• Title/Summary/Keyword: chemical shrinkage

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A Study on the Hydration Ratio and Autogenous Shrinkage of Low Water/cement Ratio Paste (저물시멘트비 페이스트의 시멘트수화율 및 자기수축에 관한 연구)

  • Hyeon, Cheol
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.385-390
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    • 2002
  • Autogenous shrinkage of concrete has been defined as decrease in volume due to hydration cement, not due to other causes such as evaporation, temperature change and external load and so on. For ordinary concretes, autogenous shrinkage is so little compared to the other deformations that it has been dignored. It has recently been proved, however, that autogenous shrinkage considerably increase with decrease in water to cement ratio. And it has been reported that cracking can be caused by autogenous shrinkage, when high- strength concretes were used. In this study, we propose an analytical system to represent autogenous shrinkage in cement paste in order to control crack due to autogenous shrinkage. The system is composed with the hydration model and pore structure model. Contrary to the usual assumption of uniform properties in the hydration progress, the hydration model to refine Tomosawa's represents the situation that inner and outer products are made in cement paste. The pore structure model is based upon the physical phenomenon of ion diffusion in cement paste and chemical phenomenon of hydration in cement particle. The proposed model can predict the pore volume ratio and the pore structure in cement paste under variable environmental conditions satisfactorily The autogenous shrinkage prdiction system with regard to pore structure development and hydration at early ages for different mix-proportions shows a reasonable agreement with the experimental data.

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Effects of Risering Design and Chemical Composition on Formation of Shrinkage Cavity in Gray Cast Iron (회주철의 수축결함생성에 미치는 주조방안 및 화학조성의 영향)

  • Yu, Sung-Kon
    • Korean Journal of Materials Research
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    • v.13 no.5
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    • pp.297-302
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    • 2003
  • The effects of risering design and alloying element on the formation of defects such as external depression, primary and secondary shrinkage cavity in gray cast iron were investigated. Two types of risering design for the cylindrically step-wise specimen, No. 1(progressive solidification) and No. 2(directional solidification) risering designs, were prepared and five different alloy compositions were casted. In the No. 1 risering design, external depression or primary shrinkage cavity due to liquid contraction was observed in all the specimens from ISO 150 to ISO 350. The primary shrinkage cavity was located right under the top surface or connected to the top surface, and was characterized by smooth surface. Its size increased with an increase in ISO number. However, neither secondary shrinkage cavity nor swollen surface was observed in all the castings. In the No.2 risering design, neither primary shrinkage cavity nor secondary shrinkage cavity was observed in all the specimens due to proper risering design. A swollen surface was also not observed in all the castings with the application of pep-set mold.

Drying Shrinkage of High-Strength Concrete (고강도 콘크리트의 건조수축)

  • 임준영;정승호;이회근;이광명
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.437-442
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    • 2002
  • Drying shrinkage is the decrease in the volume of a concrete element when it loses moisture by evaporating. Because of low water/binder ratio(W/B) and the use of chemical and mineral admixtures for high-strength concrete, the evolutions of moisture and the rate of cement hydration in high- strength concrete are significantly different from those in normal strength concrete. In this study, the drying shrinkage of high-strength concrete with and without fly ash was measured up to the age of 200 days. From the experimental test results, it was observed that the drying shrinkage decreased as the W/B decreased. As the W/B is lowered from 0.50 to 0.27, the difference of drying shrinkage between the fly ash concrete and the ordinary concrete is gradually increased.

