• Title/Summary/Keyword: chemical modifying

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The Synthesis of Crystalline-Size Controlled Organic Pigment by Microwave Energy (마이크로파 에너지에 의해 결정 크기가 조절된 유기 안료의 합성)

  • 정기석;고진필;박상보;박찬영;민성기;권종호;오인환;박성수
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.609-616
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    • 2001
  • The application of microwave technology to synthesis of polymer in solvent media has been shown by the synthesis of copper phthalocyanine (CUPc). The increase of synthetic yield-was demonstrated successfully in this study. A power variable microwave synthetic system has been developed with modifying cavity of domestic microwave oven and attaching microwave power controller. The properties of the specimen synthesized at various condition under the conventional thermal processing and microwave processing has been characterized by the means of chemical analysis, X-ray diffractometry (XRD), scanning electron microscopy (SEM), and particle size analysis (PSA).

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Numerical Analysis on Letdown System Performance Test for YGN 3

  • Seo, Ho-Taek;Sohn, Suk-Whun;Seo, Jong-Tae;Boo, Jung-Sook
    • Nuclear Engineering and Technology
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    • v.29 no.2
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    • pp.158-166
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    • 1997
  • Integrated performance test of Chemical and Volume Control System was successfully performed in 1994. However, an extensive effort to correct hardware and software problems in the letdown line was required mainly due to the lack of adequate simulation code to predict the test accurately. Although the LTC computer code was used during the YGN 3'||'&'||'4 NSSS design process, the code can not satisfactorily predict the test due to it insufficient letdown line modeling. This study developed a numerical model to simulate the letdown test by modifying the current LTC code, and then verified the model by comparing with the test data. The comparison shows that the modified LTC computer code can predict the transient behavior of letdown system lese very well. Especially, the model was verified to be able to predict the "Stiction (composition of stick and friction)" phenomena which caused instantaneous fluctuations in the letdown backpressure and flowrate. Therefore, it is concluded that the modified LTC computer code with the ability of calculating the "Stiction" phenomena will be very useful for future plant design and test predictions.predictions.

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Respiration Characteristics of Rough Rice (벼의 호흡 특성)

  • 김동철;김의웅;금동혁
    • Journal of Biosystems Engineering
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    • v.23 no.4
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    • pp.335-342
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    • 1998
  • The objectives of this study were to evaluate respiration characteristics and develop empirical respiratory rate equations for short gain rough rice. The carbon dioxide concentrations generated from mush rice at four level temperatures(10, 20, 30, 4$0^{\circ}C$) and 4 level moisture contents(17.2, 21.5, 25.9, 31.6%, d.b.) were measured by gas chromatography. The respiratory rates' increased exponentially with gain temperature and also with moisture content The relationship between respiratory rate and gain temperature fitted the Arrehenius' and Core's equations very well. Two empirical respiratory rate equations were presented as a function of gain temperature and moisture content. The values of determination coefficient for the developed respiratory rate equations were 0.999, and the result of t-test showed that there were no significant differences between predicted and measured respiratory rates on significance level of 1%. Therefore, it appeared that respiratory rates predicted by the respiratory rate equations agreed well with measured values. An equation for predicting dry matter losses of rough rice during storage was presented by modifying the respiratory rate equations based on chemical reaction of decomposition of carbohydrate.

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Catalytic Activity of DNA-Pt Complex

  • Matsuoka, Yuki;Kojima, Toshinori;Higuchi, Akon
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.253-253
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    • 2006
  • DNA has not been played the role as a biocatalyst in evolutionary history, although RNA and protein function as a biocatalyst. DNA double helix structure is believed to be impossible to form intricate active enzymatic sites. In addition, the chemical stability of DNA prevents the ability from self-modifying reactions. However, recent development of DNA engineering enables to create artificial enzymatic ability of DNA (deoxyribozyme) such as RNA cleavage and DNA modification. We investigated optimal conditions for enzymatic activity of DNA-Pt complex, and compared it with that of horse radish peroxidase. We report here that base sequence of DNA, pH and temperature affect the enzymatic activity of DNA-Pt complex.

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A Study for Chemical Resistance of Polymer Cement Concrete Using Tailing (폐석 미분말을 혼입한 폴리머 시멘트 콘크리트의 내약품성에 관한 연구)

  • 전철수;연규석;이윤수;이필호
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.355-360
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    • 1999
  • Polymer cement is made by the modifying ordinary cement concrete with polymer additive. Until now polymer cement concrete is not used for the structural member, but it is growing to be considered as developing uses such as a waterproof of roof slab, the structural member for protecting corrosion, and a road pavement. The plymer cement concrete, being used for those uses, is superior to the cement concrete against the inorganic, organic acid, salt of acetic acid and organic solvents generally. In this paper, the polymer cement concrete was made by the ratio of 1:1 of sands and tailing in fine aggregate in order to solve the environmental pollution which causes the social problem by the tailing, It was measured for the compressive strength, flexural strength, and chemicals resistance was tested by dealing with 10% HCI, 20% NaOH and 10% NaCl aqueous solution.

