• Title/Summary/Keyword: chemical foaming

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The Investigation of Rheological Properties Development for Polymer Matrix Including Foaming Agent

  • Lee, Seung Hak;Kim, Dong Gun;Lim, Sung Wook;Park, Eun Young;Park, Tae Sun;Hyun, Kyu
    • Elastomers and Composites
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    • v.51 no.1
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    • pp.24-30
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    • 2016
  • Sole in the footwear usually modified with foaming agent on the polymer resin to improve the lightweightness and crush-cushion effect. In this study, we investigated rheological properties for polymer resin filled with the different type and concentration of foaming agent, capsule type foaming agent and organo-chemical foaming agent, under the time sweep test. Curing times of each polymer resin with different kind of foaming agent are delayed than reference material (epoxy resin with curing agent). In case of adding capsule type foaming agent, however, there is appropriate concentration to reduce the curing time, relatively. When foaming agent is activated, foaming force inflates the sample in contrast to condensation force of curing and then axial normal force develop to the (+) direction. Interestingly, by increase concentration of foaming agent, there is a specific point to break down the axial normal force development. The reason for this phenomenon is that coalescence of foams induce the blocking of axial normal force development.

Preparation of Solvent-Type Low Foaming Scouring Agents and Their Scouring Effect (용제형 저기포성 정련제의 제조 및 정련효과)

  • You, Hyuk-Jae;Chung, Dong-Jin;Jung, Choong-Ho;Hahm, Hyun-Sik;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.2
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    • pp.156-163
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    • 2004
  • Low foaming scouring agents (LSSA) were prepared by blending of amine salt of dodecylbenzene sulfone, poly (PO-b-EO) glycol, Newpol PP-2000, MJU-100, ethylene glycol and organic solvent. As the results of several tests, LSSA-2 showed good scouring effect, penetrating ability and emulsifiability, and showed not much water pollution. The foaming power of LSSA-2 measured by Ross & Miles method was 11mm foam height immediately after foaming. And the foaming power of LSSA-2 measured by Ross & Clark method were less than 310mm foam height at $30^{\circ}C$, 17mm at $80^{\circ}C$. As a result, LSSA-2 was proved as a good foaming scouring agent.

An Environment-Friendly Surface Pretreatment of ABS Plastic for Electroless Plating Using Chemical Foaming Agents

  • Kang, Dong-Ho;Choi, Jin-Chul;Choi, Jin-Moon;Kim, Tae-Wan
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.4
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    • pp.174-177
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    • 2010
  • We have developed an environment-friendly etching process, an alternative to the dichromic acid etching process, as a pretreatment of acrylonitrile-butadiene-styrene (ABS) plastic for electroless plating. In order to plate ABS plastic in an electroless way, there should be fine holes on the surface of the ABS plastic to enhance mechanically the adhesion strength between the plastic surface and the plate. To make these holes, the surface was coated uniformly with dispersed chemical foaming agents in a mixture of environmentally friendly dispersant and solvent by the methods of dipping or direct application. The solvent seeps into just below the surface and distributes the chemical foaming agents uniformly beneath the surface. After drying off the surface, the surface was heated at a temperature well below the glass transition temperature of ABS plastic. By pyrolysis, the chemical foaming agents made fine holes on the surface. In order to discover optimum conditions for the formation of fine holes, the mixing ratio of the solvent, the dispersant and the chemical foaming agent were controlled. After the etching process, the surface was plated with nickel. We tested the adhesion strength between the ABS plastic and nickel plate by the cross-cutting method. The surface morphologies of the ABS plastic before and after the etching process were observed by means of a scanning electron microscope.

Preparation of Solvent-Free Low Foaming Scouring Agents and Their Scouring Characteristics (무용제형 저기포성 정련제의 제조 및 정련특성)

  • Park, Hong-Soo;Ahn, Sung-Hwan;Shim, Il-Woo;Jo, Hye-Jin;Hahm, Hyun-Sik;Kim, Yeoung-Chan;Kim, Seong-Kil
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.1
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    • pp.37-44
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    • 2006
  • Solvent-free low foaming scouring agents (LFSC) were prepared by blending of 2-ethylhexylaminoethyl sulfate (2-EHAS), POE(10) octadecylbenzyl- ammonium chloride (POBAC) and Sedlan FF-200 (FF-200). As the results of several tests, 2-EHAS/POBAC/FF-200/water (8g/12g/20g/60g) mixture (LFSC-5) showed good cleaning power, penetrating ability and stability to alkali, and gave less problem in water pollution. The foaming power of LFSC-5 measured by Ross and Miles method was 8mm foam height immediately after foaming, and that measured by Ross and Clark method was less than 300mm foam height at $30^{\circ}C$, and 18mm at $80^{\circ}C$. As a result, LFSC-5 proved a good low foaming scouring agent for fiber.

