• Title/Summary/Keyword: chemical-recycled

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A Proposal of Stress-Strain Relations Model for Recycled-PET Polymer Concrete under Uniaxial Stress (일축 하중을 받는 PET 재활용 폴리머콘크리트의 응력-변형률 모델의 제안)

  • Jo Byung-Wan;Moon Rin-Gon;Park Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.16 no.6 s.84
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    • pp.767-776
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    • 2004
  • Polymer concrete shows excellent mechanical properties and chemical resistance compared with conventional normal cement concrete. The polymer concrete is drawing a strong interest as high-performance materials in the construction industry. Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems posed by plastics and save energy. The purposed of this paper is to propose the model for the stress-strain relation of recycled-PET polymer concrete at monotonic uniaxial compression and is to investigate for the stress-strain behavior characteristics of recycled-PET polymer concrete with different variables(strength, resin contents, curing conditions, addition of silane and ages). The maximum stress and strain of recycled-PET polymer concrete was found to increase with an increase in resin content, however, it decreased beyond a particular level of resin content. A ascending and descending branch of stress-strain curve represented more sharply at high temperature curing more than normal temperature curing. Addition of silane increases compressive strength and postpeak ductility. In addition, results show that the proposed model accurately predicts the stress-strain relation of recycled-PET polymer concrete

Rheological properties and crystallization kinetics of polypropylene block copolymer with repeated extrusion

  • Sung Yu-taek;Seo Won Jin;Kim Jong Sung;Kim Woo Nyon;Kwak Dong-Hwan;Hwang Tae-Won
    • Korea-Australia Rheology Journal
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    • v.17 no.1
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    • pp.21-25
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    • 2005
  • Rheological properties and crystallization kinetics of the polypropylene (PP) block copolymer and recycled PP block copolymer were studied by advanced rheometric expansion system (ARES), differential scanning calorimetry (DSC), and optical microscopy. In the study of the dynamic rheology, it is observed that the storage modulus and loss modulus for the PP block copolymer and recycled PP block copolymer did not change with frequency. In the study of the effect of the repeated extrusion on the crystallization rate, half crystallization time of the PP samples was increased with the number of repeated extrusion in isothermal crystallization temperature ($T_c$). From the isothermal crystallization kinetics study, the crystallization rate was decreased with the increase of the number of repeated extrusion. Also, from the result of Avrami plot, the overall crystallization rate constant (K) was decreased with the increase of the number of the repeated extrusion. From the study of the optical microscopy, the size of the spherulite of the PP samples did not change significantly with the number of repeated extrusion. However, it was clearly observed that the number of the spherulite growth sites was decreased with the number of repeated extrusion. From the results of the crystallization rate, isothermal crystallization kinetics, Avrami plots, and optical microscopy, it is suggested that the crystallization rate of the PP block copolymer is decreased with the increase of the number of repeated extrusion.

A Study for Analyzing the Mechanism of Enhanced Cementitious Reactivity of Bottom Ash by Using Functional Grinding Agent (기능성 분쇄조제를 통한 건조저회의 시멘트 반응성 메커니즘 분석 연구)

  • Ahyeon Lim;Hyunuk Kang;Juhyuk Moon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.3
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    • pp.271-280
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    • 2024
  • In this study, commercially available chemical activator was utilized as a grin din g agen t for bottom ash to develop bottom ash blended cement. The hydration characteristics of the bottom ash blended cement were analyzed using X-ray diffraction and thermogravimetric analysis. In particular, the PONKCS method was employed to quantify the amorphous C-S-H and bottom ash. The use of chemical activator delayed the hydration reaction of the cement and reduced the reactivity of the bottom ash. However, appropriate delay of hydration and enhanced reaction of aluminate successfully led to the formation of a substantial amount of monocarboaluminate. Consequently, the use of chemical activator greatly improved the compressive strength of the bottom ash blended cement, resulting in the 20240713development of high-performance bottom ash blended cement.

Studies on the durability evaluation of the Recycled Cement using Waste Cementitious Powder as Raw material. (폐미분말을 주원료로한 재생시멘트의 내구성능 평가에 관한 연구)

  • Kwon, Eun-Hee;Ahn, Jae-Cheol;Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.3-4
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    • 2015
  • Environmental load reduction and sustainable development one of the study's research into the available material is discharged, remove the coarse aggregate and fine aggregate from waste concrete and utilizing the remaining cement fine powder as an alternative raw material for limestone is the main raw material of cement developing playback cement that was the purpose. Physical over existing research and chemical quality was confirmed was evaluated for durability by promoting carbonation test, research studies on the durability evaluation insignificant. As honipyul within the aggregate differential lung fine powder increases carbonation resistance performance've found that increased sharply and, S0 showed fairly similar to the OPC. Therefore, the development within the technology research to separate fine aggregate discharge fully differential and waste fine powder is determined to be the development and use of the playback durability of the cement with the carbonation levels corresponding to the OPC if made.

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Recycling of Wastepaper(Ⅷ)-Contamination of Process WAter by System Closure (고지재생연구(제 8보) -제지 공정수 폐쇄화에 따른 오여-)

  • 여성국;류정용;신종호;송봉근;오세균
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.4
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    • pp.1-7
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    • 1999
  • This study was carried out to simulate the change of various properties of recycled water when zero-discharge system was applied to a KOCC recycling process. contaminants such as chemical oxygen demand, anionic trash, and calcium hardness were gradually increased in the process water as the recycling was repeated . Especially, the increase of anionic trash and COD were closely related to the starch derived from corrugating adhesive in KOCC. Four kinds of water were compared in the preparation of handsheet to evaluate the performance of retention program. Waters used in this work were laboratory tab water, process water from Dong-II mill and the same one treated by UASB process, and closed white water prepared by KRICT. The result revealed that one the major factors fro reducing a retention power was the anioni trash accumulated in the recycled water.

