• Title/Summary/Keyword: chemical-recycled

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Physical Properties of Recycled Polyester Yarns According to Recycling Methods (재생 방법에 따른 재생 폴리에스터사의 물성 변화)

  • Lee, Sun-Young;Won, Jong-Sung;Yoo, Jae-Jung;Hahm, Wan-Gyu;Lee, Seung-Goo
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.91-96
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    • 2012
  • The physical properties of recycled polyester yarns according to recycling methods were investigated. Virgin polyester draw texturized yarn(DTY), material-recycled(MR) polyester DTY and chemical-recycled(CR) polyester DTY were prepared. Surface morphology, thermal property, micro-structure and mechanical property of recycled polyester yarns were estimated. SEM-EDS analysis showed that the CR PET yarn had better crimp and more stable structure than MR PET yarn. Tm of the MR PET yarn was higher than that of the CR PET yarn. The intensity of the crystallization peak of the CR PET yarn was a little higher than that of the MR PET yarn. Tensile strength of the MR PET yarn was slightly higher than that of the CR PET yarn. Breaking elongation of the CR PET yarn was slightly higher than that of the MR PET yarn.

Experimental study on chemical activation of recycled powder as a cementitious material in mine paste backfilling

  • Liu, Yin;Lu, Chang;Zhang, Haoqiang;Li, Jinping
    • Environmental Engineering Research
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    • v.21 no.4
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    • pp.341-349
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    • 2016
  • To improve the utilization rate of construction waste as mine backfilling materials, this paper investigated the feasibility of using recycled powder as mine paste backfilling cementitious material, and studied the pozzolanic activity of recycled construction waste powder. In this study, alkali-calcium-sulfur served as the activation principle and an orthogonal test plan was performed to analyze the impact of the early strength agent, quick lime, and gypsum on the pozzolanic activity of the recycled powder. Our results indicated that in descending order, early strength agent > quick lime > gypsum affected the strength of the backfilling paste with recycled powder as a cementitious material during early phases. The strength during late phases was affected by, in descending order, quick lime > gypsum > early strength agent. Using setting time and early compressive strength as an analysis index as well as an extreme difference analysis, it was found that the optimal ratio of recycled powder cementitious material for mine paste backfilling was recycled powder:quick lime:gypsum:early strength agent at 78%:10%:8%:4%. X-ray diffraction analysis and scanning electron microscope were used to show that the hydration products of recycled powder cementitious material at the initial stages were mainly CH and ettringite. As hydration time increased, more and more recycled powder was activated. It mainly became calcium silicate hydrate, calcium aluminate hydrate, etc. In summary, recycled powder exhibited potential pozzolanic activities. When activated, it could replace cementitious materials to be used in mine backfill.

Physical Properties of Polymer Composite Recycling Recycled Aggregate (순환골재를 재활용한 폴리머 복합재료의 물성)

  • Hwang, Eui-Hwan;Jeon, Jong-Ki
    • Applied Chemistry for Engineering
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    • v.20 no.1
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    • pp.67-74
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    • 2009
  • Nowadays, recycling of recycled aggregates from the waste concrete is seriously demanded for the protection of environment and the shortage of aggregates owing to the large scale construction project. In this study, for the development of polymer composite recycling recycled aggregates from the waste concrete, twenty five specimens of the polymer composite were prepared with the five levels of replacement ratios of recycled aggregates (0, 25, 50, 75, 100%) and polymer-cement ratios (0,5, 10, 15, 20%), respectively. For the evaluation of the performance of polymer composite specimens, various physical properties such as compressive and flexural strengths, water absorption, hot water resistance, total pore volume and porosity were investigated. As a result, physical properties of polymer composite were remarkably improved with an increase of polymer cement ratios, but greatly decreased with the replacement ratios of recycled aggregates.

A STUDY ON THE CHEMICAL RECYCLING METHOD OF METAL BRACKET (금속(金屬) Bracket의 화학적(化學的) 재생처리(再生處理) 방법(方法)에 관(關)한 연구(硏究))

  • Bang, Sang-Yong;Lee, Dong-Joo
    • The korean journal of orthodontics
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    • v.20 no.1
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    • pp.103-110
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    • 1990
  • Metal brackets were recycled by variable methods for economic reason. Such recycling methods had a great effect on bracket slot width and bonding strength. Therefore, the recycling methods that don't change the properties of original bracket were suggested. In this study, debonded brackets were recycled with 30 kinds of solvents and bracket surfaces were examined by S.E.M. (Super IIIA, ISI International Scientific Instruments, Japan) and Stero Microscope (Sz-Tr, Olympus Tokyo, Japan) methods. The following results were obtained. 1. Thermosetting resin adhesives (eq. $Monolok^{(R)}$, $Concise^{(R)}$) were swelled most in sulfuric acid (assays 95%) and slightly in alcohol groups. 2. The solvent was exchanged every 24 hours during the brackets were recycled with sulfuric acid (assays 95%). As the passage of time, the adhesives were removed more clearly, and after 72 hours adhesives were nearly detached from bracket base. 3. Chemical recycled metal bracket surface showed no irregular structure by S.E.M. method.

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Characterization of Polyolefin Bumper Recycled by Chemical Removal Method using Electronic Speckle Pattern Interferometry (화학적 박리방법과 ESPI에 의한 재생된 폴리올레핀 범퍼수지의 물성평가)

  • 김현경;강기수;김경석;홍진후
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.10a
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    • pp.295-298
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    • 1997
  • Recycl ing of PP/EPR based bumper coated with polyester urethane paint has been per formed by chemical decoating method. Electronic Speckle Pattern Interferometry (ESP11 has been applied to characterize the deformation of polyolef in based bumper. In additon, physical properties and processability of recycled materials have been investigated by dynamic mechanical thermal analysis, impact test and melt flower index measurement. The results show that the deformation ratio of recycled material is higher than that of virgin one. The morphological change of EPR, degree of distribution and dispersion during the recycling process seem to be the most important factor for the deformation and the mechanical properties of recycled materials. The experimental results obtained show that ESPI is very powerful technique to study the thermal mechanical property of polyolefin bumper system.

