• Korean Chemical Engineering Research
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• v.50 no.2
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• pp.217-222
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• 2012

The synthesis of dimethyl carbonate(DMC) is a promising reaction for the use of naturally abundant carbon dioxide. DMC has gained considerable interest owing to its versatile chemical reactivity and unique properties such as high oxygen content, low toxicity, and excellent biodegradability. In this study, the synthesis of DMC through the transesterification of ethylene carbonate(EC) with methanol was investigated by using ionic liquid and metal oxide catalysts. The screening test of different catalysts revealed that choline hydroxide ([Choline][OH]) and 1-n-butyl-3-methyl imidazolium hydroxide([BMIm][OH]) had better catalytic performance than metal salts catalysts such as MgO, ZnO and CaO. The effects of reaction parameters such as reaction temperature, MeOH/EC mole ratio, and carbon dioxide pressure on the reactivity of [Choline][OH] catalyst were discussed. High temperature and high MeOH/EC mole ratio were favorable for high conversion of EC. However, the yield of DMC showed a maximum when carbon dioxide pressure was 1.34 MPa, and then it decreased for higher carbon dioxide pressure. Zinc chloride($ZnCl_2$) was used as co-catalyst with the ionic liquid catalyst. The mixed catalyst showed a synergy effect on the EC conversion and DMC yield probably due to the acid-base properties of the catalysts.

• Elastomers and Composites
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• v.39 no.1
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• pp.71-76
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• 2004

4,4'-Methylenebis(2-chloroaniline)(MOCA) has been widely used as a crosslinking agent, but classified as a toxic chemical. Thus, its use will be limited in the near future. In this research, polyurethane coating films were prepared using 1,3-propanediolbis(4-aminobenzoate)(PDBA) as an alternative to MOCA. The base part was prepared by melting MOCA or PDBA in polyoxypropylene($M_n$=2000), followed by the addition of the various additives. The NCO-terminated toluene diisocyanate prepolymer was used as a curing agent. The polyurethane coating films were prepared by mixing the base part with the curing agent in an appropriate ratio at room temperature. The polyurethane coatings prepared using PDBA exhibited higher initial viscosity, but much longer pot lift, compared to those prepared using MOCA under the same conditions, due to lower reactivity of PDBA. The tensile strength and tear strength of the coating films were much weaker. However, the pot life, tensile strength, elongation, and tear strength of the coating films, prepared using PDBA in the presence of an increased amount of Pb(II)-octoate, were close to those of the coating films prepared using MOCA. Thus, it was concluded that PDBA can substitute MOCA in the preparation of polyurethane coatings as long as the reactivity of PDBA is enhanced using appropriate amounts of the catalyst or other appropriate catalyst.

• Journal of the Korean Society of Safety
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• v.33 no.5
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• pp.42-50
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• 2018

The Chemical Controls Act strictly regulates for the chemical companies to establish sufficient space between the liquid chemical tank and dike, but facilities already installed suffer from the space shortage between the tank and dike. Installing leakage preventing plates on the dike is considered as one of the economic solutions that can alleviate the space deficiency. However, there is no technical and reasonable criterion for the safety evaluation of the leakage preventing plate on the dike. In order to address this problem, we provide generalized and verified calculating equations that give maximum height and horizontal distance of leakage trajectories. Through the proposed equations, proper heights of the leakage preventing plates on the dike can be easily determined. In this study, new calculating methods are also developed to determine the impact force of the liquid to the leakage preventing plates. In addition, we performed the reactivity experiments between four corrosive liquid chemicals and two stainless steel materials that are candidate substances for the construction of the leakage preventing plate. The results of this study is expected to be applicable as a guideline in the design of safe dike and its leakage preventing plates.