Effect of pH on Successive Foam and Sonic Droplet Fractionation of a Bromelain-invertase Mixture

  • Ko Samuel;Prokop Ales;Tanner Robert D.
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.1
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    • pp.26-30
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    • 2002
  • A droplet fractionation method was previously developed to concentrate a dilute nonfoaming protein solution. In that earlier study with invertase, it was demonstrated that droplets created by ultrasonic energy waves could be enriched up to 8 times that of the initial dilute invertase solution. In this study, a mixture of bromelain (a foaming protein) and invertase (a nonfoaming protein) is investigated as a preliminary step to determine if droplet fractionation can also be used to separate a non-foaming protein from foaming proteins. The foaming mixture containing bromelain is first removed by bubbling the binary mixture with air. After the foam is removed, the protein rich air-water interfacial layer is skimmed off (prior to droplet fractionation) so as not to interfere with the subsequent droplet production from the remaining bulk liquid, rich in non-foaming protein. Finally, sonic energy waves are then applied to this residual bulk liquid to recover droplets containing the non-foaming protein, presumed to be invertase. The primary control variable used in this droplet fractionation process is the pH, which ranged for separate experiments between 2 and 9. It was observed that the maximum overall protein partition coefficients of 5 and 4 were achieved at pH 2 and 4, respectively, for the initial foaming experiment followed by the post foaming droplet fractionation experiment.

Application of a Microcellular Foaming Process of Mixed Materials of LDPE, EVA and Foaming Agent and Estimation of Influence of Each Factor (LDPE, EVA 및 발포제 혼합재료의 초미세 발포 공정 적용과 각 인자의 영향성 평가)

  • Park, Dae-Keun;Cha, Sung-Woon;Hwang, Yun-Dong
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.853-858
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    • 2001
  • Generally, mixed materials of LDPE, EVA and foaming agent are manufactured by crosslinking foaming or chemical foaming process. Above materials were used in a microcellular foaming injection molding process. Influence of each factor such as injection type, temperature of barrel, rate of mixed materials and contents of foaming agent was estimated by DOE(Design of Experiments). As a result of experiments, injection type and rate of LDPE, EVA have an influence on foaming rate. This data can be used in field of application of LDPE and EVA.

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Preparation of Foamed Glass Block from Recycled Soda-lime-silicate Glasses by Chemical Composition Control (폐 소다석회 유리의 조성조절에 의한 발포유리블록의 제조)

  • Kim, Jung-Min;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.382-390
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    • 2013
  • Foaming process of waste soda lime glasses by just chemical composition control of vitreous feed materials was investigated to find a novel and efficient recycling process. For the chemical composition control of feed materials, 10 wt. parts of $SiO_2$, 0.5 wt. parts of $Na_2SO_4$, 3.0 wt. parts of $B_2O_3$, and 0.3 wt. parts of carbon black as the foaming agent were mixed with 100 wt. parts of soda-lime vitreous feed powder. Proper conditions for foaming process in tunnel kiln are the foaming temperature of $830{\sim}850^{\circ}C$, the foaming time of 30~35 min, and the vitreous feed powder particle size of -325 mesh. Properties of foamed glass blocks obtained under these foaming conditions showed the density of $0.17{\sim}0.21g/cm^3$, thermal conductivity of $0.06{\pm}0.005kcal/h{\cdot}m{\cdot}^{\circ}C$, moisture absorption of 1.1~1.5%, and compressive strength of $20{\sim}30kgf/mm^2$.

A Foamed Body through the Complexation with the Sepiolite and Expanded Pearlite (해포석과 팽창진주암의 복합화에 의한 발포체 제조)

  • Lee, Chul-Tae;Jang, Moonho;Park, Tae-Moon
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.77-85
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    • 2012
  • Production process of the flexible ceramic foamed body through the complexation with the fiberous sepiolite and expanded pearlite was researched. The processing of fibrillation of the inorganic mineral fiber sepiolite is the most important whole processing for manufacturing of the ceramic foamed body consisting of the expanded perlite and sepiolite. The fibrous sepiolite and expanded pearlite are blended and becomes the slurry phase. And this slurry phase is converted to a massive foamed body through the low temperature heat treatment process less than $300^{\circ}C$. The heat-treatment process of the slurry phase composite has to be designed to include the evaporation step of the moisture remaining among the slurry composition, foaming step by the decomposition of the foaming agent, and resolution removal step of the organic material which was added in the composite remained after the foaming step. The heat treatment process should be considered as significant factors in design of total process. As to the condition of heat treatment process and foaming agent, there was the a correlation. An organic type foaming agent like DSS (dioctyl sodium sulfosuccinte) was effective in foaming of the slurry compound consisting of the expanded perlite and sepiolite fiber.

Foaming Process of Waste LCD Glass for the Recovery of Valuable Materials from Waste LCD Pannel (폐 LCD판넬의 유가성분 회수를 위한 폐 LCD유리의 발포공정)

  • Lee, Chul-Tae;Park, Tae-Moon;Kim, Jung-Min
    • Applied Chemistry for Engineering
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    • v.23 no.2
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    • pp.195-203
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    • 2012
  • Recycling method of waste LCD glass is the essential process for developing the total recycling process of LCD pannel. Pulverizing of LCD glass, determination of proper carbonacious foaming agent, the properties of residue from the recovery of valuable materials through an acid leaching process and the feasibility for the foaming of the residue obtained from leaching for indium and tin recovery were investigated for the developing of recycling method of waste LCD glass as industrial feed materials, such as heat insulation materials, sound absorbing materials, carrier of water treatment. Waste LCD glass could be pulverized finely for foaming process. Natural graphite was proper agent for foaming of the residue and the foaming technology of LCD glass would be effective recycling alternatives.