• Title/Summary/Keyword: chemical hazard

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MSDSs Reliability Evaluation in Workplaces Manufacturing Aromatic Hydrocarbon (방향족 탄화수소 화학물질 제조사업장의 MSDS 신뢰성 평가 연구)

  • Lee, Kwon Seob;Choi, Jin Hee;Jo, Jihoon;Choi, Sung Bong;Lee, Jong Han;Yang, Jeong Sun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.19 no.4
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    • pp.370-380
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    • 2009
  • Reliable hazard and risk communication is needed to prevent the safety accident & occupational disease through right use of chemicals and MSDS(Material Safety Data Sheet) is mainly used as such a tool of communication. MSDS policy has been put into effect in order to prevent the safety accident & occupational disease through right use of chemicals and fulfill workers' right to know. If information on MSDS lacks reliability due to its inaccuracy, prevention of the various effects related with environmental safety & health in advance is not possible to achieve. The most essential thing regarding authoring MSDS is to exactly evaluate the composition and ingredients of the chemical and include reliability-guaranteed information. Therefore, in this study reliability was evaluated on MSDSs in 15 aromatic hydrocarbons(benzene, toluene, xylene, etc.) manufacturers and ways to secure reliability of MSDS were suggested. The results showed 93.5% of composition agreement rate and 89% of reliability on each section in MSDSs. In order to curb MSDSs with low reliability, examination on CBI(confidential business information) in MSDS, certification of MSDS, collection and verification of MSDS are suggested.

A Study on Mechanical Characteristics and Behaviors of FRP Composite with Three Different types of Matrices under High Temperature (온도 및 매트릭스 특성 변화에 따른 섬유강화 복합재료의 역학적 특성 및 구조적 거동 변화)

  • Jung, Woo-Young;Jang, Jun-Ho;Back, Min-Ho
    • Journal of the Korean Society of Hazard Mitigation
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    • v.8 no.3
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    • pp.1-9
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    • 2008
  • Fiber Reinforced Polymer (FRP) composites are used extensively in aerospace, marine, automotive, infrastructure, chemical processing and sporting good applications. A concern with using FRP composites in some engineering structures is their high flammability and poor fire resistance In this research, material properties of FRP composites at increasingly high temperatures was measured and verified. The obtained mechanical properties of FRP composites were performed according to ASTM D3039/D3039M and tested to a wide range of heat conditions with temperatures from Room-temp. to 300 for times up to 30 min. It is found that the mechanical properties of FRP composites dropped with increasing heat or temperature. The reduction to the properties was due mainly to thermal degradation and combustion of the polymer matrix.

Analysis of Disinfection Practices in Foodservice Operations According to the Application of Hazard Analysis and Critical Control Point (식품안전관리인증기준 적용 여부에 따른 급식시설의 소독 실태 분석)

  • Park, Min-Seo;Lee, Hye-Yeon;Bae, Hyun-Joo
    • Journal of the FoodService Safety
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    • v.2 no.2
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    • pp.103-110
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    • 2021
  • This study was conducted to compare and evaluate the difference in washing and disinfection when the Hazard Analysis and Critical Control Point (HACCP) protocol was applied to foodservice operations. The results of the survey were as follows: Among the 116 foodservice operations surveyed, 67.2% were HACCP-compliant and 32.8% were not HACCP-compliant. Also, 62.9% served meals once daily, and 79.3% conducted food safety education once a month. Compared to HACCP non-compliant foodservice operations, the disinfection performance of HACCP-compliant operations was significantly better concerning worktables (p<0.001), food inspection tables (p<0.001), preparation tables for distribution (p<0.01), serving tables (p<0.01), overflow and trenches(p<0.05), sinks (p<0.05), and insect attracting lamps (p<0.01). Similarly, the disinfection performance of HACCP-compliant foodservice operations was significantly better for 18 cooking utensils and personal tools such as food slicers (p<0.001), multiple cooking machines (p<0.05), tray carts (p<0.001), stainless steel tools (p<0.001), rubber gloves (p<0.05). Worktables (45.1%), serving tables (29.6%), sinks (37.0%), and scales (21.6%) were most often disinfected 'at the end of each task', while food inspection tables (36.5%), food preparation tables for distribution (31.2%), dish machines (34.2%), overflow and trenches (25.7%), and floors (25.8%) were most often disinfected 'once a day'. All cooking utensils were most often disinfected 'at the end of each task'. 'Chemical disinfection' was most frequently used in all foodservice facilities. To improve the food safety management of foodservice operations, it is necessary to apply the HACCP protocol and comply with the washing and disinfection manual.

