• Title/Summary/Keyword: chemical damage

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Corrosion Damage Characteristics with Materials and Process Time in Ultrasonic-Chemical Decontamination of Immersion Type (침적식 초음파-화학 제염 시 재료 및 공정 시간에 따른 부식 손상 특성)

  • Lee, Seung-Jun;Hyun, Koangyong;Han, Min-Su;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.51 no.5
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    • pp.291-296
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    • 2018
  • In this study, we carried out an ultrasonic-chemical decontamination process with immersion type, reproduced in the laboratory. The corrosion damage characteristics, depending on kind of materials and ultrasonic process time, were investigated. Inconel 600, which showed lower corrosion potential and higher corrosion current density than that of STS 316, revealed severer corrosion damage and higher weight-loss rate than STS 316. Weight-loss rate of Inconel 600 increased with increasing ultrasonic process time. On the other hands, STS 316 presented a negligibly small corrosion damage, which was almost indistinguishable from visual observation. There was no effect of ultrasonic process time on the weight-loss rate of STS 316.

Evaluation of Damage Range Variation Based on Operation System of Chlorine Facility in Water Purification Plant using KORA (KORA를 활용한 정수장 염소 취급시설의 운영조건에 따른 피해범위 변화 평가)

  • Kwak, Sollim;Lim, Hyeongjun;Ryu, Taekwon;Choi, Woosoo;Jung, Jinhee;Lee, Jieun;Kim, Jungkon;Lee, Yeonhee;Ryu, Jisung;Yoon, Junheon;Yoon, Yi;Lee, Jinseon
    • Journal of the Korean Institute of Gas
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    • v.22 no.3
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    • pp.84-90
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    • 2018
  • We researched the way to minimize the damage when the chlorine-leak accident take place in a purification plant. Since the level of risk based on the Off-site Risk Assessment(ORA) is a combination of proportional to the number of residents in the damaged area and frequency of accidents, we suggested the adequate conditions to reduce the number of residents in the damaged area by means of the operating temperature of a handling facility, installation of a emergency shut-off valve, and the analysis of the variation of the damaging range in accordance with the type of enclosure. The coverage of damage was calculated by the 'KORA(Korea Off-site Risk Assessment Supporting Tool) program. The research shows that the lower operating temperature gets, the more emergency shut-off valve being installed and the higher enclosure level of facility becomes, the extent of damage gets decreased. The decreasing rate of worst case was 17.6%, 71%, 34.5% respectively, the decreasing rate of alternative case was 31.6%, 69.0%, 34.8% respectively.

Damage Characteristics of Metal Specimens by Formaldehyde (포름알데히드에 의한 금속시편의 손상 특성)

  • Kim, Myoung Nam;Lim, Bo A;Lee, Sun Myung
    • Journal of Conservation Science
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    • v.31 no.3
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    • pp.287-298
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    • 2015
  • The formaldehyde is damage to the metal are known universally. However, the quantification of the damage level and degree of damage is not clear. This study was conducted to test the following steps using a gas corrosion tester, and then evaluated by the optical, chemical and physical measurement. First, it was confirmed the damage level of the metal specimen(silver, copper, iron, lead, brass) by the formaldehyde(0.5, 1, 10, 100, 500ppm). Second, weighted damage to the metal specimens were tested according to the temperature and humidity conditions under damage levels. Third, the damage of accelerated degradation metal specimens were examined under damage levles. As a result, at 500ppm / day, the optical, chemical and physical damage of lead have been identified, the optical damage of all metals are was observed. The optical damage of some specimens were weighted in $25^{\circ}C-50%$, $30^{\circ}C-50%$. Chemical damage to the lead specimen is 2.8 times, 1.3 times were weighted in $30^{\circ}C-80%$, $25^{\circ}C-80%$. Referring to formate ion concentration of the accelerated degradation metal, corrosion products of iron and brass were actived the reaction of the formaldehyde gas, oxide film of lead was blocked the reaction of formaldehyde gas.