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Prediction Model on Autogenous Shrinkage of High Performance Concrete (고성능 콘크리트의 자기수축 예측모델에 관한 연구)

  • Yoo, Sung-Won;Soh, Yang-Sub;Cho, Min-Jung;Koh, Kyung-Taek;Jung, Sang-Hwa
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.3
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    • pp.97-105
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    • 2006
  • The autogenous shrinkage of high-performance concrete is important in that it can lead the early cracks in concrete structures. The purpose of the present study is to explore the autogenous shrinkage of high-performance concrete with admixture and to derive a realistic equation to estimate the autogenous shrinkage model of that. For this purpose, comprehensive experimental program has been set up to observe the autogenous shrinkage for various test series. Major test variables were the type and contents of admixture and water-cement ratio is fixed with 30%. The autogenous shrinkage of HPC with fly ash slightly decreased than that of OPC concrete, but the use of blast furnace slag increased the autogenous shrinkage. Also, the autogenous shrinkage of HPC is found to decrease with increasing shrinkage reduction agent and expansive additive. A prediction equation to estimate the autogenous shrinkage of HPC with admixture was derived and proposed in this study. The proposed equation show reasonably good correlation with test data on autogenous shrinkage of HPC with mineral and chemical admixture.

Shrinkage and Durability Characteristics of Latex Modified Repair Mortar for Agricultural Concrete Structures (농업용 콘크리트 구조물용 라텍스개질 보수용 모르타르의 수축 및 내구성능 평가)

  • Won, Jong-Pil;Lee, Jae-Young;Park, Chan-Gi;Park, Seong-Gi;Kim, Wan-Young
    • Journal of The Korean Society of Agricultural Engineers
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    • v.49 no.5
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    • pp.23-30
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    • 2007
  • This research was to evaluate the shrinkage and durability performance of latex modified repair mortar and to improve the service lift of the agricultural concrete structures. The shrinkage characteristics of the repair material creates the delamination of repair materials and existing concrete. It may reduce the service life of structures. Also the reduction of durability performance of the repair materials induces the destruction of the repaired concrete structures at early stage. In this research, plastic and drying shrinkage, thermal expansion coefficient for shrinkage properties, durability performance, permeability, repeated freezing and thawing, and resistance of chemical solution test were performed. Test results showed that the latex modified repair mortar indicated the shrinkage amount which the delamination does not happen, and the latex modified repair mortar appeared excellent long-term durability performance which can increase the service life.

Research of Shrinkage Phenomenon on Metal Insert Injection Molded Parts (금속인서트 사출성형품의 수축현상에 관한 연구)

  • Jeong, Y.D.;Kim, Y.S.;Kim, I.K.;Jung, H.C.
    • Journal of Power System Engineering
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    • v.2 no.1
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    • pp.80-85
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    • 1998
  • Engineering plastics have been magnified its usability due to its outstanding mechanic al, electrical and chemical properties, for example, in the area of computer, electricity, electronics, automobile, camera industry. In recent, automobile speedometer system is changing from manual operation to motor operation. All plastic gears inserted by metal shaft are used In motor operated speedometer system. Therefore, in this research, experimental investigation of the shrinkage phenomenon was executed according to various inserted depth and injection conditions. In experiments, the inserted depth was controlled as 30% and 90% of the total thickness of the plastic gear. The main parameters of injection process were selected as injection pressure, holding pressure, melt temperature, injection rate. As main results, free shrinkage rate of the test part is increased about 4 times to restricted shrinkage rate and shrinkage phenomenon against all injection conditions have a trivial effect on the test parts as conventional parts.

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A Study on the Quality Properties of the Expansive For Dry-Shrinkage Compensation of the Floor Mortar (온돌바닥 모르터의 건조수축보상을 위한 팽창제의 품질특성 연구)

  • 이웅종;이종열;정연식;이순기;정성철
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.155-160
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    • 2000
  • In this paper, we investigated quality properties for the expansive of the CaO-$CaSO_4$ family which used to compensate dry-shrinkage in the floor mortar of On-Dol heating System. This experimental study established the mix condition with quantity of the expansive and is to investigate the relativity between the compress strength and the length change and the relativity between the chemical properties and the length change with the analysis of the physical and chemical properties. As a result of the study, the expansive is controlled by more the CaO than the $CaSO_4$. The relativity between the compress strength and the length change is expressed by exponential function, showing that if the expansive performance is increased, the compress strength is decreased. And the relativity between the chemical properties and the length change is only relative the quantity of the F-CaO among the chemical properties, is expressed by the second order function, showing that if the F-CaO is increased, the expansive performance is increased.

