partially satisfied the quality standard. However, waste concrete fine aggregate can be recycled as materials of anti-frost layer and sub-base layer if we improve the engineering properties by mixing bigger aggregates than maximum particle size (5 mm) more than 25 percent of total weight.

Study on the Detachment of Fluorescent Whitening Agents from White Waster Papers (인쇄용지 재활용을 위한 형광증백제 탈착에 대한 기초연구)

  • Lee, Ji Young;Kim, Chul Hwan;Kim, Eun Hea;Park, Tae Ung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.2
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    • pp.5-12
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    • 2016
  • White waste papers are very important resources in the paper industry, but their use is limited because of the residual of fluorescent whitening agent (FWA). So the removal of FWAs from waste paper is an important task in the recycling process to improve the use of recycled resources. In this study, we focused on the FWAs used for surface treatments and carried out physical and chemical treatments to remove them from white waste papers. The white waste papers were disintegrated with a surfactant in different pH and temperature conditions, and then handsheets were made for the measurement of the fluorescence index, which is proportional to the amount of FWAs on papers. The effect of the flotation process on the removal of FWAs after disintegration was also investigated. The fluorescence index decreased as the disintegration time increased, but over a relatively long time, the fluorescence index increased again, which indicated the readsorption of the FWAs detached from the cellulosic fibers of the white waste papers. The lowest fluorescence index was shown when the waste papers were disintegrated with a 0.3% surfactant addition at pH 10 and at $45^{\circ}C$. However, the flotation treatment was not effective, because the flotation induced contact between the detached FWAs and the cellulosic fibers, and re-adsorption occurred.

Flocculation Effect of Alkaline Electrolyzed Water (AEW) on Harvesting of Marine Microalga Tetraselmis sp.

  • Lee, Su-Jin;Choi, Woo-Seok;Park, Gun-Hoo;Kim, Tae-Ho;Oh, Chulhong;Heo, Soo-Jin;Kang, Do-Hyung
    • Journal of Microbiology and Biotechnology
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    • v.28 no.3
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    • pp.432-438
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    • 2018
  • Microalgae hold promise as a renewable energy source for the production of biofuel, as they can convert light energy into chemical energy through photosynthesis. However, cost-efficient harvest of microalgae remains a major challenge to commercial-scale algal biofuel production. We first investigated the potential of electrolytic water as a flocculant for harvesting Tetraselmis sp. Alkaline electrolyzed water (AEW) is produced at the cathode through water electrolysis. It contains mineral ions such as $Na^+$, $K^+$, $Ca^{2+}$, and $Mg^{2+}$ that can act as flocculants. The flocculation activity with AEW was evaluated via culture density, AEW concentration, medium pH, settling time, and ionic strength analyses. The flocculation efficiency was 88.7% at 20% AEW (pH 8, 10 min) with a biomass concentration of 2 g/l. The initial biomass concentration and medium pH had significant influences on the flocculation activity of AEW. A viability test of flocculated microalgal cells was conducted using Evans blue stain, and the cells appeared intact. Furthermore, the growth rate of Tetraselmis sp. in recycled flocculation medium was similar to the growth rate in fresh F/2 medium. Our results suggested that AEW flocculation could be a very useful and affordable methodology for fresh biomass harvesting with environmentally friendly easy operation in part of the algal biofuel production process.

Decolorization of Wastewater and Collecting of Sludge from Hanji Production (한지 생산공정에서 발생하는 폐수의 탈색 및 슬러지 회수)

  • Choi, Hee-Seon;Kim, Tai-Jin
    • Analytical Science and Technology
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    • v.13 no.3
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    • pp.351-356
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    • 2000
  • The decolorization of wastewater and the collecting conditions of final sludge from hanji production were investigated. Black wastewater (50 mL) from the process cooking with NaOH could be effectively decolorized by 2.0 g of $Ca(OCl)_2$ So, if excess bleach $Ca(OCl)_2$ used in bleaching process were recycled, the decolorization of wastewater by adding less $Ca(OCl)_2$ would be successfully realized. However, the decolorization by electrolyzed oxidation was ineffective. The final sludge could be effectively collected by polymer coagulator, but the addition of $Al_2(SO_4)_3$ was required, and the pure fibrous sludge could not be collected. Therefore, surfactants such as triethanolamine and Triton X-100 were used instead of polymer coagulator. The collecting yield was obtained about 85% as good as those by polymer coagulator. When mixed surfactants were used in collecting the final sludge, $Al_2(SO_4)_3$ was not required. In addition, as the pure fibrous sludge could be collected, the effective recycling of sludges would be done.

