• Title/Summary/Keyword: chemical balance study

검색결과 247건 처리시간 0.03초

폴리우레탄 콘크리트의 기초적 성상에 관한 연구 (A Fundamental Study on the Properties of Polyurethane Concrete)

  • 강재홍;조영국;소승영;소양섭
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1996년도 가을 학술발표회 논문집
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    • pp.253-259
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    • 1996
  • The purpose of this study is to investigate the fundamental properties of polyurethan concrete. Polyurethane must be expanded by means of a blowing agent during polymerization. Chemical blowing is caused by the reaction water with isocyanate. Binder system for polyurethane concrete is based on polyol and isocyanate with catalyst, surfactant, and methyl chloride. Polyurethane concretes are prepared with various grading of aggregate, and tested for compressive, flexural strengths, flow test, foaming multiple proportion, working life, condition of surface, distirbution of aggregate. From the test results, the foaming of polyurethane concretes are affceted by amount and grading of aggregate. Workability increases with raising amount of methy chloride and working life reduced according to amount of catalyst. The mix proportion of B with methyl chloride of 1% and catalyst of 0.1g for polyurethane concrete is recommended in consideration of strengths, condition of surface and balance between cost and performance.

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남해안 통영지역 가두리양식장 해수-퇴적물 경계면에서의 chemical fluxes (Chemical Fluxes at the Sediment-Water Interface Below Marine Fish Cages on the Coastal Waters off Tong-Young, South Coast of Korea)

  • 심정희;강영철;최진우
    • 한국해양학회지:바다
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    • 제2권2호
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    • pp.151-159
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    • 1997
  • 1995년 6월, 남해안 통영지역 가두리양식장 해수-퇴적물 경계면에서 입자상유기물의 수직유입량과 용존산소의 소모량, 영양염류의 용출량을 관측하였다. 입자상유기물의 수직유입량은 저층고정식 sediment trap을 이용하였으며, 용존산소의 소모량과 영양염류의 용출량은 benthic chamber method로 측정하였다. 가두리양식이 연안부영양화에 미치는 영향과 가두리에서 유출된 입자상유기물의 확산강도를 정량하기 위해, 가두리 아래(수심 약 18 m, Cage Site)와 가두리에서 수평으로 약 100 m 가량 떨어진 곳(수심 약 32 m, Control Site)의 해수-퇴적물 경계면에서, 암모니아와 인산염, 규산염의 용출량을 비교하고, 탄소와 질소와 인의 mass balances를 추정하였다. 관측결과, 가두리정점(Cage Site)으로는 6400 mg C $m^{-2}d^{-1}$의 입자상유기물이 유입되었고, 동시에 230 mmol $O_2\;m^{-2}d^{-1}$ 이상의 용존산소가 소모되었다. 따라서 탄소의 경우, 가두리 아래 해저면으로 공급되는 유기 입자의 약 40%에 달하는 양이 해수-퇴적물 경계면에서 분해되며 (ca. 2400 mg C $m^{-2}d^{-1}$), 나머지 약 60%는 퇴적되어 매몰되는 것으로 보인다. (ca. 4000 mg C $m^{-2}d^{-1}$) 그러나 대비정점(Control Site)에서는 가두리정점에 비해 상대적으로 적은 양의 유기물유입과(ca. 4000 mg C $m^{-2}d^{-1}$), 낮은 용존산소소모율이 관측되었다(75 mmol $O_2\;m^{-2}d^{-1}$). 관측결과는 가두리에서 투기되는 대부분의 입자상유기물이 가두리 아래 해저면에 집중적으로 퇴적되고 있음을 보여주며, 가두리 부근 해저면으로 확산되는 입자상유기물의 양은 가두리에서 멀어질수록 급속히 감소함을 시사한다.

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다수 캐비티 사출금형에서의 균형 충전을 위한 러너 시스템 연구 (A study on the runner system for filling balance in multi-cavity injection molds)

  • 전강일;노승규;김동학
    • 한국산학기술학회논문지
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    • 제12권4호
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    • pp.1581-1588
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    • 2011
  • 사출성형은 열가소성 수지의 가공법으로 정밀도나 고품질의 제품을 효과적으로 생산하는데 널리 이용되는 기술이다. 다수 캐비티 사출성형에서 캐비티 충전 불균형이 발생하는데 이러한 현상은 사출성형품의 치수 및 중량의 편차 뿐 아니라 물리적 특성에 영향을 미치고 있다. 충전 불균형은 충전 단계에서 러너 내에서 발생되는 불균일한 전단분포에 기인하여 발생되므로 점도 변화에 영향을 주는 수지의 물성, 사출조건 등 성형공정 조건 요인에 의해 충전 불균형의 양상이 다르게 된다. 본 논문에서는 점도 및 물성이 다른 PC, PP 수지에 대하여 성형조건에 따른 충전 현상을 관찰하고 원인을 분석하였고 사출속도에 따른 충전 불균형 현상의 원인을 고찰하기 위해 사출성형실험과 CAE 해석을 수행하였다. CAE 해석을 수행하여 각 수지마다 사출속도에 따른 충전 패턴 경향과 온도분포를 예측하고 캐비티 간 충전 균형을 위해 새로운 볼륨 러너 시스템을 제시하였고 캐비티 간 충전 균형을 확인 할 수 있었다.

