• Bulletin of the Korean Chemical Society
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• v.17 no.4
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• pp.347-348
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• 1996

A set of substituent constants, σc+, has been widely used comparing the stability of carbocation in super acid condition. Plotting of 13C chemical shifts of cationic carbon (Δδc+) against σc+ constants yields an excellent correlation with a good correlation coefficient (r=0.999) for a cyclopentyl cation system. But these σc+ constants show poor linearity in norbornenyl cations that well known to show homoallylic stabilization in a cationic condition. We calculated the new substituent constant, σc+π, and found that the new substituent constants give an excellent correlation in π- and πσ-participating cation systems.

• Bulletin of the Korean Chemical Society
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• v.24 no.9
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• pp.1243-1244
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• 2003

• Bulletin of the Korean Chemical Society
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• v.24 no.9
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• pp.1345-1350
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• 2003

Principal component analysis based two-dimensional (PCA-2D) correlation analysis is applied to FTIR spectra of polystyrene/methyl ethyl ketone/toluene solution mixture during the solvent evaporation. Substantial amount of artificial noise were added to the experimental data to demonstrate the practical noise-suppressing benefit of PCA-2D technique. 2D correlation analysis of the reconstructed data matrix from PCA loading vectors and scores successfully extracted only the most important features of synchronicity and asynchronicity without interference from noise or insignificant minor components. 2D correlation spectra constructed with only one principal component yield strictly synchronous response with no discernible a asynchronous features, while those involving at least two or more principal components generated meaningful asynchronous 2D correlation spectra. Deliberate manipulation of the rank of the reconstructed data matrix, by choosing the appropriate number and type of PCs, yields potentially more refined 2D correlation spectra.

• Bulletin of the Korean Chemical Society
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• v.26 no.4
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• pp.629-633
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• 2005

In the reversed-phase chromatography, the retention time of sample was investigated based on the molecular structure of compound. Several descriptors that were related to retention factors were selected, and then the values of descriptors were calculated with several softwares. The effect of retention factor was measured with calculated values, and the results were obtained that each descriptors of molecular structure of compound have different effect on the retention factor. Therefore, the empirical equation for seven types of descriptors considered was obtained, and it has high values of correlation coefficient. Furthermore, the experimental data and calculated values have good agreement.

• Journal of Electrical Engineering and Technology
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• v.8 no.3
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• pp.588-594
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• 2013

Under the condition of Baader aging, the chemical composition variation and the influence of transformer oil aging on electrical properties such as dielectric loss factor and physic-chemical properties such as interfacial tension were studied in the aging precess. Moreover, the correlation between hydrogenated transformer oil electrical and physic-chemical properties and its chemical composition variation were also investigated. The results show that these parameters of physic-chemical and electrical properties of hydrogenated transformer oil relate to each other and have closed correlation with chemical composition.

• Journal of The Korean Society of Agricultural Engineers
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• v.54 no.2
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• pp.127-135
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• 2012

The processes of chemical and physical weathering occur simultaneously. The objective of this study was to estimate the degree weathered using fractal dimension through comparison with chemical characteristic of soil samples from Pohang (PH) and Kimpo (KP). Comparing chemical characteristics with fractal dimension, $SiO_2$, $Na_2O$, $K_2O$ content decreased and loss of ignition increased as fractal dimension increased. And fractal dimension showed high correlation with CWI while ATI, STI CIW, PI, CIA and RR demonstrated different degrees of correlation with fractal dimension. The tendency of the changes in oxide content and chemical weathering index with increasing fractal dimension appeared to be similar with the chemical changes due to weathering. Therefore, fractal dimension could be a good indicator representing the extent of weathering and chemical changes.

• Bulletin of the Korean Chemical Society
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• v.22 no.8
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• pp.807-815
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• 2001

Two-dimensional (2D) correlation method, which generates the synchronous and the asynchronous 2D spectrum by complex cross correlation of the Fourier transformed spectra, is an analysis method for the changes of the sample spectrum induced by vari ous perturbations. In the present work, the 2D electronic correlation spectra have been simulated for the cases where the sample spectrum composed of two gaussian bands changes linearly. When only the band amplitudes of the sample spectrum change, the synchronous spectrum shows strong peaks at the band centers of the sample spectrum, but the asynchronous spectrum does not make peaks. When the sample spectrum shifts without changing intensity and width, the synchronous spectrum shows peaks around the initial and final positions of the band maximum and the asynchronous spectrum shows long peaks spanning the shifting range. The band width change produces the complex 2D correlation spectra. When the sample spectrum shifts with band broadening, the width change by 50% of full width at half maximum (FWHM) does not give so large an effect on the correlation spectrum as the spectral shift by one half of FWHM of the sample spectrum.

• Journal of The Korean Society of Agricultural Engineers
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• v.55 no.2
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• pp.37-45
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• 2013

The aim of this study was to investigate chemical characteristic of livestock compost in association with livestock manure types (poultry, cattle, swine, and mixed manure). The livestock compost was collected from local nonghyup branches on a si-gun level. Chemical composition (nutrients, heavy metals etc.) of the samples was analyzed and Pearson's correlation analysis was performed. Quality of most compost samples met the standard of fertilizer specifications. Poultry compost contains greater nutrients especially $P_2O$ (p-value<0.01) and $NH_4$-N (p-value<0.05). Meanwhile swine compost has higher concentration in water content (p-value<0.05) and heavy metals (p-value<0.01 for Cd, Cu and Zn). Overall, poultry compost was correlated positively with nutrients while swine compost has positive correlation with water content and heavy metals. We expect that the study results can provide base data for determining compost types and amount for crop production.

• Korean Chemical Engineering Research
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• v.53 no.6
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• pp.814-817
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• 2015

A new ionic mass transfer correlation is derived for the fluid-saturated, horizontal porous layer. Darcy-Forchheimer model is used to explain characteristics of fluid motion. Based on the microscales of turbulence a backbone mass transfer relation is derived as a function of the Darcy-Rayleigh number, $Ra_D$ and the porous medium Schmidt number, $Sc_p$. For the Darcy's limit of $Sc_p{\gg}Ra_D$, the Sherwood number, Sh is a function of $Ra_D$ only. However, for the region of high $Ra_D$, Sh can be related with $Ra_DSc_p$. Based on the present backbone equation and the electrochemical mass transfer experiments which are electro plating or electroless plating, the new ionic mass transfer correlation is suggested in the porous media.

• 한국전기화학회:학술대회논문집
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• 2002.07a
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• pp.129-134
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• 2002

The present paper highlights on the need to understand the correlation of the characteristics of the catalyst layer with the performance of the polymer electrolyte membrane fuel cell. The paper deals with the correlation of the platinum loading in the catalyst layer and the performance of the Polymer Electrolyte Membrane Fuel Cell(PEMFC) and also the correlation of the required hydrophiliticityihydrophobicity in the catalyst layer to get the optimum performance under given operating conditions.