• 제목/요약/키워드: chemical method

검색결과 12,579건 처리시간 0.043초

A Practical Method for Identification of Nonlinear Chemical Processes by use of Volterra Kernel Model

  • Numata, Motoki;Kashiwagi, Hiroshi;Harada, Hiroshi
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1999년도 제14차 학술회의논문집
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    • pp.145-148
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    • 1999
  • It is known that Volterra kernel models can represent a wide variety of nonlinear chemical processes. Also, it is necessary for Volterra model identification to excite the process to be identified with a signal having wide range of frequency spectrum and high enough amplitude of input signals. Kashiwagi[4 ∼ 7] has recently shown a method for measuring Volterra kernels up to third order using pseudorandom M-sequence signals. However, in practice, since it is not always possible to apply such input sequences to the actual chemical plants. Even when we can apply such a pseudorandom signal to the process, it takes much time to obtain higher order Volterra kernels. Considering these problems, the authors propose here a new method for practical identification of Volterra kernels by use of approximate open differential equation (ODE) model and simple plant test. Simulation results are shown for verifying the usefulness of our method of identification of nonlinear chemical processes.

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화학무삼투백색자견이 사조에 미치는 영향 (Relationship silk reelability with nonpermeative cocoon cooking after chemical treatment)

  • 최병희;유시환
    • 한국잠사곤충학회지
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    • 제5권
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    • pp.43-46
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    • 1965
  • 본 연구는 우리나라의 원료견을 화학적으로 처리하여 무삼투 상색자견을 함으로서 생사소출량을 증대시키는 데 목적으로 하였든 바 다음 결과를 얻었다. 1. 본 연구목적을 달성하기 위하여 Serisol 해서촉진제를 창안하였다. 2. 본 해서촉진제로 생사량비율에서 0.4%의 증가를 보았다. 3. 본제는 무삼투자견을 효과적으로 하였다. 4. 본제를 사용한 생사의 마디성적은 좋은 결과이었다. 5. 본제를 사용한 생사의 기타 생사품위에 악영향이 없었다. 6. 본제는 2000배로 희석할 때 가장 그 성적이 좋았다.

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장기성능 평가를 위한 토목섬유 화학저항성 시험 고찰 (Consideration of Geosynthetics Chemical Resistance Test for Long-Term Performance Evaluation)

  • 전한용;장연수;공학봉
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2009년도 춘계 학술발표회
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    • pp.222-232
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    • 2009
  • In this study, the real site test conditions were considered and applied to suggest the improved test method for geosynthetics chemical resistance. For this, index and performance tests were done to specify and regulate the more approached test method. Accelerated model by Arrhenius equation was applied to interpretate the experimental data. Through analysis and comparison the overall experimental results, we could suggest the possibility and setup the advanced chemical resistance test method for geosynthetics.

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황색종 cyclic 건조엽의 화학성분 특성 (Effect of cyclic Change of Wet Bulb Temperature During Yellowing Stage on Chemical Properties of Flue-Cured Tobacco)

  • 이철환;진정의;한철수
    • 한국연초학회지
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    • 제20권1호
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    • pp.19-25
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    • 1998
  • The bulk curing experiment to the improve the quality of flue-cured leaves were carried out to evaluate relationship between cyclic curing and conventional curing method. We studied the effect of the cyclic change of wet bulb temperature at the yellowing stage of flue curing on chemical properties of cured leaves. The wet bulb temperature was automatically controlled between preset high($38^{\circ}C$) and low point ($35^{\circ}C$) everyone hour cyclically during 12 hours after starting luring. As a result, the acceleration of the increase in the chemical properties of cured leaves were observed. As to the chemical properties, there was decreased in citric acid, increased in malic acid of the nonvolatile organic acids and all higher fatty acids content of leaves cured by this method compared with in that of conventional curing method, while a major chemical compounds in relation to aromatic essence of cigarette smoke in essential oil components of lured leaves was mostly higher in this method than those of conventional ones, and it was evaluated that there was decreased in CO, TPM, Tar, and $CO_2$ content of the cigarette smoke comparing to the conventional luring method.