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Effects of Rubber Chips from Used Tires on Spots Turf Ground as Soil Conditioner (Rubber chip의 경기장 지반 물리성 개선과 잔디 생육에 미치는 효과)

  • ;;;David Minner
    • Asian Journal of Turfgrass Science
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    • v.16 no.1
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    • pp.19-30
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    • 2002
  • This study was conducted to investigated the effects of rubber chips from used tires on sports turf ground as soil conditioner to improve soil physical properties. The release of heavy metal ions was detected to check the soil contamination by incorporation of recycled rubber chips with topsoil. The effects of the chips were also evaluated as topdressing material to improve surface resilience. The rate of rubber chips showed a positive relationship with soil temperature increasement. Incorporation of rubber chips increased soil temperature on surface at 2.5 cm-depth. The rates of rubber chip showed a negative relationship with ground cover rate of turfgrass in early growth season. However, after 20 weeks, treatment of 10% rubber chips at 2.5 cm-depth showed a prominent cover rate of 70% which was not significantly different with untreated control. Incorporation of rubber chips within topsoil seemed to reduce soil compaction, but the effects was not prominent on physical properties. Rubber chips did not affect chemical properties and heavy metal contamination to soil environment. Rubber chips improved resilience of the compacted ground surface as topdressing material, this effect was prominent when aerification practise was preceded.

Void ratio and Strength Properties of Porous Concrete Utilizing Rice Husk Ash and Recycled Aggregate for Planting (식생 적용을 위한 왕겨재와 순환골재를 활용한 포러스 콘크리트의 공극률 및 강도 특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Korean Journal of Agricultural Science
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    • v.33 no.2
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    • pp.167-177
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    • 2006
  • This study was performed to evaluate void ratio, compressive and flexural strength, and pH properties according to the admixture ratio of rice husk ash, aggregate size, and neutral treatment time of porous concrete with an admixture of rice husk ash produced as an agricultural by-product. The SEM results for cement mortar with a 5% rice husk ash admixture for the weight of cement formed more C-S-H hydrates due to the $SiO_2$ present in the applied rice husk ash. According to the results of the SEM test, the $SiO_2$ that was a major chemical element of rice husk ash generated a large amount of calcium hydroxide in the early stage of the hydration process of cement leading to the formation of ettringite. The void ratio of porous concrete with an admixture of rice husk ash decreased with increasing admixture ratio of rice husk ash. In addition, the void ratio of porous concrete with an admixture of rice husk ash decreased compared to porous concrete with no admixture of rice husk ash. The compressive and flexural strength of porous concrete with a 5% and 10% admixture ratio of rice husk ash slightly increased compared to concrete with no admixture of rice husk ash. The pH value of porous concrete rapidly decreased immediately after neutral treatment. Then, it gradually increased and decreased again after 14 days. Also, for neutral treatment, the pH value of porous concrete showed appropriate pH levels(less than 9.5) in all mixtures for planting at 28 curing days.