Establishment of Integrated Health Evaluation Criteria for Coastal Aquaculture System (살포식 패류 양식어장 건강도 평가기준 설정)

  • Young-Shin Go;Dong-Hun Lee;Young-Jae Lee;Won-Chan Lee;Un-Ki Hwang
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.56 no.4
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    • pp.462-472
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    • 2023
  • We investigated the physio-chemical and geochemical parameters in the spraying shellfish aquacultures (Yeoja and Gangjin Bay) to establish the systematic strategy for effective environmental management. Spatial variation of each parameter showed partially significant difference (P<0.05) between Yeoja and Ganjin Bay, inferring the discriminative progress (i.e., accumulation and degradation) of the autochthonous organic matter within the aquaculture environments. We additionally integrated various properties (e.g., water/sediment quality, natural hazard, and biological health) which may affect the biological growth within the aquaculture habitats based on the biogeochemical cycles related to environmental components and aquaculture species. We used a screening approach (i.e., one out-all out; OOAO) which can permit the assessment of the health levels of aquaculture species, the scoring for other parameters (seawater, sediment, and natural hazard) as three levels (excellent, moderate and poor) depending on the complex interactive properties occurring in the aquaculture environments. Actual, discriminative scores obtained via our case studies may confirm that these stepwise processes are effectively evaluated for optimal health conditions within the aquaculture habitats. Thus, this approach may provide valuable insights for effective environmental management and sustainable growth of aquaculture operation.

Development of Laboratory Safety Management System for Chemistry and Chemical Engineering Laboratory (화학 및 화학공학 실험실의 안전관리 시스템 개발)

  • Yoo, Jin Hwan;Lee, Heon Seok;Choi, Joung Woo;Seo, Jae Min;Park, Chulhwan;Ko, Jae Wook
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.376-382
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    • 2008
  • There are many accidents such as fire and explosion in laboratories that have caused a great loss to lives and property in spite of the effort to the enhancement of laboratory safety level for years. Development of laboratory safety management system is a necessary to improve safety level because the accidents of similar types have periodically occurred in laboratories. The laboratory safety management system may reduce many accidents and a serious loss in laboratory. In this study, we summarized major items for a risk management and safety improvement based on the analysis results of various accidents in the laboratories. And then the laboratory safety management system was developed containing a laboratory safety management manual, a laboratory management system, a education management system, a MSDS (material safety data sheet) management system and a laboratory safety audit system. It may have a potential application for the laboratory safety management in the chemical laboratories.

A study on the establishment of the criteria for selection of Hazardous substances requiring management in Occupational Safety and Health Act (산업안전보건법상 관리대상 유해물질 선정기준 마련에 관한 연구)

  • Park, Eun Woo;Park, Jun Ho;Lee, Kwon Seob;Hong, Mun Ki;Ahn, Byung Jun;Lee, Eun Jung
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.24 no.4
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    • pp.425-435
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    • 2014
  • Objectives: This study was performed in order to establish reliable and relative selection criteria for hazardous substances requiring management(HSRM) in the Occupational Safety and Health Act in Korea. Methods: To determine the relative criteria and weight of evidence for HSRM, we analyzed the difference between the selection method of priority substances in studies by KOSHA(Korea Occupational Safety and Health Agency) and the European Union Risk Ranking Method(EURAM). In addition, 597 hazardous substances with exposure limit valueswereanalyzed and the posted health hazards classification by MOEL(Ministry of Employee and Labor), MOE(Ministry of Environment), and EU CLP(Classification, Labelling and Packaging regulation) were compared based on GHS(Globally Harmonized System of classification and labelling of chemicals) criteria. The existing HSRM(167 substances) were evaluated for suitability by the proposed criteria in this study. Results: As a result of this study, the criteria and procedures for selecting HSRM in the Occupational Safety and Health Act were arranged utilizing GHS health hazard classification results, occupational disease cases and domestic use situations. Conclusions: The applicability of the proposed criteria was proved via the evaluation of existing HSRM(167 substances). Most HSRM (161 substances) were found to correspond to a significant health effect or substantial health effect. The question of whether to include the six substances that have been found to have general health effects as HSRM would be require further research.

Consequence Analysis for Fire and Explosion Accidents in Propylene Recovery Process (프로필렌 회수공정에서 화재 및 폭발 사고의 피해영향 해석)

  • Han, Seong-Hwan;Lee, Hern-Chang;Park, Kyoshik;Kim, Tae-Ok
    • Journal of the Korean Institute of Gas
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    • v.18 no.1
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    • pp.52-60
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    • 2014
  • This study aims to suggest risk management plan including safety measures through hazard identification followed by consequence analysis in petrochemical plants. Consequence analysis was performed through practical release scenario by using PHAST RISK(ver. 6.7) software in the propylene recovery process(PRP). As results, consequences by fire or explosion accidents in the depropanizer zone, deethanizer zone and heat pump zone were relatively larger than other else zones among six process zones in the PRP. In the case of jet fire, it is recommendable not to install residence building within 200 m of the process zone. Additionally, process zones having large inventory or high pressure must be prevented from accidents and required to establish quick response against accidents.