• Journal of the Korean Chemical Society
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• v.56 no.4
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• pp.406-415
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• 2012

The corrosion inhibition of copper-nickel alloy by Ethylenediamine (EDA) and Diethylenetriamine (DETA) in 1.5M HCl has been investigated by weight loss technique at different temperatures. Maximum value of inhibitor efficiency was 75% at $35^{\circ}C$ and 0.2 M inhibitor concentration EDA, while the lower value was 4% at $35^{\circ}C$ and 0.01 M inhibitor concentration DETA. Two mathematical models were used to represent the corrosion rate data, second order polynomial model and exponential model respectively. Nonlinear regression analysis showed that the first model was better than the second model with high correlation coefficient. The reactivity of studied inhibitors was analyzed through theoretical calculations based on density functional theory (DFT). The results showed that the reactive sites were located on the nitrogen (N1, N2 and N4) atoms.

• Journal of Sensor Science and Technology
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• v.33 no.3
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• pp.139-146
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• 2024

Surface-enhanced Raman scattering (SERS) enables the detection of various types of π-conjugated biological and chemical molecules owing to its exceptional sensitivity in obtaining unique spectra, offering nondestructive classification capabilities for target analytes. Herein, we demonstrate an innovative strategy that provides significant machine learning (ML)-enabled predictive SERS platforms through surface-engineered graphene via complementary hybridization with Au nanoparticles (NPs). The hybridized Au NPs/graphene SERS platforms showed exceptional sensitivity (10^-7 M) due to the collaborative strong correlation between the localized electromagnetic effect and the enhanced chemical bonding reactivity. The chemical and physical properties of the demonstrated SERS platform were systematically investigated using microscopy and spectroscopic analysis. Furthermore, an innovative strategy employing ML is proposed to predict various analytes based on a featured Raman spectral database. Using a customized data-preprocessing algorithm, the feature data for ML were extracted from the Raman peak characteristic information, such as intensity, position, and width, from the SERS spectrum data. Additionally, sophisticated evaluations of various types of ML classification models were conducted using k-fold cross-validation (k = 5), showing 99% prediction accuracy.

• Elastomers and Composites
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• v.59 no.3
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• pp.108-120
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• 2024

Due to its unique physical, mechanical, and chemical properties, hydroxyl-terminated polybutadiene (HTPB) is an essential telechelic polymer that is used and applicable in areas ranging from automotive to aerospace and coatings industries. It is a key precursor in polyurethane chemistry and is celebrated for its versatility and ability to undergo various post-polymerization modifications to meet specific industrial needs. This review focuses on the sophisticated methodologies employed to enhance the stability and functionality of HTPB through targeted chemical modifications. Representative techniques include hydrogenation, which suppresses the oxidation susceptibility of polymers by saturating weak double bonds, and epoxidation, which introduces epoxy groups that increase the reactivity and compatibility with polar additives. These modifications not only preserve the inherent attributes of HTPB, they also amplify their utility across a spectrum of applications, from aerospace to automotive industries, where enhanced material performance is critical. This study outlines the challenges in modifying HTPB, discusses the chemical strategies employed, and showcases the improved performance characteristics of the resulting polymers, thus providing a comprehensive overview of the current advancements and future potential of HTPB utilization.

• Journal of the Korean Ceramic Society
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• v.35 no.9
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• pp.899-904
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• 1998

Interface reaction between LSMC and YSZ is discussed with chemical composition of LSMC. The reac-tivity between LSMC and YSZ increased with increasing Co amount and A-site deficient perovskite is very effective on reducing reactivity. The (La0.8Sr0.2)xMn0.8Co0.2O3 (X=0.9-1) composition is not reactive with YSZ in experimental range. The electrode reaction reaction resistance increases due to reaction product.

• Proceedings of the Korean Vacuum Society Conference
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• 2009.02a
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• pp.225.2-225.2
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• 2009

• Archives of Pharmacal Research
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• v.24 no.5
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• pp.377-384
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• 2001

The reaction of either Digitoxin or Digoxin with cyanoacetic acid hydrazide gave the hydrazone derivatives 3a and 3b respectively. The reactivity of the latter products towards chemical reagents was studied to give heterocyclic derivatives with potential biological activities.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2006.05a
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• pp.282-287
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• 2006