• Title/Summary/Keyword: chemical hazard

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Introduction of Globally Harmonized System for Agrochemical Products (농약제품을 위한 GHS 제도 도입)

  • Jeong, Sang-Hee;Park, Cheol-Beom;Han, Bum-Seok;Kang, Chang-Soo;Jeong, Mi-Hye;Sung, Ha-Jung
    • The Korean Journal of Pesticide Science
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    • v.15 no.2
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    • pp.201-207
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    • 2011
  • The use of chemical products to enhance and improve life is a widespread worldwide practice. In spite of the benefits of these products, there is the potential of chemicals for adverse effects to people or the environment. The globally harmonized system (GHS) of classifying and labeling chemicals that was recommended by the United Nations in 2003, has been introduced globally since 2008. Compare to the classification criteria of agricultural formulations today, classification criteria of GHS is different partly. One pictogram is removed and 3 pictograms are introduced newly. The classification criteria of GHS will be changed preferentially and implemented gradationally to hazard products.

A Study on Workers' Risk-Aware Smart Bands System in Explosive Areas (폭발위험지역 근로자 위험 인지형 스마트밴드시스템에 대한 연구)

  • Lee, Byong-Kwon
    • Journal of Internet of Things and Convergence
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    • v.5 no.2
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    • pp.73-79
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    • 2019
  • Research is underway on services and systems that provide real-time alerts for suffocating gases and potentially explosive materials, but currently smart bend type services are lacking. This study supports real-time identification of explosion hazards due to static electricity in the workplace and immediate elimination of accident occurrence factors, real-time monitoring of worker status and workplace hazards (oxygen, hazardous chemical concentration), and immediate warning and data in case of danger. We propose a method of establishing an accident prevention system through analysis. In this way, various accidents that may occur in industrial sites are monitored using IoT-based intelligent sensor nodes, wireless network technology, data processing middleware, and integrated control system, and real-time risk information at the industrial sites is prevented and accidents are prevented. By supporting a safe working environment, the company can significantly reduce costs compared to post-procurement costs.

Thermodynamic Analysis of Vapor Explosion Phenomena (증기폭발 현상의 열역학적 해석)

  • Bang, Kwang-Hyun
    • Nuclear Engineering and Technology
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    • v.25 no.2
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    • pp.265-275
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    • 1993
  • A vapor explosion has been a concern in nuclear reactor safety due to its potential for a destructive mechanical energy release. In order to properly assess the hazard of a vapor explosion, it is necessary to accurately estimate the conversion efficiency of the thermal energy to mechanical energy. In the absence of a complete model to determine the explosive energy yield, one may have to rely on a simpler upper bound estimate such as a thermodynamic model. This paper discusses various thermodynamic models and presents a clarification of each model in their mathematical formulation and the thermodynamic work conversion. It is shown that the work release in the shock adiabatic model of Board and Hall is essentially equal to that of Hicks-Menzies thermodynamic model. The effect of coolant void fraction on the explosion efficiency is also predicted based on these thermodynamic models. Finally, the Hicks-Menzies model is modified to account for the chemical reaction between a metallic fuel and water and the resultant effects on the explosion expansion work are discussed.

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A Study on the Criteria for Selection of Permitted Standard Substances in the Occupational Safety and Health Act in Korea (산업안전보건법상 허용기준 설정대상 유해인자 선정기준 마련에 관한 연구)

  • Lee, Junghyun;Hahm, Miran;Lee, Eun Jung;Lee, Kwon Seob;Hong, Mun Ki;Byeon, Sang-Hoon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.27 no.2
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    • pp.97-104
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    • 2017
  • Objectives: This study aims to suggest definitions in accordance with the purpose of the permissible limit system in order to suggest criteria for substances with permissible exposure limits and expanded candidate substances under the Occupational Safety and Health Act in Korea. Methods: The occupational safety and health related acts from six countries were researched, including from Korea. To understand the health hazards of substances with permissible exposure limits, health hazards were prioritized for 211 substances through working environment measurement on the basis of KOSHA's preceding research. Results: To suggest criteria for substances with permissible exposure limits and expanded candidate substances, definitions were suggested in accordance with the purpose of the permissible limit system. Based on the health hazard priorities for the working environment, selection criteria were identified. Conclusions: Three suggestions for substances with permissible exposure limits were proposed including substances where occurred serious health hazards such as carcinogenicity, germ cell mutagenicity, and reproductive toxicity to workers.

