• 제목/요약/키워드: chemical solution

검색결과 6,721건 처리시간 0.037초

Equilibrium and Hydriding Characteristics of Metal Hydride Chemical-Treated and Compacted in Pellet (화성처리 및 성형화에 따른 금속수소화물의 평형특성 및 수소흡장거동)

  • Park, C.K.;Cho, T.H.
    • Transactions of the Korean hydrogen and new energy society
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    • 제5권1호
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    • pp.9-17
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    • 1994
  • Activation behavior, hydriding rate and disintegration were studied for a compact in pellet form and hydrogen storage alloy particles treated with newly developed inorganic solution. Cylindrical disc of 12.95mm diameter and of 7.1mm thickness was prepared by compressing(8ton) a mixture of $MmNi_{4.5}Al_{0.47}$ and PTFE. Chemical treatment of particles with 1mol of solution was performed at room temperature for several hours until the pH of solution did not change. Chemical treatment made much accelerated activation without any incubation period which generally exists in the untreated alloys and the hydriding reaction rate after full activation also was improved.

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Encapsulation of Whole Cell CGTase from Concentrated Broth Solution

  • Park, Joong-Kon;Sohn, Joon-Hyuk;Park, Hyung-Woo;Lee, Yong-Hyun
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제6권1호
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    • pp.67-71
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    • 2001
  • Most of the Cyclodextrin glucanotransferase (Gtases) which have been produced from B. subtilis were found to be excreted from the cells during cultivation. Immobilized whole cell CGTase from B. subtilis was prepared by encapsulating the broth solution which had been concentrated ten times with a rotary vacuum evaporator. Cyclization activity of CGTase was reduced by about 10% during the concentrating process, however, its transglycosylation activity, to convert xylitol to glucosyl-xylitol, using dextrin as glucosyl donor, increased by a factor of 3 or 5.

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Chemical Solution Deposition 방법으로 증착된 $Bi_{0.8}A_{0.2}FeO_3$ (A=Pb, Co) 박막의 자기적 특성에 대한 연구

  • Cha, Jeong-Ok;An, Jeong-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.245-245
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    • 2011
  • $BiFeO_3$ (BFO)박막에 전위금속 Pb와 Co를 각각 치환환 박막을 chemical solution deposition 방법으로 Pt/Ti/SiO2/Si(100) 기판위에 증착하였다. Bi 자리에 Pb와 Co를 20 at.% 치환하였으며, 치환된 $Bi_{0.8}Pb_{0.2}FeO_3$ (BPFO), $Bi_{0.8}Co_{0.2}FeO_3$ (BCFO) 박막의 구조적, 자기적 특성 변화를 BFO 박막과 비교하여 조사하였다. XRD 패턴을 분석한 결과 BPFO, BCFO 박막들은 모두 rhombohedrally distorted perovskite 구조였으며 불순물인 pyrochlore 상이 약하게 관측되었다. 치환이 이루어진 BPFO, BCFO 박막들의 자기 이력곡선은 안정된 포화곡선을 나타냈으며 BFO의 포화값(5 emu/$cm^3$)에 비해 크게 증가된 55 emu/$cm^3$, 35 emu/$cm^3$의 값을 나타냈다. 또한 보자력장(coercive field, Hc)값도 BFO의 500 Oe보다 크게 증가된 1,200 Oe, 800 Oe의 값을 보였다.

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A Fundamental Study for the Automatic Control System in Greenhouse Using Microcomputer(I) (마이크로컴퓨터에 의한 시설재배의 자동화에 관한 기초연구(I))

  • Kim, C.S.;Kim, J.H.
    • Journal of Biosystems Engineering
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    • 제19권2호
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    • pp.99-111
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    • 1994
  • Automatic control system using microcomputer that have been studied in greenhouse, however, it was very difficult operation with success due to handicap for a various conditions and cultivated plants. This study was performed in order to develop of the basic program and hardware system for automatic control in greenhouse, such as automatic supplying of water, liquefied fertilizer solution and chemical solution. The results were summarized as follows. 1. The program for soil moisture control used by the switch type tensiometer was well operated. 2. The proximity switch was applied as well to water level control but it was very expensive, so low-priced sensor has to be developed. 3. The water meter was not excellent for mixing control of liquefied fertilizer, chemical and water, so water meter for only agricalture has to be developed. 4. Interface system for this study was suited to the developed controller. 5. Automatic control system to supply for water, liquefied fertilizer and chemical solution that was well operated as a fundamental study for product of controller.

