• Title/Summary/Keyword: chemical elements

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Chemical Composition of Petals of Chrysanthemum spp.

  • Park, Nan-Yong;Kwon, Jong-Ho
    • Preventive Nutrition and Food Science
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    • v.2 no.4
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    • pp.304-309
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    • 1997
  • Chemical compositions of petals of Chrysanthemum spp. were determined to renew its interest as a food material. The moisture contents of wild Chrysanthemum boreale and holticulturized Chrysanthemum morifolium were 11.7% and 11.0%. The proximate chemical ompositions were 6.1% and 11.7% in protein, 3.7% and 5.2% in ash, 11.1% and 12.8% in reducing sugar, of C. boreale and C. morifolium, respectively. Free sugars were mainly composed of fructose, glucose and sucrose. In fatty acid composition, the ratios of saturated to unsaturated fatty acids were 1.2:1 and 3.0:1, respectively. The amino acids determined were found 0.18 and 0.26 in the ratio of essential to total amino acids in each sample. Major elements of Chrysanthemum petals were Ca, K, Fe, Mg and Na, but the contents of Ca and Fe were more than twice higher in C. boreale than c. morifolium, Major volatile flavor components were 28.22% of epi-bicyclophellandrene and 24.55% of camphor in C. boreale, and 14.24% of 4-methyl-1-(10methylethyl)-3-cyclhexen-1-ol, 10.74% of camphor and 7.64% of 1,8-cineol in C. morifolium.

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A Study on the Thermal and Chemical Characteristics of Wasted Coal for the Development of Low Cost Fuel

  • Lee, G.H.;Shim, J.D.
    • Agricultural and Biosystems Engineering
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    • v.3 no.2
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    • pp.79-84
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    • 2002
  • The seawater involving diverse chemical elements was mixed with wasted coals to improve the quality. The thermal and chemical characteristics of these seawater-mixed coals were investigated and compared with those of original coals. The contents of MgO, $Na_2O$, and $K_2O$ were increased by mixing seawater in wasted coals. The content of $Na_2O$ in these coal samples was greatly increased due to the sodium, which was the main component of seawater. Thus, it was expected that fusion temperatures of these coal samples were decreased. Coal samples mixed with seawater showed that the rapid weight loss was started at the lower temperature than those of original coal samples. In these coal samples, the temperatures of maximum heat emission were lowered by average $61^{\circ}C.$. Thus, it is suggested that some chemical constituents of the seawater act an important role on lowering the ignition temperature of wasted coal. By mixing seawater into wasted coals, the calorific values were increased. Especially, calorific values were greatly increased in the coal samples of lower quality as Baksan A and B with the improvement of 15~20%.

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Laboratory Safety Management System and Its Role on the Performance of Safety-Related Activities in Korean Academia (대학의 실험실 안전보건관리체계 구축이 안전보건관리활동에 미치는 영향)

  • Yoo, Kyong-Nam;Park, Jeong-Im;Park, Tae-Joo;Choi, Min-Kju;Lee, Chung-Hak
    • Journal of Environmental Health Sciences
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    • v.31 no.5 s.86
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    • pp.365-371
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    • 2005
  • This study was peformed to explore the current situation of university environmental health and safety (EHS) system and evaluate the effects of such system on university EHS practices. Essential elements for the university EHS system were identified based on the representative examples of foreign universities, and Hey were incorporated into a questionnaire, which was used in this study. Among the academic institutions we surveyed in this study, 89% of the universities employed health and safety manager, and 65% kept departments. However, less than 50% of universities maintained EHS policies, maintained health and established safety committees within the university headquarters, and held health and safety meetings on regular basis. Several basic requirements such as chemical hygiene program and laboratory safety training program lacked in many universities. Some basic surveillance was performed in many universities, however, only few universities carried out surveillance on biological safety, medical examination, and chemical exposure monitoring. EHS system had significant influence on university EHS program (p<0.05). Performances of EHS activities were influenced by presence of EHS policies, and university health and safety committees.

