• Title/Summary/Keyword: chemical damage

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Corrosion Damage Behavior of STS 304 and STS 415 for Reactor Coolant Pump during Ultrasonic-Chemical Decontamination Process (원자로 냉각재 펌프용 STS 304와 STS 415의 초음파-화학제염 공정 시 부식 손상 거동)

  • Hyeon, Gwang-Ryong;Park, Jae-Cheol;Han, Min-Su;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.51 no.4
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    • pp.218-223
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    • 2018
  • In this study, we proposed a new ultrasonic-chemical decontamination process for decontaminating radioactive corrosion products during the maintenance of reactor coolant pump (RCP). The actual decontamination process was reproduced in the laboratory. And the corrosion characteristics of stainless steel (STS), constituting the RCP interior parts, were examined. The weight-loss measurment and polarization experiment were carried out in order to determine the corrosion characteristics of STS 304 and STS 415 by repeated decontamination processes. The STS 304 presented a little corrosion damage, which was almost indistinguishable from visual observation. The weight-loss rate of STS 304 was also significantly lower. On the other hand, STS 415 showed severe corrosion damage on its surface, greater weight-loss rate and higher corrosion current density than STS 304.

Modeling of time-varying stress in concrete under axial loading and sulfate attack

  • Yin, Guang-Ji;Zuo, Xiao-Bao;Tang, Yu-Juan;Ayinde, Olawale;Ding, Dong-Nan
    • Computers and Concrete
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    • v.19 no.2
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    • pp.143-152
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    • 2017
  • This paper has numerically investigated the changes of loading-induced stress in concrete with the corrosion time in the sulfate-containing environment. Firstly, based on Fick's law and reaction kinetics, a diffusion-reaction equation of sulfate ion in concrete is proposed, and it is numerically solved to obtain the spatial and temporal distribution of sulfate ion concentration in concrete by the finite difference method. Secondly, by fitting the existed experimental data of concrete in sodium sulfate solutions, the chemical damage of concrete associated with sulfate ion concentration and corrosion time is quantitatively presented. Thirdly, depending on the plastic-damage mechanics, while considering the influence of sulfate attack on concrete properties, a simplified chemo-mechanical damage model, with stress-based plasticity and strain-driven damage, for concrete under axial loading and sulfate attack is determined by introducing the chemical damage degree. Finally, an axially compressed concrete prism immersed into the sodium sulfate solution is regarded as an object to investigate the time-varying stress in concrete subjected to the couplings of axial loading and sulfate attack.

Dispute Mediation Cases and Suggestions for Calculating Compensation for Dust Damage (먼지 피해의 환경분쟁조정 사례 분석과 배상액 산정안 제언)

  • Jeong-Ho Park
    • Journal of Environmental Science International
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    • v.32 no.10
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    • pp.693-701
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    • 2023
  • In this study, we analyzed 82 dust damage dispute mediation cases over the past 5 years and evaluated cases where the probability of damage was verified through dust concentration measurement, modeling prediction, and chemical composition analysis. The cause of dust damage was a construction site, which accounted for most of the damage (97%), and was closely related to the distance from the construction site, total floor area of the construction site, and construction duration. Compensation was decided in only 33% of dust damage cases, and in only 6% (five cases) were damages determined using scientific techniques such as dust measurement, and forecasting. The main criteria for determining compensation were whether administrative measures were taken and evidence of damage in the form of videos and photos. In the future, measuring or model for the amount of dust damage is necessary to determine whether the limit has been exceeded and to revise the standard for calculating compensation through various lines of evidence of dust damage.