Effects of Reaction pH and Hardener Type on Reactivity, Properties, and Performance of Urea-Formaldehyde (UF) Resin

  • Park, Byung-Dae;Kim, Yoon Soo;So, Won Tek;Lim, Kie Pyo
    • Journal of the Korean Wood Science and Technology
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    • 제30권3호
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    • pp.1-11
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    • 2002
  • This study was conducted to investigate the effects of reaction pH conditions and hardener types on the reactivity, chemical structure and adhesion performance of UF resins. Three different reaction pH conditions, such as traditional alkaline-acid (7.5 → 4.5), weak acid (4.5), and strong acid (1.0), were used to synthesize UF resins which were cured by adding three different hardeners (ammonium chloride, ammonium citrate, and zinc nitrate) to measure adhesion strength. Fourier transform infrared (FT-IR) and carbon-13 nuclear magnetic resonance (13C-NMR) spectroscopies were employed to study chemical structure of the resin prepared under three different reaction pH conditions. Adhesion strength of the resins cured with three different hardeners was determined with lap shear specimens in tension. The gel time of UF resins decreased with an increasing in the amount of both ammonium chloride and ammonium citrate added in the resins. However, the gel time increased for zinc nitrate. Both FT-IR and 13C-NMR spectroscopies showed that the strong reaction pH condition produce uronic structures in UF resin, while both alkaline-acid and weak acid conditions produce quite similar chemical species in the resins. The maximum adhesion strength was occurred with the resin prepared under strong acid pH condition. However, this study indicated that the weak acid reaction condition provide a balance between increasing resin reactivity and improving adhesion strength of UF resin. The measurement of formaldehyde emission from the panels bonded with the UF resins prepared is planned for future work.

로지스틱 회귀분석을 이용한 조직 근로환경에서의 심리사회적 위험관리 방안의 효과 검증 (The Effectiveness Validation of Psychosocial Risk Management Plans in an Organizational Working Environment Using Logistic Regression Analysis)

  • 김수연;한승조;이동형
    • 산업경영시스템학회지
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    • 제44권2호
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    • pp.78-84
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    • 2021
  • In addition to physical risks such as electrical, chemical, and mechanic ones in the workplace, psychosocial risks are also raising as an important issue in recent years in connection with human rights and work-life balance policies. The purpose of this study is to confirm the degree of effect of the psychosocial risk management plan at the workplace on workers through logistic regression analysis. Input data for logistic regression analysis is the results of a survey of 4,558 people conducted by the Institute for Occupational Safety and Health were used. There are 9 independent variables, including the change a workplace and confidential counseling, and the dependent variable is whether the worker feels the effect on the psychosocial risk management plan. As a result of this study, changes in work organization, dispute resolution procedures, provision of education program, notification of the impact of psychosocial risks on safety and health, and the persons in charge of solving psychosocial problems are shown effective in reducing worker's psychosocial risks. This study drives which of the management plans implemented to reduce the psychosocial risk of workers in the workplace are effective, so it can contribute to the development of psychosocial risk management plans in the future.

O/W 나노에멀젼 분산안정성에 미치는 보관온도의 영향 (Effect of Storage Temperature on the Dispersion Stability of O/W Nano-emulsions)

  • 이예은;유인상
    • KSBB Journal
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    • 제29권5호
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    • pp.385-391
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    • 2014
  • In this study, the emulsion dispersion stability of optimizing storage temperature was investigated. The system was based on oil/water (O/W) emulsions. In order to evaluate the stability, mean diameter of droplet was measured as a function of temperature with various mixed hydrophilic lipophilic balance (HLB). In addition, the correlations between phase inversion temperature (PIT) and the optimum storage temperature were probed. In this system, majority of the smallest droplet was shown at temperature of $20^{\circ}C$ below PIT. Whether the temperature was increased or decreased from the optimum, size of the droplet increased. According to the mixed HLB, the particle size and optimum storage temperature were also affected. As the concentrations of surfactant were increased, the size of particle decreased with lower optimum temperature for storage. If the surfactant (4 wt%) were mixed with HLB, the optimum storage temperature was $21^{\circ}C$ for maintaining the size of smallest droplet at 108.3 nm in diameter. At above optimum condition, increased size of particle was observed approximately 4 % increases from 108.2 nm to 112.3 nm after 600 hours. The size of particle in emulsion was maintained stably without any considerable effect of Ostwald ripening phenomena at the optimum storage temperature with low polydispersity index.

