• Title/Summary/Keyword: chemical durability

Search Result 766, Processing Time 0.032 seconds

Durability Characteristics of Limestone Powder added Concrete for Environment-Friendly Concrete (석회석미분말을 첨가한 친환경 시멘트콘크리트의 내구 특성)

  • Choi, Woo Hyeon;Park, Cheol Woo;Jung, Won Kyung;Jeon, Beom Joon;Kim, Gyu Seon
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.16 no.5
    • /
    • pp.59-67
    • /
    • 2012
  • During the manufacturing of Portland cement, CO2 gas is also necessarily produced through both decarbonation of calcium carbonate and kiln burning. By partially replacing the Portland cement with limestone powder, which is an inert filler in a concrete mixture, CO2 consumption can be reduced in a construction field. This study is to investigate the fundamental durability characteristics of limestone powder added concrete. Experimental variable was the replacement ratio of limestone powder from 0% to 25% with 5% increment. Durability characteristics were investigated by resistance to freeze-thaw, alkali-silica reaction and de-icing chemical in addition to the properties of fresh concrete. From test results, it was observed that the addition of limestone powder did not significantly affect the resistance to freeze-thaw reaction and de-icing chemical. The addition of limestone powder reduced the occurrence potential of alkali-silica reaction by reducing an alkali content in Portland cement.

Hypochlorite Production by Using SPEEK/APSf and SPEEK/APEI Bipolar Membranes Modified by the Direct Fluorination (직접 불소화에 의해 표면 개질된 SPEEK/APSf, SPEEK/APEI 바이폴라막을 이용한 차아염소산나트륨 생성)

  • Kim, Ka young;Cheong, Seong Ihl;Rhim, Ji Won
    • Membrane Journal
    • /
    • v.25 no.5
    • /
    • pp.447-455
    • /
    • 2015
  • In this study, Polysulfone (PSf) and polyetherimide (PEI) as the anion exchange polymers were aminated in the different ratio whereas the polyether ether ketone (PEEK) as the cation exchange polymer was sulfonated. The bipolar membranes of SPEEK (sulfonated PEEK)/APSf (aminated PSf) and SPEEK/APEI (aminated PEI) were prepared by the double-casting method. The surfaces of bipolar membranes were fluorinated in accordance with the amination ratio and applied to produce the hypochlorite. As the amination increased, the hypochlorite concentration is also increased. Typically, for SPEEK/APSf 3 : 1 membrane, the produced hypochlorite concentration was 61.0 ppm and its durability was 220 min for the non-fluorinated membrane while for the fluorinated membrane, the concentration of 58.6 ppm and its durability lasted 570 min. Also for SPEEK/APEI 3 : 1 membrane, the hypochlorite concentrations of 60.1 ppm and 58.3 ppm for before- and after-fluorination, respectively were observed whereas the durability was remarkably developed from 150 min to 440 min. Therefore, the surface fluorination takes an important role for the development of the membrane durability.

The Characteristics of the Dehydration Reaction and the Durability for the Thermal Decomposition in Na2B4O7·10H2O/Na2B4O7·5H2O System (Na2B4O7·10H2O/Na2B4O7·5H2O 계의 열분해 탈수반응 및 내구성 고찰)

  • Choi, Ho-Sang;Park, Young-Tae
    • Applied Chemistry for Engineering
    • /
    • v.10 no.6
    • /
    • pp.885-888
    • /
    • 1999
  • This study was carried out to determine the reaction kinetic constant of the dehydration - thermal decomposition of $Na_2B_4O_7{\cdot}10H_2O/Na_2B_4O_7{\cdot}5H_2O$ and to investigate the durability during the repeated use of a chemical heat-storage material and the reproducibility of reaction system. The order of the dehydration reaction was 1st-order. The reaction rate was directly proportional to a partial pressure difference of water steam. The kinetic constant was 0.27 and the reproducibility of dehydration reaction for a kinetic constant and a reaction order was excellent. The activity variation in the durability test of a chemical heat-storage material was within range of ${\pm}5%$ during the repeatedly use in several times.