Effect of N2/Ar flow rates on Si wafer surface roughness during high speed chemical dry thinning

  • Heo, W.;Lee, N.E.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.128-128
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    • 2010
  • In this study, we investigated the evolution and reduction of the surface roughness during the high-speed chemical dry thinning process of Si wafers. The direct injection of NO gas into the reactor during the supply of F radicals from NF3 remote plasmas was very effective in increasing the Si thinning rate, due to the NO-induced enhancement of the surface reaction, but resulted in the significant roughening of the thinned Si surface. However, the direct addition of Ar and N2 gas, together with NO gas, decreased the root mean square (RMS) surface roughness of the thinned Si wafer significantly. The process regime for the increasing of the thinning rate and concomitant reduction of the surface roughness was extended at higher Ar gas flow rates. In this way, Si wafer thinning rate as high as $20\;{\mu}m/min$ and very smooth surface roughness was obtained and the mechanical damage of silicon wafer was effectively removed. We also measured die fracture strength of thinned Si wafer in order to understand the effect of chemical dry thinning on removal of mechanical damage generated during mechanical grinding. The die fracture strength of the thinned Si wafers was measured using 3-point bending test and compared. The results indicated that chemical dry thinning with reduced surface roughness and removal of mechanical damage increased the die fracture strength of the thinned Si wafer.

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A Study on the Effect of Damages on the Conditions of Dike in the Leakage of Hydrochloric Acid Storage Tank (염산 저장탱크 누출 시 방류벽 조건에 따른 피해영향 연구)

  • Kang, Jungchun;Kim, Seungha;Kim, KyuHwan;Kim, YeonSoo;Kwon, Donguk
    • Korean Journal of Hazardous Materials
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    • v.6 no.2
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    • pp.7-12
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    • 2018
  • Hydrochloric acid is a highly corrosive toxic substance and requires proper safety to minimize damage in case of leakage. Among the various risk-reduction facilities, the dike is a typical safety facility installed to protect the surrounding buildings and facilities by preventing the external spread of hazardous materials from the storage tank. In this study, the KORA program was used to assume leakage accident of hydrochloric acid storage tank. At this time, the extent of the damage effects of ERPG-2 were assessed for each of the three separation distance between the storage tank and the dike. The study found that the smaller the separation distance between the dike and the storage tank, the smaller the extent of damage caused by hydrochloric acid leakage, and the greater the impact of indoor conditions under the same conditions. Through this process, we are going to assist in selecting locations and installing facilities for new and existing businesses.

Effect of damage on permeability and hygro-thermal behaviour of HPCs at elevated temperatures: Part 2. Numerical analysis

  • Gawin, D.;Majorana, C.E.;Pesavento, F.;Schrelfer, B.A.
    • Computers and Concrete
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    • v.2 no.3
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    • pp.203-214
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    • 2005
  • In the Part 1 paper (Gawin, et al. 2005) some experimental results concerning micro-structural tests, permeability measurements and stress-strain tests of four types of High Performance Concrete, exposed to elevated temperatures (up to $700^{\circ}C$) are presented and discussed. On the basis of these experimental results parameters of the constitutive relationships describing influence of damage and temperature upon material intrinsic permeability at high temperature were determined. In this paper the effects of various formulations of damage-permeability coupling on results of computer simulations are analysed and compared with the results obtained by means of the previously proposed approach, that does not take into account the thermo-chemical concrete damage directly. Numerical solutions are obtained using the recently developed fully coupled model of hygro-thermal and damage phenomena in concrete at elevated temperatures. High temperature effects are considered by means of temperature and pressure dependence of several material parameters. Based on the mathematical model, the computer code HITECOSP was developed. Material parameters of the model were measured by several European laboratories, which participated in the "HITECO" research project. A model problem, concerning hygro-thermal behaviour and degradation of a HPC structure during fire, is solved. The influence of two different constitutive descriptions of the concrete permeability changes at high temperature, including thermo-chemical and mechanical damage effects, upon the results of computer simulations is analysed and discussed.

Numerical simulations of progression of damage in concrete embedded chemical anchors