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Removal of Nutrients Using an Upflow Septic Tank(UST) - Aerobic Filter(AF) System (부패조와 호기성 여과공정을 이용한 영양염류 제거)

  • Park, Sang-Min;Jun, Hang-Bae; Bae, Jong-Hun;Park, Woo-Kyun;Park, Noh-Back
    • Korean Journal of Environmental Agriculture
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    • v.29 no.3
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    • pp.232-238
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    • 2010
  • The objective of this study was to investigate a small sewage treatment system. This system was developed to improve a nitrogen and phosphorus removal efficiency and generate less solid using upflow septic tank(UST) - aerobic filter(AF) system. The UST equipped with an aerobic filter, the filter was fed with both raw sewage and recycled effluent from the UST to induce the denitrification and solid reduction simultaneously. Overall removal efficiencies of COD and total nitrogen(TN) were above 96% and 73% at recycle ratio of 200%, respectively. Critical coagulant dose without the biochemical activity was found to be 40 mg/L. Removal efficiency of total phosphorus(TP) in influent was above 90% by chemical and biological reactions. Although the phosphorus concentration was low under the high alkalinity in raw sewage, the pH value was unchanged by the coagulant dose.

Characteristics of Asphalt Concrete using Waste Foundry Sand (주물고사 첨가 아스팔트 콘크리트의 특성에 관한 연구)

  • Kim, Kwang-Woo;Ko, Dong-Hyuk;Choi, Dong-Chon;Kim, Sung-Won;Kim, Joong-Yul
    • International Journal of Highway Engineering
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    • v.3 no.4 s.10
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    • pp.105-116
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    • 2001
  • This study was performed to evaluate the characteristics of waste foundry sand (WFS) and the asphalt mixture made of a foundry waste sand. To estimate the applicability of WFS, chemical and physical properties were measured by XRF(X-ray fluorescent), and SEM(Scanning electronic microfilm). To improve the stripping resistance of WFS asphalt mixture, anti-stripping agents (a hydrated lime and a liquid anti-stripping agent) were used. To improve tensile properties and durability of WFS asphalt concrete mixture, LDPE(low-density polyethylene) was used as an asphalt modifier Marshall mix design, indirect tensile strength, tensile strength ratio(TSR) after freezing and thawing, moisture susceptibility and wheel tracking tests were carried out to evaluate performance of WFS asphalt concrete. Comparing with conventional asphalt concrete, WFS asphalt concretes showed similar or the better qualify in mechanical properties, and satisfied all specification limits. Therefore, it Is concluded that waste foundry sand can be recycled as an asphalt pavement material.

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The Vertical Fluxes of Particles and Radionuclides in the East Sea

  • Moon, Deok-Soo;Kim, Kee-Hyun;Noh, Il
    • Journal of the korean society of oceanography
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    • v.35 no.1
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    • pp.16-33
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    • 2000
  • In order to measure the vertical fluxes of particles and reactive radionuclides such as thorium and polonium isotopes, Dunbar-type sediment traps were freely deployed at the Ulleung Basin and in warm and cold water masses around the polar front of the East Sea. We estimated the ratios of the catched (F) to the predicted $^234$Th fluxes (P) using natural tracers pair $^234$Th-$^238$U. The F/P ratios are decreased with increasing water depth. Whereas the concentrations of suspended particles are homogeneous in water column, the mass fluxes are also decreased with increasing water depth like the F/P ratios. These facts indicate that organic matters of settling particles are destructed within the euphotic layer due to decomposition. Whereas regenerations of sinking particles are negligible in the cold water mass, about 80% of them are regenerated in the warm water mass during falling of large particles. These downward mass fluxes are closely correlated with their primary productions in euphotic zone. The activities of $^234$Th, $^228$Th and $^210$Po in the sinking material were increased with water depth. Because $^234$Th steadily produced in the water column are cumulatively adsorbed on the surface of sinking particles, vertical $^234$Th fluxes were observed to increase with water depth. Therefore, these sinking particles play important roles in transporting the particle reactive elements like thorium from surface to the deep sea. The scavenging processes including adsorption and settling reactions generate radio-disequilibrium between daughter and parent nuclides in water column. The activity ratios of $^234$Th/$^238$U and $^228$Th/$^228$Ra were observed to be < 1.0 in the surface water and approached to be equilibrium below the thermocline. The extent of the deficiency of daughter nuclides compared to the parents nuclide was highly correlated with the vertical particle flux. Because most of the $^210$Po in the surface water are scavenged on a labile phase and are recycled at sub-surface depths (< 200 m), the $^210$Po are always observed to be excess activities compared to $^226$Ra in surface water.

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