Development of a numerical modelling technique for evaluation of a long-term chemical deterioration of tunnel shotcrete lining (터널 숏크리트 라이닝의 장기 화학적 열화 손상 평가를 위한 수치 모델링 기법 개발)

  • Shin, Hyu-Soung;Kim, Dong-Gyou
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.9 no.3
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    • pp.299-307
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    • 2007
  • In this study, a new concept for simulating a physical damage of tunnel shotcrete lining due to a long-term chemical deterioration has been proposed. It is known that the damage takes place mainly by internal cracks, reduction of stiffness and strength, which results mainly from volume expansion of the lining and corrosion of cement materials, respectively. This damage mechanism of shotcrete lining appears similar in most kinds of chemical reactions in tunnels. Therefore, the mechanical deterioration mechanism induced by a series of chemical reactions was generalized in this study and mathematically formulated in the framework of thermodynamics. The numerical model was implemented to a 3D finite element code, which can be used to simulate behaviour of tunnel structures undergoing external loads as well as chemical deterioration in time. A number of illustrative examples were given to show a feasibility of the model in tunnel designs.

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A Study on Total Hazard Level Algorithm Development for Hazardous Chemical Substances (유해화학물질의 종합위해등급 알고리즘 개발에 관한 연구)

  • 고재선;김광일;정상태
    • Fire Science and Engineering
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    • v.14 no.4
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    • pp.7-16
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    • 2000
  • In the study, three criteria(toxicity, fire & explosion, environment) and damage prediction method for each case was set up, and all these criteria were applied to the subject substance that was selected as hazardous level by integrating all criteria through Algorithm. Particularly, the environment criterion is a comprehensive concept, environment index modeling by combining USCG(United State Coast Guard) & MSDS(Material Safety Data Sheet) environment criteria classifications and the environment part of MFPA's health hazardousnes(Nh). And for damage prediction method of each criterion were adopted and they were applied to hazardous chemical substances in use or stored by chemical substance related enterprises located in each region that made possible to set up total hazard level of used substances(inflammability, poisonousness and counteraction on a unit substance, and hazard level & display modeling on environment) & damage prediction in case of accident & solidity setup(CPQRA: Chemical Process Quantitative Risk Assessment, IAEA: International Atomic Energy Agency, VZ eq: Vulnerable Zone) risk counter. Thus it is deemed that it can be applied to toxic substance leakage that can happen during any chemical processing & storage, application as a tool for prior safety evaluation through potential dangerousness computation of fire & explosion.

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Life History, Ginseng Damage and Chemical Control of the Snail Acusta despecta sieboldiana (명주달팽이의 생활사, 인삼의 피해 및 약제 방제)

  • 김기황
    • Journal of Ginseng Research
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    • v.16 no.2
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    • pp.146-150
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    • 1992
  • Life history, ginseng damage, and chemical control of the snail Acusta despecta sieboldiana Pfeiffer were investigated in the field and laboratory conditions from 1987 to 1990. Eggs of the snail were whitish globular and 1.,93${\pm}$ 0.09 mm in diameter which were deposited as egg mass composed of 28.4${\pm}$ 15.4 eggs. Egg period was 11.8${\pm}$ 1.6 days under the laboratory condition. Most eggs were laid during mid July in the field. The snail had a life cycle of a year and hibernated from November to April. Significant ginseng damages by the snail (over 10% to the total number of plants) were observed only in the three to five year old ginseng fields with rice straw mulching. Based on the dates that the first ginseng damages were observed and on the questionary examination, ginseng damages seemed to occur from May to July. Metaldehyde (6%) bait showed reliable control effects on the snail.