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Compound waterproofing method of green roof using copper barrier sheet and recycled tire melting liquid waterproofing material that reinforced treatments are valve and glass fiber mesh. (알루미늄 판막과 유리섬유를 합지한 구리방근시트와 폐타이어 용융액상 도막방수재를 이용한 옥상녹화 복합방수공법)

  • Kim, Young chan;Cho, Il Kyu;choi, sung min;Oh, Sang Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.173-178
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    • 2008
  • This is green roof bottom system which composed by aluminum valve and glass fiber together as major reinforcement, so the cooper sheet can have root proof, and using recycled tire gel-type membrane waterproofing system which dost not contains VOCs. The copper sheet reduce the plants' root growing, so it helpes to maintain the waterproofing layer and stability of root proofing. Gel type membrane waterproofing system can do waterproofing, stress dispersion, and reducing leakage expansion. So those two materials can help each other to make green roof bottom layer would have the stability and durability.

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Deinking of Computer Printed Out and White Ledger (백상지 고지의 탈묵)

  • 한신호
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.1
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    • pp.48-56
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    • 2000
  • The objective of this study was to investigate the enzymatic deinking technology. Office recycled papers such as computer printed out(CPO) and white ledger(WL) were used in the evaluation of four different deinking conditions ; alkaline deinking , neutral deinking and enzymatic deinking at alkaline and neutral pH. Filltering pads were prepared after flotation deinking to measure brighteness gain and ink removal efficiency. Three different surfactants were also used in the evaluation of deinking efficiency including surface chemical properties by measuring foam height and stability, surface tension and cloud point of views. The results indicated that the neutral deinking method with enzyme and surfactant addition showed highest deinking efficiency of office recycled papers.

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A Study on the Life Cycle Environmental Impact Comparison of Recycled Polyol of Waste Polyurethane with Virgin Polyol (폐 우레탄 재생 폴리올과 신재 폴리올의 전과정 환경영향 비교에 관한 연구)

  • Yang, Inmog;Kim, Youngsil;Lee, Daesoo;Cho, Bong Gyoo;Ahn, Joong Woo
    • Clean Technology
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    • v.21 no.3
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    • pp.171-177
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    • 2015
  • A life cycle assessment (LCA) methodology was employed to evaluate environmental impact of recycled polyol from polyurethane in an R&D stage and to suggest future direction for improvement of environmental performance of the recycling technology. The comparison result shows between recycled polyol in the developing stage and in the anticipated mass production with virgin polyol production that environmental impact of recycled polyol of the developing stage and the anticipated mass production level correspond to 93%, 60% of that of virgin polyol, respectively. The LCA result identifies improvement areas of reducing environmental impact in recycling polyols, that is, use of alkylene oxide and steam. In the future research, this must be taken into consideration for better performance of recycling technology.

Thermal Property of the Roof Green Unit System Using Artificial Lightweight Soil Recycled with Bottom Ash (바텀애시 재활용 인공토양 적용 옥상녹화 유니트 시스템의 열특성)

  • Yoo, Jong-Su;Lee, Jong-Chan;Oh, Chang-Won
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.49-55
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    • 2020
  • In this study, the surface temperature of the roof green system using ALSRBA(Artificial Lightweight Soil Recycled with Bottom Ash) was measured in each season and the thermal property of the ALSRBA was investigated. As a result, it was certified that ALSBRA has superior thermal property than the usual artificial soil. In addition, The daily temperature range in each season was measured to investigate the thermal isolation property of EUS(Existing Unit System) and DUS(Developed Unit System). The result showed that the thermal isolation effect of EUS was lower than that of SPSS(Site-Place-Soil System), but thermal isolation effect of DUS was similar to that of SPSS because DUS has continuous ALSBRA layer by removing unit barrier.

Effects of recycling on the biomechanical characteristics of retrieved orthodontic miniscrews

  • Yun, Soon-Dong;Choi, Sung-Hwan;Cha, Jung-Yul;Yu, Hyung-Seog;Kim, Kwang-Mahn;Kim, Jin;Hwang, Chung-Ju
    • The korean journal of orthodontics
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    • v.47 no.4
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    • pp.238-247
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    • 2017
  • Objective: The aim of this study was to compare recycled and unused orthodontic miniscrews to determine the feasibility of reuse. The comparisons included both miniscrews with machined surfaces (MS), and those with etched surfaces (ES). Methods: Retrieved MS and ES were further divided into three subgroups according to the assigned recycling procedure: group A, air-water spray; group B, mechanical cleaning; and group C, mechanical and chemical cleaning. Unused screws were used as controls. Scanning electron microscopy, energy-dispersive X-ray spectrometry, insertion time and maximum insertion torque measurements in artificial bone, and biological responses in the form of periotest values (PTV), bone-implant contact ratio (BIC), and bone volume ratio (BV) were assessed. Results: Morphological changes after recycling mainly occurred at the screw tip, and the cortical bone penetration success rate of recycled screws was lower than that of unused screws. Retrieved ES needed more thorough cleaning than retrieved MS to produce a surface composition similar to that of unused screws. There were no significant differences in PTV or BIC between recycled and unused screws, while the BV of the former was significantly lower than that of the latter (p < 0.05). Conclusions: These results indicate that reuse of recycled orthodontic miniscrews may not be feasible from the biomechanical aspect.