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제조방법에 따른 TiO2의 광촉매 특성 분석 (Photocatalytic Properties of TiO2 According to Manufacturing Method)

  • 이홍주;박유강;이승환;박정훈
    • Korean Chemical Engineering Research
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    • 제56권2호
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    • pp.156-161
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    • 2018
  • 염소법과 졸-겔법으로 $TiO_2$ 광촉매 분말을 제조하였다. 제조방법 및 조건에 따라 촉매의 결정상 형태(아나타제와 루타일)와 비표면적이 변화하는 것을 알 수 있었다. TTIP-sol로 제조한 광촉매가 염소법이나 TBOT-sol로 제조한 광촉매에 비해 methylene blue (MB) 분해 특성이 더 높았으며, 수용액상의 90% 이상의 MB를 제거할 수 있었다. 실험 결과를 통해 $TiO_2$ 광촉매는 단일 아나타제상와 큰 비표면적을 가지면 유기물 분해 특성을 향상될 수 있는 것을 확인하였다.

Preparation of Metal Film by Spin Coating Method

  • Kim, Hak-Ju;Lee, Jung-Ho;Sohn, Il-Hyun;Oh, Myoung-Hwan;Lee, Kwan-Yong
    • 한국유변학회:학술대회논문집
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    • 한국유변학회 2001년도 Australian-Korean Rheology Conference 2001
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    • pp.156.5-156
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    • 2001
  • (No abstract, see full-text)

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화학반응을 수반하는 극초음속 희박류 유동의 직접모사법 개발 (A DSMC Technique for the Analysis of Chemical Reactions in Hypersonic Rarefied Flows)

  • 정찬홍;윤성준
    • 한국전산유체공학회지
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    • 제4권3호
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    • pp.63-70
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    • 1999
  • A Direct simulation Monte-Carlo (DSMC) code is developed, which employs the Monte-Carlo statistical sampling technique to investigate hypersonic rarefied gas flows accompanying chemical reactions. The DSMC method is a numerical simulation technique for analyzing the Boltzmann equation by modeling a real gas flow using a representative set of molecules. Due to the limitations in computational requirements. the present method is applied to a flow around a simple two-dimensional object in exit velocity of 7.6 km/sec at an altitude of 90 km. For the calculation of chemical reactions an air model with five species (O₂, N₂, O, N, NO) and 19 chemical reactions is employed. The simulated result showed various rarefaction effects in the hypersonic flow with chemical reactions.

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연소법 전처리에 의한 고분자 물질 중 중금속의 분석 (Analysis of heavy metal in polymer materials by combustion ICP-AES Method)

  • 임헌성;이보름;이석근
    • 분석과학
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    • 제23권6호
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    • pp.615-618
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    • 2010
  • An oxygen bomb combustion procedure were studied for determination of heavy metal in polymer materials such as polyvinyl chloride and polypropylene by ICP-AES. This method is proposed as a rapid and simple sample preparation for decomposition of polymer containing certified contents of the analytes by teflon coated oxygen bomb combustion using different absorbing solution. The recoveries of metal were found to be 30~102% from absorbed solution by ICP-AES method using polypropylene certified reference material(PP CRM-As, Ba, Cd, Hg, Pb, Zn). The recoveries of metal using PVC CRM(Cd, Hg, Pb) was found to be 45 ~101% with same procedures.

Facile Route to Laterally Graded Nanotemplate

  • Kim, Tae-Hyeong;Lee, Mi-Sun;Jung, Seung-Ho;Jeong, Soo-Hwan
    • Bulletin of the Korean Chemical Society
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    • 제30권5호
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    • pp.1131-1134
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    • 2009
  • Preparation of graded materials displaying gradients of desired properties is one of the important issues and less-developed areas in materials chemistry. For the first time we demonstrate facile control of porosity and length in the pores of AAO template in lateral directions by controlled dipping method. To demonstrate the versatility of the proposed method, laterally graded silica nanotubes are also prepared by using the laterally graded AAO templates. The method demonstrated here will open numerous possibilities for obtaining a variety of graded materials with lateral gradients of catalytic, electrochemical, mechanical and optical properties on the nanoscale.