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A Study of Chemical Mechanical Polishing on Shallow Trench Isolation to Reduce Defect (CMP 연마를 통한 STI에서 결함 감소)

  • 백명기;김상용;김창일;장의구
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.501-504
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    • 1999
  • In the shallow trench isolation(STI) chemical mechanical polishing(CMP) process, the key issues are the optimized thickness control within- wafer-non-uniformity, and the possible defects such as nitride residue and pad oxide damage. These defects after STI CMP process were discussed to accomplish its optimum process condition. To understand its optimum process condition, overall STI related processes including reverse moat etch, trench etch, STI filling and STI CMP were discussed. It is represented that the nitride residue can be occurred in the condition of high post CMP thickness and low trench depth. In addition there are remaining oxide on the moat surface after reverse moat etch. It means that reverse moat etching process can be the main source of nitride residue. Pad oxide damage can be caused by over-polishing and high trench depth.

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Simulation and Damage Analysis of an Accidental Jet Fire in a High-Pressure Compressed Pump Shelter

  • Jang, Chang Bong;Choi, Sang-Won
    • Safety and Health at Work
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    • v.8 no.1
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    • pp.42-48
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    • 2017
  • Background: As one of the most frequently occurring accidents in a chemical plant, a fire accident may occur at any place where transfer or handling of combustible materials is routinely performed. Methods: In particular, a jet fire incident in a chemical plant operated under high pressure may bring severe damage. To review this event numerically, Computational Fluid Dynamics methodology was used to simulate a jet fire at a pipe of a compressor under high pressure. Results: For jet fire simulation, the Kemeleon FireEx Code was used, and results of this simulation showed that a structure and installations located within the shelter of a compressor received serious damage. Conclusion: The results confirmed that a jet fire may create a domino effect that could cause an accident aside from the secondary chemical accident.

Metallothionein Induces Site-specific Cleavages in tRNAPhe

  • Seon, Jung-Yun;Koh, Moon-Joo
    • Bulletin of the Korean Chemical Society
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    • v.26 no.6
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    • pp.921-924
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    • 2005
  • It is known that metallothionein (MT) plays a role in the scavenging of free radicals, which is produced under various stress conditions. MT may function as an antioxidant that protects against oxidative damage of DNA, protein, and lipid induced by superoxide anion, hydrogen peroxide, hydroxyl radical, nitric oxide, and peroxynitrite. This study was undertaken to test the hypothesis that MT also protects from RNA damage induced by peroxynitrite, an important reactive nitrogen species that causes a diversity of pathological processes. A cell-free system was used. RNA damage was detected by the mobility of $tRNA^{Phe}$ in electrophoresis. Cleavages on tRNA were not induced by 3-morpholinosydnomine, which produces peroxynitrite directly. MT induced tRNA damage which was site specific.

An Analysis on the Appropriation of Chemical Accident Evacuation Facility Using GIS - focused on Ulsan metropolitan city - (GIS 기법을 활용한 화학사고 대피시설의 적정성 분석 - 울산광역시를 대상으로 -)

  • SONG, Bong-Geun;LEE, Tae-Wook;KIM, Hyun-Ju;KIM, Tai-Hoon
    • Journal of the Korean Association of Geographic Information Studies
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    • v.21 no.1
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    • pp.71-82
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    • 2018
  • The purpose of this study is to minimize damage of chemical accidents through the appropriation analysis of evacuation facility position focused on Ulsan metropolitan city. For analysis, informations such as pollutant release and transfer registers(PRTR), population census, and evacuation facilities were used. After then, damage assessment of chemical accidents, accessibility and appropriation of evacuation facilities were analyzed. Damage of chemical accidents is high in around 5km of industrial complex there is dense of chemical facility and population. Evacuation facilities were mainly situated in hazard area of chemical accidents, but accessibility of evacuation facilities was vulnerable in chemical plant neighborhood. Therefore, safety check of deteriorated plants is important for prevention of chemical accidents. Also, effective evacuation plan considering capacity and scale of evacuation facilities will be established.