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Characteristics of Dental Restorative Composite Resins Prepared from 2,2-bis- [4- (2-hydroxy-3-rnethacryloyloxy propoxy) phenyl] propane Derivatives and Spiro Orthocarbonate (2,2-비스[4-(2-하이드록시-3-메타크릴로일옥시프로폭시)페닐] 프로판 유도체와 스파이로 오쏘카보네이트가 포함된 치아 수복재의 특성)

  • Kim Yong;Lee Juyeon;Park Kwangyong;Kim Chang Keun;Kim Ohyoung
    • Polymer(Korea)
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    • v.28 no.5
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    • pp.426-432
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    • 2004
  • To reduce volumetric shrinkage of the commercially available polymeric dental composite during curing reaction, (2,2-bis [4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane) (bis -GMA) derivatives, i.e., (2,2-bis[3-methyl, 4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propan) (DMBis-GMA) and (2,2-his [3,5-dimethyl ,4- (2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane) (TMBis-GMA) were synthesized and then new dental composite resin composed of Bis-GMA derivatives, diluent, spiro orthocarbonate (SOC), and inorganic filler was produced. Among the Bis-GMA derivative/Bis-GMA derivative/diluent mixtures, Bis-GMA/ TMBis-GMA/TEGDMA mixture exhibited the lowest volumetric shrinkage. Volumetric shrinkage of this mixture was further reduced by adding SOC. Volumtric shrinkage of dental composite prepared from commercially available resin monomer mixture was $2.5\%$, while that prepared from resin monomer mixture having minimum volumetric shrinkage was reduced to $0.7\%$. Mechanical strength of this dental composite was nearly the same with that of commercial products but the time required for the curing reaction was retarded.

Drying Shrinkage Characteristics of the Concrete Incorporated Shrinkage Reducing Agent According to Mixed Proportion of Concrete (콘크리트 배합조건에 따른 수축저감제의 건조수축 특성)

  • Kim, Young-Sun;Kim, Kwang-Ki;Park, Soon-Jeon;Kim, Jung-Sun
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.3
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    • pp.245-252
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    • 2017
  • Recently, structures such as large retailers, outlets and warehouses have been increasing in accordance with changes in consumption patterns. Since these structures include ultra-flat slab members, they are thoroughly managed to control slab cracking by the plastic and drying shrinkage. In order to control the cracking of the slab member, a chemical crack reduction method is used. In particular, the use of the shrinkage reducing agent has been examined. However, domestic research results are limited. In this study, the shrinkage properties of concrete using shrinkage reducing agent and the drying shrinkage properties according to the mixing factors were investigated. The performance of domestic shrinkage reducing agent was appeared similar to that of overseas high-grade shrinkage reducing agent. As the shrinkage reducing agent usage increased, the drying shrinkage reduction effect increased. At the age of 100 days, the dry shrinkage rate of specimen with the shrinkage reducing agent of 1.5%was shown about half that of the specimen without the shrinkage reducing agent. The shrinkage reducing agent was gound to have no specific performance change for the use of the admixture.

Evaluation on the shrinkage crack of concrete with crack self-healing agent (균열 자기치유형 혼화재 적용 콘크리트의 수축균열 평가)

  • Hong, Seok-Beom;Yoo, Jo-Hyeong;Kim, Woo-Jae
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.82-83
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    • 2014
  • Concrete with self-healing admixture can reduce the crack width by using a compound for chemical reaction with incoming water and carbon dioxide through the crack. Also, concrete with self-healing admixtures can reduce early-age shrinkage crack by using a inorganic expansive agent. In this research, we perform the basic workability test and compressive test. Also, We measure the drying shrinkage of concrete specimen. Finally, we make mock-up (3m X 3m X 0.23m) and monitor the crack width and length for 3 months.

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