The research regarding the energy storage device which applies the carbon nanotube (탄소나노튜브를 활용한 에너지 저장 소자에 관한 연구)

  • Kim, Do-Hwan;Kang, Soon-Duk
    • The Journal of Information Technology
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    • v.10 no.2
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    • pp.37-45
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    • 2007
  • The multiple-ability which the structure and the physical properties which the carbon or scull tube are unique show the applicability is superior in the plane indication element which is an indispensability of information communications apparatus, the stubbornness memory element, 2nd change of air and the rough copy dosage [khay] plaque seater, the hydrogen store material and the chemical sensor back and it has the possibility which will pass over the limit which the element of existing has. from the present paper it compared in the steel and only 10 the boat it did and it analyzed against an energy storage space voluntary application and developmental apply the carbon or scull tube trend in order about under researching the effective energy storage element it could be appeared, the technique of the strong carbon nano tube. 1. The hazard which embodies the energy storage element which uses the carbon or scull tube it follows in the function which stands and CNT of the structure which is various is necessary. 2. CNT fabrications of each one must precede possible not only must be each Cabinet conference circumstances quality gain and loss. 3. The structural control of syntheses, length controls, diameter controls and the metal - CNT junction control backs of quality CNT must precede. Applies the hereafter carbon or the scull tube in the various element with the primary preceding base technique for the structural plan technique of the carbon or scull tube to be certainly established, it does, secondarily the various element functional control technique which uses the carbon or scull tube is researched and will do.

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Safety Monitoring of a Processing Plant for Preparing Raw Oysters Crassostrea gigas for Consumption (생식용 굴(Crassostrea gigas) 작업장의 위생안전성에 대한 모니터링)

  • Kang, Kyung Tae;Park, Sun Young;Choi, Jong-Duck;Kim, Min Joo;Heu, Min Soo;Kim, Jin-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.50 no.2
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    • pp.120-129
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    • 2017
  • This study assessed the safety of raw oysters Crassostrea gigas for consumption during processing in a processing plant. Bacterial contamination (e.g., viable cell counts, coliform groups, Escherichia. coli and pathogenic bacteria) and chemical contamination (e.g., heavy metals and shellfish toxins) were measured on raw oysters, a processing equipment, employees and work areas. No total mercury, lead, paralytic shellfish poison, diarrheic shellfish poison or norovirus was detected in any post-harvested oyster samples. However, the cadmium level ranged from 0.1-0.2 mg/kg. The viable cell count, E. coli and coliform group levels in post-harvested oysters ranged from 4.00-4.54 log CFU/g, ND-210 MPN/100 g and 110-410 MPN/100 g, respectively. The viable contaminating cell counts on employees, equipment and work areas were in the range of $0.90-3.46log\;CFU/100cm^2$. Airborne bacteria in the work areas ranged from 0.60 to 1.81 log CFU/plate/15 min. Thus, no significant health risks were detected in the processing plant.

Investigation of Hazards from Onions and Their Cultivation Areas to Establish a Good Agricultural Practices (GAP) Model (Good agricultural practices 모델 개발을 위한 양파 및 생산 환경에서의 위해요소 조사)

  • Choi, Young-Dong;Lee, Chae-Won;Kim, Jeong-Sook;Chung, Duck-Hwa;Shim, Won-Bo
    • Korean Journal of Food Science and Technology
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    • v.45 no.6
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    • pp.785-790
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    • 2013
  • The purpose of this study was to investigate the hazards from onions and their cultivation areas. A total of 32 samples were collected from onion farms and tested for biological (sanitary indicators, and pathogenic bacteria and fungi) and chemical (heavy metals and pesticide residues) hazards. Aerobic bacteria and coliforms were detected at a level of 0.2-7.1 log CFU/g (or mL) in the soil and agricultural water, 1.6-3.6 log CFU/g on surface of the onion, 0.0-6.0 log CFU/hand (or $cm^2$) on the workers' hands, clothes, and gloves, and 4.7 log $CFU/cm^2$ on the onion bags. Fungi were detected at a level of 0.0-5.0 log CFU/g (or mL, hand, or 100 $cm^2$) in all the samples. Staphylococcus aureus was detected at a level of 1.2 log CFU/hand on the workers' hands, the detection level of Bacillus cereus was up to 4.8 log CFU/g in the soil. However, Escherichia coli (and in particular strain O157:H7), Listeria monocytogenes, and Salmonella spp. were not detected. Although heavy metals were detected in the environment (in soil and agricultural water) and pesticide residues were detected in onion, the levels were lower than the regulation limits.