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Inhibition of Purine Nucleoside Phosphorylase (PNP) in Micrococcus luteus by Phenylglyoxal

  • Choi, Hye-Seon
    • Journal of Microbiology
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    • v.34 no.3
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    • pp.270-273
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    • 1996
  • Micrococcus luteus purine nucleoside phosphorylase (PNP) has been purified and characterized. The physical and kinetic properties have been described previously. Chemical modification of the enzyme was attempted to gain insight on the active site. The enzyme was inactivated in a time-dependent manner by the arginine- specific modifying reagent phenylglyoxal. There was a linear relationship between the observed rate of inactivation and the phenylglyoxal concentration. At 30 $^{\circ}C$ the bimolecular rate constant for the modification was 0.015 $min^{-1}mM^{-1}$ in 50 mM $NaHCO_3$ buffer, pH 7.5. The plot of logk versus log phenylglyoxal concentration was a strainght line with a slope value of 0.9, indicating that modification of one arginine residue was needed to inactivate the enzyme. Preincubation with saturated solutions of substrates protected the enzyme from inhibition of phenylglyoxal, indicating that reactions with phenylglyoxal were directed at arginyl residues essential for the catalytic functioning of the enzyme.

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An Analytic study on the bond of the contact surface in CFT tubular column (중심축하중을 받는 CFT 합성기둥의 접촉면 부착에 관한 해석적 연구)

  • Ye, Sang-Min;Lee, Soo-Young;Kim, Yun-Tae;Park, Seoug-Moo
    • Proceeding of KASS Symposium
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    • 2005.05a
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    • pp.205-212
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    • 2005
  • In order for utilization of the concrete filled tubular, It Is necessary to scrutinize interfacial characteristics between heterogeneous materials, and be performed to various analytical studies on the composite structure. In this paper, this analytic study is carried on using ABAQUS Package/ Version 5.8-1, and the variables aye the relations between the coefficient of friction and the contact pressure for analyzing the behavior on the contact surface, through modifying the analytic methods and improving some problems. It is used to subdivided analytical methods in this research which categorize into four regions and can obtain closer effect for the bond behavior. Four categories compose of the chemical bond and mechanical bond legions replaced the full-interaction before yielding, and the pure friction and moving-down regions after yielding.

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Synthesis of new black pigment; Carbon black pigment capsulated into the meso-pore of silica as black pigment in cosmetic

  • Jang, Hye-In;Lee, Kyung-Chul;Park, Jong-Eul;Lyoo, Hee-Chang
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.308-312
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    • 2003
  • Recently the trend of new materials development is extensively and very actively progressing in the study of physical and chemical characteristics developing a totally new material along with the study field of recently discovered material modifying physically and chemically characteristics. Among these fields of studies, one method to improve adaptation of inorganic material is the study of mesoporous materials. The most general way to synthesize mesoporous materials is to mold the very systematical mesopore into a corpuscle by using templates(omitted)

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Control of Encapsulation Efficiency and Initial Burst in Polymeric Microparticle Systems

  • Yeo, Yeon;Park, Ki-Nam
    • Archives of Pharmacal Research
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    • v.27 no.1
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    • pp.1-12
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    • 2004
  • Initial burst is one of the major challenges in protein-encapsulated microparticle systems. Since protein release during the initial stage depends mostly on the diffusional escape of the protein, major approaches to prevent the initial burst have focused on efficient encapsulation of the protein within the microparticles. For this reason, control of encapsulation efficiency and the extent of initial burst are based on common formulation parameters. The present article provides a literature review of the formulation parameters that are known to influence the two properties in the emulsion-solvent evaporation/extraction method. Physical and chemical properties of encapsulating polymers, solvent systems, polymer-drug interactions, and properties of the continuous phase are some of the influential variables. Most parameters affect encapsulation efficiency and initial burst by modifying solidification rate of the dispersed phase. In order to prevent many unfavorable events such as pore formation, drug loss, and drug migration that occur while the dispersed phase is in the semi-solid state, it is important to understand and optimize these variables.

Trends of Green Policies of Biogas Renewable Technology using POME in Malaysia (말레이시아 팜오일폐수 POME(Palm Oil Mill Effluent)를 이용한 바이오가스 신재생에너지기술 그린정책 동향)

  • Park, Young Gyu
    • Journal of Korea Society of Waste Management
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    • v.35 no.7
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    • pp.571-586
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    • 2018
  • The Malaysian biogas upgrading technologies and policies were examined. In Malaysia, the regulation of palm oil mill effluent (POME) has been enforced to reduce the biochemical oxygen demand to 20 ppm and the biogas capture in the palm oil mills have been recently enforced for renewable energy. A huge amount of organic waste is produced from POME, and 80 million tons from palm oil trees, every year. Due to the renewable energy trends, the Malaysian government is modifying the use of biogases as fuels in favor of their conversion into compressed natural gas (CNG) and other chemicals; various green policies are being promoted because of many advantages of the organic substances. The Korean policies for biogas are a good model for exporting environmental plants after upgrading the digestion and purification technologies. Therefore, this article introduces the current status of POME and biogas production in Malaysia, it could encourage creating a new market for biomethane.