  • Sasmal, S.;Thiyagarajan, R.;Lieberum, K.H.;Koenders, E.A.B.
    • Computers and Concrete
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    • v.22 no.4
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    • pp.395-405
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    • 2018
  • In this paper, the performance of post-installed adhesive bonded anchor embedded in concrete is assessed using numerical simulations. This study aims at studying the influence of parameters on the performance of a chemically bonded anchorage system. Non-linear finite element modelling and simulations are carried out by properly using the material properties and phenomenon. Materials parameters such as characteristic length, fracture energy, damage criteria, tension retention and crack width of concrete and interface characteristics are carefully assigned so as to obtain a most realistic behaviour of the chemical anchor system. The peak strength of two different anchor systems obtained from present numerical studies is validated against experimental results. Furthermore, validated numerical models are used to study the load transferring mechanism and damage progression characteristics of various anchors systems where strength of concrete, strength of epoxy, and geometry and disposition of anchors are the parameters. The process of development of strain in concrete adjacent to the anchor and energy dissipated during the course of damage progression are analysed. Results show that the performance of the considered anchorage system is, though a combined effect of material and geometric parameters, but a clear distinction could be made on the parameters to achieve a desired performance based on strength, slip, strain development or dissipated energy. Inspite the increase in anchor capacity with increase in concrete strength, it brings some undesirable performance as well. Furthermore, the pullout capacity of the chemical anchor system increases with a decrease in disparity among the strength of concrete and epoxy.

Curl Wave Formation and Hair Damage by the Rinsing (중간 세척이 컬 웨이브 형성과 모발 손상에 미치는 영향)

  • Moon, Soon-Joo;Kim, Min-Joung
    • Journal of the Korean Society of Fashion and Beauty
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    • v.4 no.3 s.9
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    • pp.13-17
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    • 2006
  • Perm is one the of the most common thing in a beauty salon like hair-cut and hair perm needs processing solutions which is chemical substances. Those chemical substances damage the hair cuticle. Damaged hair cuticles with mistakes of perm will follow with the next performance and it will cause more damage to hair. As damage of hair cuticle become worse, it is harder to recover the hair cuticle like before. Therefore, this study shows that plain rinse is the way to reduce the damage of hair cuticle with perm as much as possible. With experiments, I suggest the right way to do plain rinse to satisfy customers' demand and reduce the damage. During the research, I figured that plain rinse with the knowledge, structure of hair cuticle, principle of perm and plain rinse, is very needed. The hair with plain rinse have more elastic curl and have less scales which came off from hair cuticle than the hair without plain rinse. This experiment concludes that hairdresser has to figure out about the time, temperature and type of water depends on the degree of damaged hair of customers. In order to perm, there is no way to not to use chemical substances to perm. Therefore, hairdresser has to choose suitable processing solutions and right steps, and as this is the age of 'well-being' boom, hairdresser must try to keep the healthy hair. Consequently, in order to meet the demands and conditions of customers, hairdresser needs to find the right method to do plain rinse and use the method in perm.

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Laser via drilling technology for the EWT solar cell (EWT 태양전지 제작을 위한 레이저 미세 관통홀 가공 기술)

  • Lee, Hong-Gu;Seo, Se-Young;Hyun, Deoc-Hwan;Lee, Yong-Wha;Kim, Gang-Il;Jung, Woo-Won;Lee, Ah-Reum;Cho, Jaee-Ock
    • Journal of the Korean Solar Energy Society
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    • v.31 no.4
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    • pp.103-111
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    • 2011
  • Laser drilling of vias is the one of key technologies in developing Emitter-Wrap Through(EWT) solar cell which is particularly attractive due to the use of industrial processing and common solar grade p-type silicon materials. While alternative economically feasible drilling process is not available to date, the processing time and laser induced damage should be as small as possible in this process. This paper provides an overview on various factors that should be considered in using the laser via drilling technology for developing highly efficient and industrially applicable EWT solar cells.

Experimental and numerical investigation into the damage response of composite sandwich panels to low-velocity impact

  • Feng, Dianshi;Aymerich, Francesco
    • Structural Monitoring and Maintenance
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    • v.4 no.2
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    • pp.133-151
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    • 2017
  • The paper describes the results of an experimental and numerical investigation into the structural and damage response of sandwich composites to low-velocity impact. Sandwich panels consisting of laminated composite skins with three different layups bonded to a PVC foam core were subjected to impact at various energy levels corresponding to barely visible impact damage (BVID) in the impacted skins. Damage assessment analyses were performed on the impacted panels to characterise the extent and the nature of the major failure mechanisms occurring in the skins. The data collected during the experimental analyses were finally used to assess the predictive capabilities of an FE tool recently developed by the authors for detailed simulation of impact damage in composite sandwich panels. Good agreement was observed between experimental results and model predictions in terms of structural response to impact, global extent of damage and typical features of individual damage mechanisms.