• 제목/요약/키워드: chemical correlation

검색결과 2,059건 처리시간 0.038초

대기중의 휘발성 유기물 제거용 분리막 (Membrane for the Removal of Volatile Organic Compounds from Air)

  • Deng, S.;Lang, K.;Wang, J.;Tremblay, A.;Matsuura, T.
    • 멤브레인
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    • 제7권1호
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    • pp.22-30
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    • 1997
  • Porous asymmetric membranes were prepared from polyetherimide polymer by the phase-inversion technique under different conditions. The performance of the membranes was tested for the removal of acetone vapour from nitrogen. A membrane which showed a high acetone permeability and a high selectivity was chosen and tested further for the separation of different organic vapours from nitrogen. The molecular structure of organic vapours and the selectivity were correlated. A strong correlation was also found between the chromatographic retention time of the organic vapour and the selectivity. These experimental results led to the conclusion that the sorption is the factor governing the separation of volatile organic compounds from nitrogen. A membrane was also prepared by coating the surface of a porous polyetherimide membrane with silicone rubber. The performance of membranes with and without silicone rubber coating was compared.

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Effect of elasticity of aqueous colloidal silica solution on chemical absorption of carbon dioxide with 2-amino-2-methyl-1-propanol

  • Park, Sang-Wook;Choi, Byoung-Sik;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • 제18권3호
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    • pp.133-141
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    • 2006
  • Carbon dioxide was absorbed into the aqueous nanometer sized colloidal silica solution of 0-31 wt% and 2-amino-2-methyl-1-propanol of $0-2kmol/m^3$ in a flat-stirred vessel with the impeller of various sizes and speeds at $25^{\circ}C$ and 0.101 MPa to measure the absorption rate of $CO_2$. The volumetric liquid-side mass transfer coefficient$(k_La)\;of\;CO_2$ was used to obtain the empirical correlation formula containing the rheological behavior of the aqueous colloidal silica solution. Reduction of the measured $k_La$ was explained by the viscoelastic properties of the aqueous colloidal silica solution. The theoretical value of the absorption rate of $CO_2$ was estimated from the model based on the film theory accompanied by chemical reaction and compared with the measured value.

플라이애시 생산지 및 로트별 화학조성과 모르타르 활성도 지수의 상관관계 분석 (Analysis of correlation between activity factor ash and chemical composition by location and lot in fly ash)

  • 김환수;박광훈;송용순;강석화
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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    • pp.307-308
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    • 2010
  • 본 연구는 플라이애시 생산지 및 로트별 품질변화에 따른 콘크리트 압축강도 발현 특성에 미치는 요인을 분석하기 위한 기초연구로, 플라이애시 생산지 및 로트별 모르타르 활성도 지수와의 상관관계를 검토하였다.

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골재 미립분에 포함된 토분의 분석방법 고찰 (A Study on the Analysis Method of Soil Dust Included in the Aggregate Fines)

  • 민태범;김인;이재삼;백철승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 봄 학술논문 발표대회
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    • pp.257-258
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    • 2023
  • As a result of examining research contents related to soil excretion being studied in Korea, there are five methods for soil excretion testing. As a result of analyzing the correlation between each test method and concrete compressive strength, the chemical test method and the Methylene blue test showed a high correlation index.

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Cyanide-Bridged CrIIIMnII Binuclear Complexes Based on [Mn(phen)2]2+ and Dicyanidechromate(III) Building Blocks: Syntheses, Crystal Structures, and Magnetic Properties