  • PDF

Shrinkage and Durability Characteristics of Latex Modified Repair Mortar for Agricultural Concrete Structures (농업용 콘크리트 구조물용 라텍스개질 보수용 모르타르의 수축 및 내구성능 평가)

  • Won, Jong-Pil;Lee, Jae-Young;Park, Chan-Gi;Park, Seong-Gi;Kim, Wan-Young
    • Journal of The Korean Society of Agricultural Engineers
    • /
    • v.49 no.5
    • /
    • pp.23-30
    • /
    • 2007
  • This research was to evaluate the shrinkage and durability performance of latex modified repair mortar and to improve the service lift of the agricultural concrete structures. The shrinkage characteristics of the repair material creates the delamination of repair materials and existing concrete. It may reduce the service life of structures. Also the reduction of durability performance of the repair materials induces the destruction of the repaired concrete structures at early stage. In this research, plastic and drying shrinkage, thermal expansion coefficient for shrinkage properties, durability performance, permeability, repeated freezing and thawing, and resistance of chemical solution test were performed. Test results showed that the latex modified repair mortar indicated the shrinkage amount which the delamination does not happen, and the latex modified repair mortar appeared excellent long-term durability performance which can increase the service life.

Prediction of RC structure service life from field long term chloride diffusion

  • Safehian, Majid;Ramezanianpour, Ali Akbar
    • Computers and Concrete
    • /
    • v.15 no.4
    • /
    • pp.589-606
    • /
    • 2015
  • It is well-documented that the major deterioration of coastal RC structures is chloride-induced corrosion. Therefore, regional investigations are necessary for durability based design and evaluation of the proposed service life prdiction models. In this paper, four reinforced concrete jetties exposed to severe marine environment were monitored to assess the long term chloride penetration at 6 months to 96 months. Also, some accelerated durability tests were performed on standard samples in laboratory. As a result, two time-dependent equations are proposed for basic parameters of chloride diffusion into concrete and then the corrosion initiation time is estimated by a developed probabilistic service life model Also, two famous service life prediction models are compared using chloride profiles obtained from structures after about 40 years in the tidal exposure conditions. The results confirm that the influence of concrete quality on diffusion coefficients is related to the concrete pore structure and the time dependence is due to chemical reactions of sea water ions with hydration products which lead a reduction in pore structure. Also, proper attention to the durability properties of concrete may extend the service life of marine structures greater than fifty years, even in harsh environments.

Durability of High Performance Polymer Concrete Composites (Focusing on Chemical Resistance and Hot Water Resistance) (고성능 폴리머 콘크리트 복합재료의 내구성(내약품성 및 내열성을 중심으로))

  • Hwang, Eui-Hwan;Kim, Yong-Yeon;Song, Min-Kyu
    • Applied Chemistry for Engineering
    • /
    • v.28 no.3
    • /
    • pp.360-368
    • /
    • 2017
  • In order to investigate the durability of high performance polymer concrete composites, polymer concrete specimens were prepared using the ortho-type unsaturated polyester resin (UPR) and iso-type UPR as a polymer binder and the calcium carbonate and silica fine powder as a filler. The durability of polymer concrete specimens was measured by hot water resistance, chemical resistance, pore analysis and SEM observation. The compressive strength of the specimen using the iso-type UPR was higher than that of using the ortho-type UPR, and the compressive strength of the specimen using the silica fine powder was higher than that of using the calcium carbonate filler. From hot water resistance results, it was found that the specimen using the iso-type UPR was superior to that of using the ortho-type UPR and the specimen using the calcium carbonate filler was superior to that of using the silica fine powder. The compressive strength reduction rate was measured after the chemical resistance test and the sodium hydroxide solution showed the highest reduction rate, followed by sulfuric acid, hydrochloric acid and calcium chloride solutions. When using the alkaline solution of sodium hydroxide, the weight reduction rate of the specimen using calcium carbonate was lower than that of using silica fine powder, while for the acidic solutions of sulfuric acid and hydrochloric acid, the weight reduction rate of the specimen using the silica fine powder was lower than that of using calcium carbonate.