Evaluation of Environmental Mutagens-Complex Mixture in Diesel Exhaust Respirable Particulate Matter

  • Kim, Soung-Ho;Ryu, Byung-Tak;Jang, Hyoung-Seok;Kim, Yun-Hee;Lee, Do-Han;Han, Kyu-Tae;Oh, Seung-Min;Chung, Kyu-Hyuck
    • Proceedings of the Korea Society of Environmental Toocicology Conference
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    • 2003.05a
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    • pp.194-194
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    • 2003
  • The International Agency for Research on Cancer (IARC, 1989) has classified whole diesel exhaust as probably carcinogenic to humans. Diesel exhaust particulate matter (DPM) adsorbs different chemical substances including PAHs and nitroarenes. DPM is emphasized because it is a major component of diesel exhaust, it is suspected of contributing to a health hazard. Diesel exhaust is a complex mixture of carbon particles and associated organics and inorganics, and it is not known what fraction or combination of fractions cause the health effects [cancer effects, noncancer effects (respiratory tract irritation/inflammation and changes in lung function)] that have been observed with exposure to diesel exhaust. In order to identify which chemical classes are responsible for the majority of the observed biological activities, we performed a particular biological/chemical analysis. Respirable particulate matter (PM2.5: <2.5mm) was collected from diesel engine exhaust using a high-volume sampler equipped with a cascade impactor. Particulate oganic matter was extracted by the dichloromethane/sonication method and the crude extract was fractionated according to EPA recommended procedure into seven fractions by acid-base partitioning and silica gel column chromatography. We examined genotoxic potentials of diesel exhaust particulate matter using novel genotoxicity tests, which are rapid, simple and sensitive methods for assessing DNA-damage at the DNA and chromosomal level (comet assay, in vitro MN test and Ames test). Higher genotoxic potency was observed in non polar fractions and several PAHs were detected by GC-MS, such as 1,2,5,6 dibenzanthracene, chrysene, 1,2-benzanthracene, phenanthrene and fluoranthene.

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A study on the Recognition of Material Safety Data Sheets and Safety of Handling Harmful Chemicals in Dental Hygienists (치과위생사의 물질안전보건자료 인식도와 유해화학물질 취급 시 안전 실태에 관한 연구)

  • Kim, Eun-Kyoung;Chung, Kyung-Yi
    • Journal of Digital Convergence
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    • v.16 no.4
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    • pp.185-194
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    • 2018
  • The purpose of this study was to understand the dental hygienist's perception of dental materials and to understand the safety status of harmful chemicals. The study was conducted from January to February 2015 for 250 dental hygienists working in Gwangju Metropolitan City. as a result, the degree of recognition of MSDS for dental materials was higher with age (P <0.05) and higher in dental hygienist (P <0.001) working at dental hospital. (P <0.001), and the factors affecting the perception of first aid treatment were positively correlated with experience of hazard education (P <0.001). Therefore, by understanding the MSDS awareness of dental materials by dental hygienists and the safety situation in the handling of hazardous chemical substances, we provide basic data for establishing proper recognition of safety in the handling of harmful chemical substances and developing educational programs to prevent accidents.

Reliability Analysis of Material Safety Data Sheets(MSDS) for Photoresist Chemicals used in some Semiconductor Factories (일부 반도체 사업장 포토레지스트 화학물질 MSDS 정보의 신뢰성 분석)

  • Lee, Kyunghwa;Lee, Seokyong;Choi, Yoonji;Choi, Hanyoung
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.26 no.4
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    • pp.404-410
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    • 2016
  • Objectives: This study aimed to examine and analyze the material safety data sheet(MSDS) information for photoresist chemicals used in certain processes in semiconductor plants. Methods: After collecting MSDS for 178 chemical products currently used in certain processes in semiconductor plants, we analyzed Sections 2, 3, 11, and 15 of each MSDS with reference to the guidelines for evaluating the reliability of MSDS provided by the Korea Occupational Safety and Health Agency. In addition, we reviewed the recorded uses and the ratios of trade secrets. Results and Conclusions: We studied a total of 178 chemical products. An MSDS was available for 176(98.9%) of them and all adhered to the Globally Harmonized System(GHS) regulations. There were 37 cases of errors in Hazard Identification, pertaining to 20.8% of all products surveyed. There were 64 cases of errors in the current legal circumstances, pertaining to 36.0% of all products. There were a total of 407 trade secrets across 52.2% of products. We believe that a government-led education and certification system needs to be introduced to improve the transfer of MSDS information. The government, chemical manufacturers and suppliers all need to make an effort to produce reliable MSDS.