• 제목/요약/키워드: chemical foaming

검색결과 117건 처리시간 0.023초

The Investigation of Rheological Properties Development for Polymer Matrix Including Foaming Agent

  • Lee, Seung Hak;Kim, Dong Gun;Lim, Sung Wook;Park, Eun Young;Park, Tae Sun;Hyun, Kyu
    • Elastomers and Composites
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    • 제51권1호
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    • pp.24-30
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    • 2016
  • Sole in the footwear usually modified with foaming agent on the polymer resin to improve the lightweightness and crush-cushion effect. In this study, we investigated rheological properties for polymer resin filled with the different type and concentration of foaming agent, capsule type foaming agent and organo-chemical foaming agent, under the time sweep test. Curing times of each polymer resin with different kind of foaming agent are delayed than reference material (epoxy resin with curing agent). In case of adding capsule type foaming agent, however, there is appropriate concentration to reduce the curing time, relatively. When foaming agent is activated, foaming force inflates the sample in contrast to condensation force of curing and then axial normal force develop to the (+) direction. Interestingly, by increase concentration of foaming agent, there is a specific point to break down the axial normal force development. The reason for this phenomenon is that coalescence of foams induce the blocking of axial normal force development.

용제형 저기포성 정련제의 제조 및 정련효과 (Preparation of Solvent-Type Low Foaming Scouring Agents and Their Scouring Effect)

  • 유혁제;정동진;;함현식;박홍수
    • 한국응용과학기술학회지
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    • 제21권2호
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    • pp.156-163
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    • 2004
  • Low foaming scouring agents (LSSA) were prepared by blending of amine salt of dodecylbenzene sulfone, poly (PO-b-EO) glycol, Newpol PP-2000, MJU-100, ethylene glycol and organic solvent. As the results of several tests, LSSA-2 showed good scouring effect, penetrating ability and emulsifiability, and showed not much water pollution. The foaming power of LSSA-2 measured by Ross & Miles method was 11mm foam height immediately after foaming. And the foaming power of LSSA-2 measured by Ross & Clark method were less than 310mm foam height at $30^{\circ}C$, 17mm at $80^{\circ}C$. As a result, LSSA-2 was proved as a good foaming scouring agent.

An Environment-Friendly Surface Pretreatment of ABS Plastic for Electroless Plating Using Chemical Foaming Agents

  • Kang, Dong-Ho;Choi, Jin-Chul;Choi, Jin-Moon;Kim, Tae-Wan
    • Transactions on Electrical and Electronic Materials
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    • 제11권4호
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    • pp.174-177
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    • 2010
  • We have developed an environment-friendly etching process, an alternative to the dichromic acid etching process, as a pretreatment of acrylonitrile-butadiene-styrene (ABS) plastic for electroless plating. In order to plate ABS plastic in an electroless way, there should be fine holes on the surface of the ABS plastic to enhance mechanically the adhesion strength between the plastic surface and the plate. To make these holes, the surface was coated uniformly with dispersed chemical foaming agents in a mixture of environmentally friendly dispersant and solvent by the methods of dipping or direct application. The solvent seeps into just below the surface and distributes the chemical foaming agents uniformly beneath the surface. After drying off the surface, the surface was heated at a temperature well below the glass transition temperature of ABS plastic. By pyrolysis, the chemical foaming agents made fine holes on the surface. In order to discover optimum conditions for the formation of fine holes, the mixing ratio of the solvent, the dispersant and the chemical foaming agent were controlled. After the etching process, the surface was plated with nickel. We tested the adhesion strength between the ABS plastic and nickel plate by the cross-cutting method. The surface morphologies of the ABS plastic before and after the etching process were observed by means of a scanning electron microscope.

무용제형 저기포성 정련제의 제조 및 정련특성 (Preparation of Solvent-Free Low Foaming Scouring Agents and Their Scouring Characteristics)

  • 박홍수;안성환;심일우;조혜진;함현식;김영찬;김성길
    • 한국응용과학기술학회지
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    • 제23권1호
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    • pp.37-44
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    • 2006
  • Solvent-free low foaming scouring agents (LFSC) were prepared by blending of 2-ethylhexylaminoethyl sulfate (2-EHAS), POE(10) octadecylbenzyl- ammonium chloride (POBAC) and Sedlan FF-200 (FF-200). As the results of several tests, 2-EHAS/POBAC/FF-200/water (8g/12g/20g/60g) mixture (LFSC-5) showed good cleaning power, penetrating ability and stability to alkali, and gave less problem in water pollution. The foaming power of LFSC-5 measured by Ross and Miles method was 8mm foam height immediately after foaming, and that measured by Ross and Clark method was less than 300mm foam height at $30^{\circ}C$, and 18mm at $80^{\circ}C$. As a result, LFSC-5 proved a good low foaming scouring agent for fiber.

Effect of pH on Successive Foam and Sonic Droplet Fractionation of a Bromelain-invertase Mixture

  • Ko Samuel;Prokop Ales;Tanner Robert D.
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제7권1호
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    • pp.26-30
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    • 2002
  • A droplet fractionation method was previously developed to concentrate a dilute nonfoaming protein solution. In that earlier study with invertase, it was demonstrated that droplets created by ultrasonic energy waves could be enriched up to 8 times that of the initial dilute invertase solution. In this study, a mixture of bromelain (a foaming protein) and invertase (a nonfoaming protein) is investigated as a preliminary step to determine if droplet fractionation can also be used to separate a non-foaming protein from foaming proteins. The foaming mixture containing bromelain is first removed by bubbling the binary mixture with air. After the foam is removed, the protein rich air-water interfacial layer is skimmed off (prior to droplet fractionation) so as not to interfere with the subsequent droplet production from the remaining bulk liquid, rich in non-foaming protein. Finally, sonic energy waves are then applied to this residual bulk liquid to recover droplets containing the non-foaming protein, presumed to be invertase. The primary control variable used in this droplet fractionation process is the pH, which ranged for separate experiments between 2 and 9. It was observed that the maximum overall protein partition coefficients of 5 and 4 were achieved at pH 2 and 4, respectively, for the initial foaming experiment followed by the post foaming droplet fractionation experiment.