증착공정에서의 회전원판 정체점유동에 대한 상사해석 (Similarity analysis of a forced uniform flow impinging on a rotating disk in a vapor deposition process)

  • 송창걸;황정호
    • 대한기계학회논문집B
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    • 제21권3호
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    • pp.371-379
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    • 1997
  • A theoretical study for a forced uniform flow impinging on a rotating disk, typically involved in Chemical Vapor Deposition(CVD) and Vapor-phase Axial Deposition(VAD) processes, has been carried out. A set of exact solutions for flow and temperature fields are developed by employing a similarity variable obtained from force balance on a control volume near the disk. The solutions depend on the rotating speed of the disk, .omega., and the forced flow speed toward the disk, a. For constant forced flow speed, the overall boundary layer thickness decreases when the rotating speed increases. Approximately 5%, 15%, and 30% decreases of the thickness are obtained for .omega./a = 2, 5, and 10, respectively, compared to the case of .omega./a = 0 (axisymmetric stagnation point flow). For constant rotating disk speed the boundary layer thickness immediately decreases as the forced flow speed increases, compared to the case of .omega./a .rarw. .inf. (induced flow near a rotating disk). Effects of .omega. and a on heat transfer coefficient are studied and explained with the boundary layer characteristics.

Analysis of the Wet-end Dynamics in Paper Mills

  • 류재용;여영구;서동준;강홍
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2003년도 추계학술발표논문집
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    • pp.306-330
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    • 2003
  • The wet-end dynamics of a paper mill was analyzed to characterize its dynamic behavior during the grade change. The model representing the wet-end section is developed based on the mass balance relationships written for the simplified wet-end white water network. From the linearization of the dynamic model, higher-order Laplace transfer functions were obtained followed by the reduction procedure to give simple lower-order models in the form of $1^{st}$-order or $2^{nd}$-order plus dead times. The dynamic response of the wet-end is influenced both by the white water volume and by the level of wire retention. Effects of key manipulated variables such as the thick stock flow rate, the ash flow rate and the retention aid flow rate on the major controlled variables were analyzed by numerical simulations. The simple dynamic model developed in the present study can be effectively used in the operation and control.

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추적자를 이용한 유량 측정 (Measurement of Water Flow in Closed Conduits by Chemical Tracer Method)

  • 이선기;정백순;김창호
    • 한국유체기계학회 논문집
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    • 제2권2호
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    • pp.19-26
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    • 1999
  • Thermal output in a nuclear power plant is verified with calorimetric heat balance on the secondary plant. The calorimetry involves the precise measurement of the feedwater flow rate. However, the correct indication of feedwater flow rate obtained by a pressure-difference measurement across a venturi can be affected by instrument errors, fouling or a poorly developed velocity profile. This can result in an inaccurate mass flow rate and consequently an inaccurate estimate of power. The purpose of this study is to develop verification methods with accuracy better than $0.5\%$ for high precision flow measurement to be used for measuring feedwater flow rate. This chemical tracer method is a testing process that uses tracers which can be applied to quantify losses in electrical output due to the incorrect measurements of feedwater flow rate. And this system has good response to the variation of the flow rate. Accuracy of better than 0.5 percent can be expected for feedwater flow measurement, providing that the system can be stabilized during the test. This methodology is applicable to other flow systems well.

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하계 소백산 안개의 화학적 특성에 관한 연구 (A Study on Chemical Features of Fog Sample in Summer at Mt. Sobaek)

  • 최재천;이민영;이선기;남재철
    • 한국대기환경학회지
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    • 제12권4호
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    • pp.399-406
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    • 1996
  • Acidic fog is catastrophic to aviation and potentially affect materials, vegetation, crops and public health. This paper was carried out to investigate the chemical features of fog sample at Mt. Sobaek (mean sea level : 1, 340m) from June to August 1995. Each sample was analyzed for pH, electrical conductivity and major ions (anion : $Cl^N)_3^-, SO_4^{2-}, cation : Na^+, NH_4^+, K^+, Mg^{2+}, Ca^{2+}$) by ion chromatography. The quality analysis of fog sample data was performed based on ion balance and electrical conductivity method. The wind directions are subdivided into the northerly and southerly wind according to the wind direction data at the Sobaek-san meteorological observation station. Statistical analyses were performed on the complete set of results in order to obtain a description of fog sample. All the statistical treatment was carried out using the SPSS/PC + software package. The major ion concentration of fog samples was higher for the northwesterly wind cases than sourtheasterly wind cases. The pH of fog sample varied between 2.95 and 6.08. The average pH and electrical conductivity of total sample (n=210) were 4.39 and 113.0 $\mu$S/cm, respectively. It may be noted that in nearly all the cases, the dominant major ions in the fog sample at Mt. Sobaek were $SO_4^{2-}, NO_3^-, H^+ and NH_4^+$.

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