CHEMICAL ABUNDANCE ANALYSIS OF M31 AND M33 BASED ON THE SPECTRUM OF HII REGIONS (HII 영역 분광자료를 통한 M31과 M33의 화학원소 결정)

  • HAN SOO RYEON;HYUNG SIEK;PARK HONG-SUH;LEE WOO-BAlK
    • Journal of The Korean Astronomical Society
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    • v.34 no.2
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    • pp.67-80
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    • 2001
  • Chemical evolution of galaxies can be understood by studying the spatial distribution of heavy elements. We selected two nearby galaxies, M31 and M33 and investigated spectrum of their HII regions: a) the elec-tron densities have been derived from the [S II] 6717/6731 ratio along with the most recent atomic constants (Hyung & Aller 1996); b) the electron temperatures were determinated from the Pagel's empirical method. Nebula Model (Hyung 1994) has been employed to predict the spectral line intensities which gives the proper chemical abundances. The model would predict the line intensities correctly only when various input parameters such as the effective central star temperatures, gravity log g, model atmosphere as well as the geometry and the nebula physical condition are appropriate. Thus, the determination of chemical abundances of O, S, N of the two nearby galaxies M31 and M33 has been done, which shows a radial dependance of O/H and N/H: decrease with the distance, or increasing electron temperature due to the elemental deficiency. Abundances of M31 appear to be enhanced than those of M33.

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Effects of Metal Anion Complexes in Electrolyte on the Properties of Anodic Oxide Films on ADC12 Al Alloy

  • Yoo, Hyeonseok;Lee, Chulho;Oh, Kiseok;Choi, Jinsub
    • Journal of the Korean institute of surface engineering
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    • v.49 no.2
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    • pp.130-134
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    • 2016
  • The anodization of ADC12 aluminum alloy was investigated in the metal anionic acid media. Anodic oxide films containing foreign elements were formed on ADC12 Al alloy by anodization in the anion complex solution. Furthermore, the rough surface and cracks were considerably smoothened by the deposit of metal anions. When the size of metal anion was small, relatively large amount of metal anions was loaded in anodic films. Existence of $MoO_3$, $TiO_2$ and MgO was confirmed by XPS. According to the results of Tafel analysis, Mo oxide represented the most noble anti-corrosion potential due to $MoS_2$ formation. Corrosion current densities were generally higher than that of pristine anodic oxide without anion complexes.

Iron Ion Contamination and Acid Washing Effect of Polymer Membrane and Electrode in Polymer Electrolyte Fuel Cell (고분자전해질 연료전지에서 고분자 막과 전극의 철 이온 오염 및 산 세척 효과)

  • Yoo, Donggeun;Park, Minjeong;Oh, Sohyeong;Park, Kwon-Pil
    • Korean Chemical Engineering Research
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    • v.60 no.1
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    • pp.20-24
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    • 2022
  • In the process of long-term use of PEMFC (Proton Exchange Membrane Fuel Cells), chemical degradation of membrane electrode assembly (MEA) occurs due to corrosion of stack elements and contamination of supply gas. In this study, we investigated whether chemically degraded MEA can be recovered by acid washing. The performance was measured and compared in a PEMFC cell after contamination with iron ions and washing with an aqueous sulfuric acid solution. The performance was reduced by about 25% by 0.5 ppm iron ion contamination, and 97.1% performance recovery was possible by washing of 0.15 M sulfuric acid. The membrane resistance was increased due to iron ion contamination of the polymer membrane, and the ionic conductivity was restored by washing the iron ions from the membrane while minimizing the loss of the electrode catalyst by washing with a low-concentration sulfuric acid aqueous solution. The possibility of solving the decrease in durability caused by chemical contamination of PEMFC MEA by the acid washing was confirmed.

A Study on Quantitative Risk Analysis & Model Application for Hydrogen Filling Center (수소충전시설에 대한 정량적 위험성 평가 및 모델적용에 관한 연구)

  • Shin, Jung-Soo;Byun, Hun-Soo
    • Journal of the Korean Institute of Gas
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    • v.16 no.6
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    • pp.87-101
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    • 2012
  • In gas industries, the potential risks of serious accidents have been increased due to high technology application and process complexities. Especially, in case of gas-related accidents, the extent of demage is out of control since gas plants handle and produce combustible, flammable, explosive and toxic materials in large amounts. The characteristics of this kind of disaster is that accident frequency is low, while the impact of damage is high, extending to the neighboring residents, environment and related industries as well as employees involved. The hydrogen gases treated important things and it used the basic material of chemical plants and industries. Since 2000, this gas stood in the spotlight the substitution energy for reduction of the global warming in particular however it need to compress high pressure(more than 150 bar.g) and store by using the special cylinders due to their low molecular weight. And this gas led to many times the fire and explosion due to leak of it. To reduce these kinds of risks and accidents, it is necessary to improve the new safety management system through a risk management after technically evaluating potential hazards in this process. This study is to carry out the quantitative risk assesment for hydrogen filling plant which are very dangerous(fire and explosive) and using a basic materials of general industries. As a results of this risk assessment, identified the elements important for safety(EIS) and suggested the practical management tools and verified the reliability of this risk assessment model through case study of accident.