A Study on improving Effect of Durability Performance Using Penetration waterproofing Agent of Ceramic nano materials (세라믹계 나노물질을 이용한 침투성 방수제의 내구성능 개선효과 연구)

  • Ryu Gum-Sung;Park Jung-Jun;Koh Kyoung-Taek;Kim Do-Gyeum;Lee Jang-Hwa
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2004.05a
    • /
    • pp.176-179
    • /
    • 2004
  • The latest concrete structure has showed that the deterioration of durability has been increased by the damage from salt, carbonization, freezing & thawing and the others. Therefore, the measures for the concrete which has deteriorated durability have been taken. Among them, it has been often used that surface treatment which cuts off the deterioration factors of durability by protecting the surface of concrete. This study was evaluated the surface improving agent for permeability, watertightness, air-permeability, chemical resistance and elution resistance.

  • PDF

Development and Durability Characteristics of FRP Reinforcing Bar for Concrete Structures (콘크리트 보강용 FRP 리바의 개발 및 내구 특성)

  • Won, Jong-Pil;Park, Chan-Gi;Yoon, Jong-Han;Hwang, Kum-Sik;Cho, Yong-Jin
    • Proceedings of the Korean Society of Agricultural Engineers Conference
    • /
    • 2003.10a
    • /
    • pp.371-374
    • /
    • 2003
  • The corrosion of steel reinforcing bar(re-bar) has been the major cause of the reinforced concrete deterioration. FRP(Fiber-reinforced polymer) reinforcing bar has emerged as one of the most promising and affordable solutions to the corrosion problems of steel reinforcement in structural concrete. In this study, long-term durability performance of FRP re-bar were evaluated. The mechanical and durability properties of two type of CFRP- and GFRP re-bar were investigated; the FRP re-bars were subjected to alkaline solution, acid solution, salt solution and deionized water. The mechanical and durability properties were investigated by performing tensile and short beam tests. Experimental results confirmed the desirable resistance of FRP re-bar to aggressive chemical environment.

  • PDF

Development of a Strut Mount with High Reliability by Improving Durability (내구성 향상을 통한 고 신뢰성 Strut Mount 개발)

  • Chung, Chan-Hong
    • Journal of Applied Reliability
    • /
    • v.11 no.1
    • /
    • pp.31-41
    • /
    • 2011
  • A strut mount is an important part of vehicles which reduces the vibration and the impact transmitted from the wheels while supporting a shock absorber and a coil spring. Rubber compounding, shape design, and process design technologies are important components to improve the functionality of a strut mount such as durability, static, dynamic, and torsional characteristics. Among them the rubber compounding technology is the key technology which dominates the quality of a strut mount. In this study a strut mount with high reliability has been developed by adopting new rubber compounding and improving the shape of the inner plate and the isolator. Through the tests for prototypes it has been shown that the durability has been improved more than 2.5 times, from about 60,000 cycles to about 160,000 cycles.

Fabrication of a Porous Carbon Surface Using Ethanol Vapor Treatment (에탄올 증기 처리를 통한 다공성 탄소 표면 제작)

  • Im, Doyeon;Kim, Geon Hwee;An, Taechang
    • Journal of Sensor Science and Technology
    • /
    • v.31 no.4
    • /
    • pp.244-248
    • /
    • 2022
  • Recently, several studies on the development of superhydrophobic surfaces using various nano-sized carbon-based materials have been conducted. The superhydrophobic surfaces developed using carbon soot have advantages such as low processing cost and remarkable physical and chemical properties. However, their durability is low. To address this problem, in this study, a superhydrophobic surface with high durability and a multilayer structure was fabricated using ethanol vapor treatment. Candle soot was deposited on an aluminum substrate coated with paraffin wax, and a micro-nano multilayer structure with a size of several micrometers was fabricated via ethanol vapor treatment. The fabricated superhydrophobic surface was confirmed to have a contact angle of at least 156° and high durability. Finally, it was confirmed that ethanol vapor not only changed the nanostructure of carbon but also affected the durability of the structure.