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A Study on Synthesis and Antioxidant Recycled Rubber Mat used Waste Tire Powder (폐타이어 분말을 활용한 리사이클 고무 매트의 합성 및 항산화성에 관한 연구)

  • Kim, Ki-Jun;Lee, Joo-Youb;Park, Tae-Sul
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.3
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    • pp.345-350
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    • 2011
  • Antioxidant agent, 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane were prepared and investigated the antioxidant activity on recycled rubber mat manufactured with waste tire powder. Mechanical properties of rubber mat are influenced by many factor such as compounding ingredients and state of cure, process of rubber, and fillers. Our study aim is to investigate influence of antioxidant activities on ozone cracking and the thermal aging time. In this work, the degradation of recycled rubber mat was studied and suggested mechanism to involve two-type of degradation, thermal aging and cracking both of which can be contained antioxidant or non-antioxidant agent.

Effect of Recycled PET Fiber Reinforced Concrete on Chemical Environment (화학적 환경하에서 재생 PET섬유보강 콘크리트의 성능)

  • Jang, Chang-Il;Lee, Sang-Woo;Choi, Min-Jung;Kim, Joon-Mo;Won, Jong-Pil;Kim, Wan-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.709-712
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    • 2008
  • This study evaluated a mechanical performance of recycled polyethylene terephthalate(PET) fiber reinforced concrete on chemical environment. This study applied to three types of environmental condition including alkaline, salt, $CaCl_2$ in water solution and measured a reduction of mechanical performance of recycled PET fiber reinforced concrete for 30, 60, 90 days under chemical solutions. The mechanical performance of recycled PET fiber reinforced concrete evaluated to carried out a compressive strength test. As the result of test, it was found that the mechanical performance decreased as the exposure time to alkaline environment and indicated a excellence performance under salt, $CaCl_2$ environment conditions.

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Carbon nanotubes formation on clay and fly ash from catalytic thermal decomposition of recycled polypropylene

  • Nur A. Atikah Kamaruddin;Norzilah A. Halif;Siti A. Hussin;Mohd. N. Mazlee
    • Advances in materials Research
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    • v.13 no.3
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    • pp.173-181
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    • 2024
  • Fly ash, plastic waste, and clay are mineral materials and residues commonly found in Malaysia. In this study, these materials were fully utilized as raw materials for synthesizing carbon nanotubes (CNTs). Recycled polypropylene, previously used as a food container, served as a carbon source. Fly ash and clay were explored as potential substrates for CNTs growth. The recycled polypropylene was thermally decomposed at 900 ℃ in an inert environment for 90 minutes. Carbon atoms released during this process were deposited on fly ash and clay substrates, which had been immersed in a ferrocene solution to provide a metal catalyst for CNTs growth. The deposited products were characterized using a Scanning Electron Microscope (SEM) and X-Ray Diffraction (XRD). Morphological analysis revealed that both fly ash and clay were coated with fiber-like structures, confirmed to be CNTs based on a diffraction peak around 26° from the XRD pattern. In conclusion, clay and fly ash demonstrate the potential to be utilized as substrates for CNTs formation.

Performance Evaluation of Quality-Improved Recycled Aggregate Using Ultrasonic Wave and Chemical Neutralization Reaction (초음파 세척 및 화학적 중화반응을 이용한 품질 개선된 순환골재의 성능 평가)

  • Jay Jang-Ho Kim;Young-Jun You
    • Journal of Korean Society of Disaster and Security
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    • v.17 no.1
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    • pp.27-35
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    • 2024
  • This paper presents experimental research results to evaluate the applicability of chemical neutralization reaction and ultrasonic wave to remove cement paste and mortar attached to the surface of recycled aggregate. In order to derive optimal ultrasonic cleaning efficiency and chemical neutralization reaction, experiments were conducted using variables such as ultrasonic frequency and type of chemical solution. As a result, the optimal frequency was found to be 24 kHz, and immersion in a 15% hydrochloric acid solution for 30 minutes of stimulation showed the highest efficiency. In addition, the specific gravity, absorption rate, and wear rate of the quality-improved recycled coarse aggregate were similar to those of general aggregate and were found to satisfy all KS F 2527 standards. Therefore, it is believed that the recycled aggregate whose quality has been improved through the method proposed in this study can be used for concrete.

Study on pH Reducing Method of Recycled Fine Aggregate for Embanking or Covering (성복토용 순환잔골재의 pH 저감방법에 관한 연구)

  • Han, Min-Cheol;Han, Dongyeop
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.1
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    • pp.23-30
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    • 2017
  • The aim of the research is to suggest an economical and sustainable method of reducing pH of recycled aggregate as an embanking and a covering materials. Because of the unhydrated cement based materials on the surface of the recycled aggregate, it causes a severe problem on environment with leaked high alkali water from embankment and covering by using recycled aggregate. In this research, to reduce the pH of recycled aggregate, regarding the recycled fine aggregate, eight different methods were tested and analyzed with three different categorized: natural treatment, artificial treatment, and chemical treatment. From the results of experiment, it was considered that the most efficient method of reducing pH of recycled aggregate was the chemical treatment using acid such as $CO_2$ acceleration or monoammonium phosphate (MAP), and diammonium phosphate (DAP). Especially, using MAP and DAP, fertilizers, is the most efficient method of reducing pH with its time duration and performance.