  • Li, Guo-Ling;Zhang, Li-Fang;Ni, Zhong-Hai;Kou, Hui-Zhong;Cui, Ai-Li
    • Bulletin of the Korean Chemical Society
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    • 제33권5호
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    • pp.1675-1680
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    • 2012
  • Three new cyanide-bridged $Cr^{III}Mn^{II}$ binuclear complexes, $[Mn(phen)_2Cl][Cr(bpmb)(CN)_2]{\cdot}H_2O$ ($\mathbf{1}$) (phen = 1,10-phenanthroline, $bpdmb^{2-}$ = 1,2-bis(pyridine-2-carboxamido)-4-methyl-benzenate), $[Mn(phen)_2Cl][Cr(bpmb)-(CN)_2]{\cdot}H_2O$ ($\mathbf{2}$) ($bpdmb^{2-}$ = 1,2-bis(pyridine-2-carboxamido)-4,5-dimethyl-benzenate), and $[Mn(phen)_2Cl]-[Cr(bpClb)(CN)_2]{\cdot}CH_3OH{\cdot}H_2O$ ($\mathbf{3}$) ($bpClb^{2-}$ = 1,2-bis(pyridine-2-carboxamido)-4-chloro-benzenate) were obtained based on $Mn(phen)_2Cl_2$ and a series of dicyanidechromate(III) building blocks. Single crystal X-ray diffraction analysis shows the structures of the three complexes are dimeric type with two different metal centers linked by a cyanide group from corresponding dicyanidechromate(III) building block. Magnetic investigations indicate the existence of relatively weak antiferromagnetic coupling between Cr(III) and Mn(II) ions with best-fit constants $J_{CrMn}=-2.78(5)cm^{-1}$ for $\mathbf{1}$, $J_{CrMn}=-3.02(2)cm^{-1}$ for $\mathbf{2}$ and $J_{CrMn}=-2.27(3)cm^{-1}$ for $\mathbf{3}$ based on the spin exchange Hamiltonian = $-2J_{CrMn}\hat{S}_{Cr}\hat{S}_{Mn}$. The magneto-structural correlation of cyanide-bridged $Cr^{III}Mn^{II}$ complexes has been discussed at last.

경남지역 과수원 토양 화학성분이 미생물 생태에 미치는 영향 (Response of Microbe to Chemical Properties from Orchard Soil in Gyeongnam Province)

  • 이영한;장용선
    • 한국토양비료학회지
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    • 제44권2호
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    • pp.236-241
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    • 2011
  • 경남지역 과수원 토양 25개소를 대상으로 2010년에 토양 화학성분과 미생물 다양성을 검토하고 토성, 지형 및 작물별 주요 변동요인을 주성분분석으로 해석하였다. 토양 유효인산 및 치환성 칼륨 함량은 적정수준 보다 각각 2.6배 및 2.3배 높았으며 대부분 토양 화학성분의 최소값과 최대값 차이가 크게 나타났다. 지형적으로 산록경사지는 토양 유효인산 함량이 유의적으로 높았고 (p<0.05) 미사질양토에서 곰팡이와 형광성 슈도모나스균 개체수가 사양토 보다 유의적으로 높았다 (p<0.05). 주성분 분석결과 제 1주성분이 28.4%, 제 2주성분이 20.1%로서 전체 48.5%의 자료를 설명할 수 있었으며 제 1주성분은 토양의 세균 개체수가 가장 크게 기여하였다. 토양 유기물 함량은 곰팡이 개체수와 정의상관을 보인 반면 세균 개체수와 부의상관을 나타냈다.

Correlations among Shearing Force, Morphological Characteristic, Chemical Composition, and In situ Digestibility of Alfalfa (Medicago sativa L) Stem

  • Liu, L.;Yang, Z.B.;Yang, W.R.;Jiang, S.Z.;Zhang, G.G.
    • Asian-Australasian Journal of Animal Sciences
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    • 제22권4호
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    • pp.520-527
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    • 2009
  • Alfalfa (Medicago sativa L) is a high-quality forage for ruminants and the main stem is the dominant morphological component contributing to the forage nutritive value in mature alfalfa forage. Shearing force, a fracturing property of plant stem, is an important indictor of forage value. The objectives of this study were to investigate the effects of morphological characteristic on shearing force, the relationship between shearing force and chemical composition, and the relationship between shearing force and in situ digestibility of alfalfa stem. The results showed that linear density (weight per unit length of stem) was more important than chemical composition in affecting shearing force. There was a positive relationship between lignin content and shearing force (r = 0.78). Correlations were not found between shearing force and other chemical components such as neutral detergent fiber (NDF), acid detergent fiber (ADF), cellulose and hemicelluloses. In situ digestibility (of dry matter and NDF) was related to shearing force. A negative correlation was found between shearing force and dry matter (DM) digestibility (r = -0.70), and there was also a negative correlation between shearing force and NDF digestibility (r = -0.87). When shearing force was standardized for stem diameter or stem linear density, the relationship between shearing force and digestibility was consistent regardless of stem diameter and stem linear density. Shearing force was significantly correlated with lignin content and in situ digestibility (of DM and NDF), and was a more direct indicator for estimating forage nutritive value related to animal performance, so it can be used to predict the forage value of alfalfa.