Effect of soil fumigation treatment on the growth and the chemical composition of Korea ginseng, Panax ginseng C.A. Meyer (토양훈증제 처리가 2년생 인삼의 생육과 화학적 조성에 미치는 영향)

  • Ahn Y.J.;Kim Y.T.;Kim M.S.;Choi S.Y.
    • Korean journal of applied entomology
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    • v.20 no.1 s.46
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    • pp.31-36
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    • 1981
  • These experiments were conducted to investigate some effects of the soil fumigants Dow-fume MC-2, Cylone, TeloneC-17, and D-D on the growth response of the Korea ginseng(two-year old), Panax ginseng C.A. Meyer, and the chemical composition of the plants. Fumigant treatment increased growth of roots, stems, and leaves. The increase of root growth rates ranging from 2.8 to $58.7\%$ in fresh weight and 8.1 to $63.8\%$ in dry weight were observed in the 2-year old ginseng plants grown in the old ginseng soil treated with the different soil fumigants. The chemical analysis of inorganic elements such as N, P, K, Ca, Mg, Na, Fe, Mn, and Zn was made for the roots, stems and leaves of the 2-year old plants. The increases or decreases of content of the elements were observed, and their contents of each of the elements were changed with the kind of fumigants, part of the plants, and soil depth of the fumigant treatments, but their changing tendencies were not steady.

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A Study on Chemical Composition and Firing Temperature of White Wares from the Guyre-2ri Kiln Sites, Wonju (원주 귀래2리 가마터 출토 백자의 화학조성과 소성온도 연구)

  • Lee, Byeong Hoon;So, Myoung-Gi
    • Journal of Conservation Science
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    • v.30 no.3
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    • pp.249-261
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    • 2014
  • This study aims to examine production technique of white wares from the Guyre-2ri 1st and 2nd kiln sites, Wonju, Gangwon Province and characteristics of the used materials, and to find a correlation among materials of the excavated white wares. X-ray fluorescence sequential spectroscopy(XRF), X-ray diffraction(XRD), Dilatometer and Inductively coupled plasma mass spectrometry(ICP-MS), Inductively coupled plasma automic emission spectrometer(ICP-AES) were applied to determine the chemical composition, crystalline phase of samples, firing temperatures, trace elements and rare earth elements. White wares from the Guyre-2ri kiln sites contained high contents of coloring oxides and fluxes. Though firing temperature of each sample was different, they were mostly fired at a temperature below $1200^{\circ}C$ and some of them experienced a low temperature of $1000^{\circ}C{\pm}20^{\circ}C$ and a high temperature above $1200^{\circ}C$. When analyzing body crystalline phases of the white wares using the XRD method, quartz and mullite were extracted from all the samples, and the proportions were similar to each other. When analyzing the excavated white wares using the Seger formula, also, all the samples showed similar clay sources and production techniques. Moreover, the white wares were made of host rocks of the same geological origin, according to the result of rare earth elements analysis.

Surface Properties of Color Concrete Using Acid Stained Agent (표면 착색용 산화제를 사용한 컬러 콘크리트의 표면 특성)

  • Kim, Jin-Man;Jeong, Ji-Yong;Park, Hyo-Jin
    • Journal of the Korea Concrete Institute
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    • v.23 no.3
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    • pp.265-272
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    • 2011
  • Even though concrete is the most important material for building structures, its intrinsic gray color degrades urban esthetics. In order to improve this problem, coloring methods of mixing pigment in concrete batch and painting the surface of concrete surface have been tried. However, applications of the coloring methods in construction field are difficult due to high cost and low durability. Recently, acid stain agent is emerging as a new coloring method for concrete. It is able to apply a remarkably thin colored layer on a concrete surface from chemical reaction between acid and alkaline solutions. This study has examined the changes and variations of the surface layer of mortar specimen from chemical reaction of acid stained agents. The colors were changed into natural irregular stains according to aging. After the staining, no shape change was found from visible inspections. Microstructure of the colored surface applied with acid stained agent was much rougher than that of original mortar. When the colored layer was compared to original surface, crystals of hydrate such as $Ca(OH)_2$ and C-S-H gel were observed. Surface hardness was same or slightly higher in the colored layer. The value of pH was reduced by approximately 10%, weight contents of elements such as Ca, Si, and Al were low. In the chemical composition of the colored layer, the non-cement based elements of Mn, Cr, and Cu increased. Also, Fe and alkali elements of K and Na increased.