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Preparation of Polymer Composites Containing Gold Nanonetworks Using an Amphiphilic Poly(oxyethylene) Brush

  • Cha, Sang-Ho;Kim, Jong-Uk;Lee, Jong-Chan
    • Macromolecular Research
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    • 제16권8호
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    • pp.711-716
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    • 2008
  • We synthesized gold nanonetwork using the amphiphilic polymer brush, poly(oxyethylene) containing decyltri(oxyethylene)thiomethyl ($C_{10}H_{21}(OCH_2CH_2)_3SCH_2-$) side groups, as a stabilizer and/or a template. When tetrabutylammonium borohydride solution in THF was added to a mixture solution of the polymer and $LiAuCl_4$ in THF, 0-D gold nanomaterials were obtained. However, when an aqueous solution of sodium borohydride was added, gold nanonetworks were synthesized. The composites composed of polymer/0-D gold nanomaterials and polymer/gold nanonetworks showed electrical conductivities of ${\sim}10^{-9}$ and ${\sim}10^{-3}S/cm$, respectively, which indicated that the gold nanonetworks increased the electrical conductivity.

Luminescent properties of a new yellow phosphor $CaBaSiS_4:Eu^{2+}$ synthesized by an advanced chemical solution method

  • Ohara, Keishiro;Petrykin, Valery;Tezuka, Satoko;Kakihana, Masato
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1274-1275
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    • 2009
  • We report on preparation of $CaBaSiS_4:Eu^{2+}$ material by an advanced chemical solution method and fluorescent properties of the new material. The emission spectrum of $CaBaSiS_4:Eu^{2+}$ has the main peak centered at 598 nm, with the corresponding excitation maximum at around 420 nm. The strongest emission intensity of this material approached 96% compared to one of the best commercially available YAG:$Ce^{3+}$ phosphor.

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Zn$_2SiO_4$ : Mn Phosphor Particles Prepared by Spray Pyrolysis Process

  • Kang, Yun-Chan;Park, Hee-Dong;Lim, Mi-Ae
    • Journal of Information Display
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    • 제2권4호
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    • pp.57-62
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    • 2001
  • Green-emitting $Zn_2SiO_4$:Mn phosphor particles having a spherical shape and high luminescence intensities under VUV were prepared by spray pyrolysis process under severe preparation conditions. The type of precursor solutions affected the morphology and luminescence characteristics of the prepared particles. The particles prepared from the clear solution by laboratory-scale process had spherical shape and dense morphology, while the particles prepared from the severe preparation conditions had rough surface and collapsed structure. However, the particles prepared from the colloidal solution utilizing fumed silica were spherical in shape and filled morphology at the severe preparation conditions of high flow rate of carrier gas, high concentration of solution, and large reactor size. The prepared $Zn_2SiO_4$:Mn phosphor particles with complete spherical shape had higher photoluminescence intensity than that of the commercial product prepared by solid state reaction.

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A Study on the Determination of Ionic and Molecular Weight of Dissolved Substance by Dialysis Method (Ⅲ). Effects of the Outer Solution Volume and the Dialyzing Temperature on Dialysis (透析法에 依한 이온量 및 分子量의 決定에 關한 硏究 (第三報). 外部液量 및 透析溫度가 透析에 미치는 影響)

  • Shin, Yun-Kyoung;Rhee Jhun
    • Journal of the Korean Chemical Society
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    • 제18권2호
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    • pp.138-142
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    • 1974
  • In a series of investigation of dialysis conditions at which the dialysis coefficient can be expressed as a constant, accumulation limits of the diffusing particles in the outer solution where the accumulation effect to the dialysis may be negligible were studied for various volume size of the outer solution. Dependence of the dialysis coefficient on the dialyzing temperature was also studied.

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