LDPE, EVA 및 발포제 혼합재료의 초미세 발포 공정 적용과 각 인자의 영향성 평가 (Application of a Microcellular Foaming Process of Mixed Materials of LDPE, EVA and Foaming Agent and Estimation of Influence of Each Factor)

  • 박대근;차성운;황윤동
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집A
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    • pp.853-858
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    • 2001
  • Generally, mixed materials of LDPE, EVA and foaming agent are manufactured by crosslinking foaming or chemical foaming process. Above materials were used in a microcellular foaming injection molding process. Influence of each factor such as injection type, temperature of barrel, rate of mixed materials and contents of foaming agent was estimated by DOE(Design of Experiments). As a result of experiments, injection type and rate of LDPE, EVA have an influence on foaming rate. This data can be used in field of application of LDPE and EVA.

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폐 소다석회 유리의 조성조절에 의한 발포유리블록의 제조 (Preparation of Foamed Glass Block from Recycled Soda-lime-silicate Glasses by Chemical Composition Control)

  • 김정민;이철태
    • 공업화학
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    • 제24권4호
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    • pp.382-390
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    • 2013
  • 소다석회 조성의 폐 병유리를 대상으로 효율적인 재활용방안을 찾기 위해서 발포화에 적절한 조성의 조절을 통해 직접 보온단열재 발포유리블럭을 제조할 수 있는 공정을 조사하였다. 폐 병유리의 직접 발포화를 위해 첨가되는 성분 및 조성은, 폐 유리분말 100중량부에 대하여 $SiO_2$ 10중량부, $Na_2SO_4$ 0.5중량부, $B_2O_3$ 3.0중량부, 그리고 발포제로서 카본 블랙류 탄소재 0.3중량부이다. 발포공정은 턴넬키른에서 진행하며, 발포소성 조건은 폐 유리분말의 입도는 -325 mesh, 발포소성온도는 $830{\sim}850^{\circ}C$, 발포시간은 30~35 min이 바람직하다. 상기 조건하에 제조된 발포체는 밀도가 $0.17{\sim}0.21g/cm^3$, 열전도도 $0.06{\pm}0.005kcal/h{\cdot}m{\cdot}^{\circ}C$, 수분 흡수율 1.1~1.5%, 압축강도는 $20{\sim}30kgf/mm^2$의 물성을 나타내었다.

해포석과 팽창진주암의 복합화에 의한 발포체 제조 (A Foamed Body through the Complexation with the Sepiolite and Expanded Pearlite)

  • 이철태;장문호;박태문
    • 공업화학
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    • 제23권1호
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    • pp.77-85
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    • 2012
  • 팽창진주암(expanded perlite)과 섬유상 해포석(sepiolite)과의 복합화를 통해 유연성을 지닌 세라믹 발포체의 제조가능성을 조사하였다. 무기광물 섬유 해포석의 해섬처리는 팽창진주암과 해포석으로 이루어진 세라믹발포체의 제조를 위해 가장 중요한 전 처리공정이다. 해섬된 해포석과 팽창진주암은 혼합 교반되어 슬러리 상태로 이루어지며, 이 슬러리상의 복합물은 $300^{\circ}C$ 이하의 저온 열처리과정을 통해 형상화 및 발포화되어 괴상의 발포체로 제조된다. 슬러리상 복합물의 열처리공정은 슬러리 복합물 중에 잔존하는 수분의 증발단계, 일정발포온도에서 발포화제가 분해되어 진행되는 발포화단계 및 발포 후 잔류되는 유기물질의 분해제거단계를 포함하는 것으로 설계되어야 한다. 열처리 공정조건과 발포제는 상관성이 있으며 팽창진주암과 해포석섬유로 이루어진 슬러리상 혼합물의 발포에 적절한 발포제는 유기계 발포제가 적절하며 DSS (dioctyl sodium sulfosuccinte)가 효과적이었다.

폐 LCD판넬의 유가성분 회수를 위한 폐 LCD유리의 발포공정 (Foaming Process of Waste LCD Glass for the Recovery of Valuable Materials from Waste LCD Pannel)

  • 이철태;박태문;김정민
    • 공업화학
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    • 제23권2호
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    • pp.195-203
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    • 2012
  • 폐 LCD유리의 재활용 방안은 평판 디스플레이용 폐 LCD판넬의 전체 재활용 공정의 확립을 위한 중심요건이다. 본 연구는 폐 LCD유리를 보온단열재, 흡음차음제, 토목용 경량골재 또는 수처리용 담체 등의 원료로 재활용하기 위한 발포공정의 기초공정으로서 폐 LCD유리의 분쇄특성, 적절한 탄소발포제의 선정, 유가물 회수를 위한 산침출 후 잔유된 유리질의 물성 및 이들의 발포화의 문제점을 조사하였다. 폐 LCD유리의 분쇄공정을 통해 발포용 원료로 사용가능한 미분화가 가능하였으며, 고융점을 갖는 LCD 유리의 발포화를 위해서는 결정성 천연흑연이 적절하였으며, 산 침출 후 잔사인 슬러지 상태의 폐유리성분도 발포체의 원료로 재활용될 수 있음을 확인하였다.