• Bulletin of the Korean Chemical Society
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• 제21권12호
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• pp.1213-1216
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• 2000

Localized structures with fronts connecting a Turing patterns and Hopf oscillations are found in discrete reaction-diffusion system. The Chorite-Iodide-Malonic Acid (CIMA) reaction model is used for a reaction scheme. Localized structures in discrete reaction-diffusion system have more diverse and interesting features than ones in continuous system. Various localized structures can be obtained when a single perturbation is applied with variation of coupling strength of two intermediates. Roles of perturbations are not so simple that perturbations are sources of both Turing patterns and Hopf oscillating domains, and spatial distribution of them is determined by strength of a perturbation applied initially.

• Bulletin of the Korean Chemical Society
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• 제4권5호
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• pp.228-230
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• 1983

Molecular reorientation of oblate symmetric top molecules with internal rotation is investigated theoretically and an analytic expression for the overall reorientational correlation time in terms of the internal angular momentum correlation time is derived. This expression is quite different from the expression for prolate symmetric top molecules but reduces to the same expression in the spherical top limit. Fast internal rotation is treated by a modified version of the extended rotational diffusion while the bulky symmetric top mainbody is treated by the rotational diffusion model.

• Bulletin of the Korean Chemical Society
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• 제17권4호
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• pp.365-373
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• 1996

Time profile of the transient grating signal induced by a nanosecond pulsed laser excitation of methyl red is investigated in alcohols and toluene at several solvent temperatures. The signal decays biexponentially with well-separated time constants; the faster decay is identified as due to thermal diffusion of the solvents and the slower one as mainly due to translational diffusion of the solute. The measured translational diffusion constants of methyl red in toluene are close to a hydrodynamic prediction with a slip boundary condition while those in alcohols are larger by 30% and increase slightly with the size of alcohols. We compare the results with modified hydrodynamic models.

• Korean Chemical Engineering Research
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• 제57권3호
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• pp.338-343
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• 2019

고분자전해질 연료전지에서 전해질막의 물이동과 함수율은 고분자막의 성능에 많은 영향을 미친다. 본 연구에서는 간단한 방법에 의해 물이동에 관한 고분자막의 물성(전기삼투계수, 물 확산계수)을 측정하고 이들을 이용해 막을 통한 물의 이동량과 이온전도도를 모델식에 의해 모사한 후 실험값과 비교하였다. 물이동의 구동력은 전기삼투와 확산만이 라고 본 1차원 정상상태 지배방정식을 매트랩으로 수치해석하였다. $144{\mu}m$ 두께의 고분자막의 전기삼투계수를 수소펌핑셀에서 구한 결과 1.11을 얻었다. 물확산계수를 상대습도의 함수로 나타냈고 물확산에 대한 활성화에너지는 $2,889kJ/mol{\cdot}K$였다. 이들 계수를 적용해 모사한 물이동량과 이온전도도 결과는 실험값과 잘 일치함을 보였다.

• Computers and Concrete
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• 제10권1호
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• pp.79-93
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• 2012

This paper estimates theoretically the diffusion-reaction behaviour of sulfate ion in concrete caused by environmental sulfate attack. Based on Fick's second law and chemical reaction kinetics, a nonlinear and nonsteady diffusion-reaction equation of sulfate ion in concrete, in which the variable diffusion coefficient and the chemical reactions depleting sulfate ion concentration in concrete are considered, is proposed. The finite difference method is utilized to solve the diffusion-reaction equation of sulfate ion in concrete, and then it is used to simulate the diffusion-reaction process and the concentration distribution of sulfate ion in concrete. Afterwards, the experiments for measuring the sulfate ion concentration in concrete are carried out by using EDTA method to verify the proposal model, and results show that the proposed model is basically in agreement with the experimental results. Finally, Numerical example has been completed to investigate the diffusion-reaction behavior of sulfate ion in the concrete plate specimen immersed into sulfate solution.

• 대한화학회지
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• 제56권6호
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• pp.768-771
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• 2012

• Bulletin of the Korean Chemical Society
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• 제26권2호
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• pp.331-333
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• 2005

• Bulletin of the Korean Chemical Society
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• 제29권5호
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• pp.1059-1062
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• 2008

• Bulletin of the Korean Chemical Society
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• 제22권9호
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• pp.945-947
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• 2001

The He-Xe interaction potential has been determined using a direct inversion of the experimentally reduced-viscosity collision integrals obtained from the corresponding states correlation. The potential is in a good agreement with the previously determined potential. The potential predicts viscosity and diffusion coefficients and they are found to be in a good agreement with experiment.

• 전기화학회지
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• 제5권1호
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• pp.7-12
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• 2002

염수 전해 공정에서 산소음극형 가스화산전극의 적용에 대해 연구, 조사하였다. 가스확산전극은 반응층, 가스확산층, 급 전체로 구성된다. 반응층은 친수성 카본블랙, 소수성 카본블랙, PTFE(polytetrafluoroethylene), 은거울반응이나 함침법에 의해 담지된 은 촉매로 제조하였다. 가스확산충은 소수성 카본블랙과 PTFE로 제조되며, 반응층 내에 사용되는 급전체는 Ni망을 사용하였다. 실험에 의하면 함침법에 의해 Ag촉매를 반응충 카본에 담지시켜 제작된 전극$(Ag\;10wt\%$,바인더 $20wt\%)$이 산소음극 과전압이 약 700mv, 전해조에 장착하여 측정한 전해전압(전해 조건이 $80^{\circ}C,\;32wt\%$ 가성소다 그리고 $300 mA/cm^2$의 전류 밀도)이 약 2.2V로 가장 우수한 결과를 나타내었다. 이는 기존 공정의 전해전압 3.4V에 비해 $30\%$이상 저감된 결과이다. 또한 개발된 가스확산 전극은 염수 분해용 전해 공정에서 3개월 연속 운전이 가능하였다.