Vitamin C Tablet Assay by Near -Infrared Reflectance spectrometry

  • Kargosha, Kazem;Ahmadi, Hamid;Nemati, Nader
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.4111-4111
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    • 2001
  • When a drug is prepared in a tablet, the active component represents only a small portion of the dosage form. The other components of the formulation include materials to assist in the dissolution, antioxidants, coloring agents and bulk fillers. The tablets are tested using approved testing methods usually involving separation and subsequent quantification of the active component. Tablets may also be tested by near-Infrared Reflectance spectrometry (NIRS). In the present study, based on NIRS and multivariate calibration methods, a novel and precise method is developed for direct determination of ascorbic acid in vitamin C tablet. Two different tablet formulations were powdered in three different sizes, 63-125 ${\mu}{\textrm}{m}$, and examined. Spectral region of 4750-4950 $cm^{-1}$ / was used and optimized for quantitative operations. Partial least squares (PLS) and multiple linear regression (MLR) methods were performed for this spectral region. The results of optimized PLS and MLR methods showed that reproducibility increase with decreasing grain size and standard error of calibration (SEP) of less than 1% w/w of ascorbic acid and a correlation coefficient of 0.998 can be achieved. The PLS method showed better results than MLR. Seven overdose and underdose samples (prepared in the laboratory to match marketed products) were tested by proposed and iodometric standard methods. A correlation between NIRS predicted ascorbic acid values and iodomet.ic values was calculated ($R^2$=0.9950). Finally, the direct analysis of individual intact tablets in their unit-dose packages (Blistering in aluminum and PVC foils) obtained from market were also carried out and a correlation coefficient of 0.9989 and SEP of 0.931% w/w of ascorbic acid were achieved.

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농약에 대한 담수산 어류(잉어 : Cyprinus carpio, 송사리 : Oryzias latipes, 일본산 송사리 : Oryzias latipes)의 약제 감수성 비교 (Sensitivity of the three freshwater fish, Cyprinus carpio, Oryzias latipes (wildtype indigenous to Korea), and Oryzias latipes (Japanese killifish) to 30 pesticide formulations)

  • 이성규;신천철;노정구
    • 한국환경농학회지
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    • 제6권2호
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    • pp.66-72
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    • 1987
  • 잉어(C. carpio), 송사리(O. latipes), 일본산 송사리(O. latipes)등 3종의 담수산어 류에 대한 30개 농약의 급성독성$(48hr-LC_{50})$을 평가하여 각 어종간 농약에 대한 감수성의 상관관계를 비교하였다. 어종간 농약감수성의 상관관계는 잉어와 송사리는 r=0.80, 잉어와 일본산 송사리는 r=0.89로 비교적 높은 편이나, 송사리와 일본산 송사리의 상관관계는 r=0.93으로 매우 높았다. 따라서 일본산 송사리의 실험결과로 잉어 및 송사리의 농약 감수성을 예측할 수 있을 것으로 생각되었다. 그리고 우리나라의 잉어에 대한 어독성실험 지침은 실험수조내의 DO가 2mg/1 정도까지 떨어지므로 실험지침에 대한 검토가 있어야 할 것이다.

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유입식 변압기의 열화시간에 따른 절연 열화특성 및 선형회귀법을 이용한 상관관계 분석 (Analysis for Insulating Degradation Characteristics with Aging Time for Oil-filled Transformers and/or Correlation between using Linear Regression Method)

  • 이승민
    • 전기학회논문지
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    • 제59권4호
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    • pp.693-699
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    • 2010
  • General transformer's life is known as paper insulation' life. If a transformer is degraded by these aging factors, it is known that electrical, mechanical and chemical characteristics for transformer's oil-paper are changed. When the kraft paper is aged, the cellulose polymer chains break down into shorter lengths. It causes decrease in both tensile strength and degree of polymerization of paper insulation. The paper breakdown is accompanied by an increase in the content of furanic compounds within the dielectric liquid. In this paper it is aimed at analysis on correlation between aging characteristics for insulating diagnosis of thermally aged paper. For investigating the accelerated aging process of oil-paper samples accelerating aging cell was manufactured for estimating variation of paper insulation during 500 hours at $140^{\circ}C$ temperature. To derive the results, it was performed analysis such as tensile strength(TS), depolymerization(DP), dielectric strength(DS), relative permittivity, water content(WC) and furan compound(FC) for aged paper. Also for analyzing correlation between insulating degradation characteristics, we used linear regression method. As as results of linear regression analysis, there was a close correlation between TS and DP. WC, FC. But dielectric strength was a weak correlation with aging time.