Prediction of Heavy Metal Content in Compost Using Near-infrared Reflectance Spectroscopy

  • Ko, H.J.;Choi, H.L.;Park, H.S.;Lee, H.W.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.12
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    • pp.1736-1740
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    • 2004
  • Since the application of relatively high levels of heavy metals in the compost poses a potential hazard to plants and animals, the content of heavy metals in the compost with animal manure is important to know if it is as a fertilizer. Measurement of heavy metals content in the compost by chemical methods usually requires numerous reagents, skilled labor and expensive analytical equipment. The objective of this study, therefore, was to explore the application of near-infrared reflectance spectroscopy (NIRS), a nondestructive, cost-effective and rapid method, for the prediction of heavy metals contents in compost. One hundred and seventy two diverse compost samples were collected from forty-seven compost facilities located along the Han river in Korea, and were analyzed for Cr, As, Cd, Cu, Zn and Pb levels using inductively coupled plasma spectrometry. The samples were scanned using a Foss NIRSystem Model 6500 scanning monochromator from 400 to 2,500 nm at 2 nm intervals. The modified partial least squares (MPLS), the partial least squares (PLS) and the principal component regression (PCR) analysis were applied to develop the most reliable calibration model, between the NIR spectral data and the sample sets for calibration. The best fit calibration model for measurement of heavy metals content in compost, MPLS, was used to validate calibration equations with a similar sample set (n=30). Coefficient of simple correlation (r) and standard error of prediction (SEP) were Cr (0.82, 3.13 ppm), As (0.71, 3.74 ppm), Cd (0.76, 0.26 ppm), Cu (0.88, 26.47 ppm), Zn (0.84, 52.84 ppm) and Pb (0.60, 2.85 ppm), respectively. This study showed that NIRS is a feasible analytical method for prediction of heavy metals contents in compost.

Altered Gene Profiles using KISTCHIP-400 in MCF-7 cells after Exposure to Di(2-ethylhexyl) Phthalate (DEHP) and Dibutyl Phthalate (DBP)

  • Yun, Hye-Jung;Kim, Youn-Jung;Kim, Eun-Young;Ryu, Jae-Chun
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.10a
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    • pp.174-174
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    • 2003
  • There are many synthetic chemicals, such as di(2-ethylhexyl) phthalate (DEHP) and dibutyl phthalate (DBP), used in chemical reaction processes in industry. The establishment of toxicity and detection of synthetic chemicals that may pose a genetic hazard in our enviornment is subjects of great concern at present DEHP, a ubiquitous phthalate plasticizer, induces a wide range of developmental and reproductive toxicities in mammals. DEHP belongs to the large diverse class of peroxisome proliferator compounds, which include herbicides, hypolipidemic drugs. DBP is a plasticizer used to products containing nitrocellulose, polyvinyl acetate, and polyvinyl chloride such as food wraps and blood bags. DBP is also used in cosmetics as a solvent and fixative for perfumes, a suspension agent for solids, an antifoamer, a skin emollient, and hair spray The present study was performed to examine patterns of gene expression in MCF-7 cells following DEHP and DBP exposure. Changes in gene expression were determined by microarray analysis using KISTCHIP-400 including 401 endocrine related genes based on public database and research papers. Of the genes analysis, we determined that genes detected by array showed a 2-fold or greater change in their expression level(increase or decrease). The results of this study demonstrate that a number of genes were differentially expressed in MCF-7 cells but these changes were not significant. Therefore, we keep going this study using microarray analysis and future studies will examine changes of gene expression on time-course and does treatment in variable cell lines.

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A study on the needs to improve Korea abattoir's critical control point of HACCP system

  • Kim, Seongjoon;Choi, Kwanghoon;Myung, Donghoon;Chung, Hangsung;Kim, Sukwon;Choe, Nonghoon
    • Korean Journal of Veterinary Research
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    • v.60 no.3
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    • pp.105-108
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    • 2020
  • These days abattoirs' hygiene of Korea is regulated by Hazzard Analysis Critical Control Point (HACCP). Although 20 years have been left since first HACCP was adjusted in Korea, 12% of abattoirs got inconsistence on evaluations. Food poisoning caused by bacteria feces like pathogenic Escherichia coli and Salmonella has not decreased. These bacteria on meat cross-contaminate at the abattoir. Therefore, field verification of abattoir's critical control point (CCP) and experiments to find alternative ways of the CCP were conducted. The aerobic bacteria were measured before and after high-pressure water based washing process set as CCP in most abattoirs. Four parts of cattle carcasses were selected to apply sponge-swab method. The effects were < 1 log reduction which is not significant. Lactic acid (LC), chlorine dioxide (ClO2) and slightly acidic electrolyzed water (SAEW) were used to measure the effect of reducing bacteria on beef by the different time. LC has 1.24-2.02 log reduction for aerobic bacteria. ClO2 has 1.44-1.96 log reduction for aerobic bacteria. SAEW has 1.1-1.91 log reduction for aerobic bacteria. There was significant difference according to concentrations (p < 0.05). This study presents legitimacy for hygiene improvement of CCP by field verification. In addition, chemical disinfectants that can be mechanically applied have better reduction effects of high-pressure washing.