• 제목/요약/키워드: chemical analysis

검색결과 12,608건 처리시간 0.044초

PREPARATION OF POLYSTYRENE BEADS CONTAINING SULFONAMIDE GROUPS AND THEIR APPLICATION TO POLYMERIC BIOCIDES

  • Kim, Cheol-Jin;Kim, Jee-Yeon;Byun, Jang-Woong;Kim, Jae-Eun;Lee, Yoon-Sik;Yoon, Je-Yong
    • Environmental Engineering Research
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    • 제11권6호
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    • pp.325-332
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    • 2006
  • A novel series of polystyrene (PS) beads containing various sulfonamide groups was prepared, and their chemical stabilities in an aqueous solution were tested in order to determine their ability to inactivate microbes. By reacting aminomethyl polystyrene (AM PS) beads or carboxy polystyrene beads with various benzenesulfonic acid derivatives, the sulfonamide groups were introduced on the PS beads. The characteristics of the product beads were analyzed by elementary analysis after the substitution of various sulfonamide groups. Energy Dispersive Spectroscopy (EDS), and FT-IR analysis were used to analyze the elemental functional group composition, respectively. The hydrolytic stabilities of the PS beads containing various sulfonamide groups along with the relationship between the swelling ratio and their hydrophilicity were investigated. The antibacterial activity of the beads was determined by their ability to inactivate E. coli. This study reports that PS beads containing sulfonamide groups had lasting antibacterial efficacy over a satisfactory period, whilst maintaining their chemical stabilities against hydrolysis. The 8 synthesized polymer beads exhibited antibacterial ability.

휴대용 및 Bench-Top X-선 형광 분석기를 이용한 오일 시료 중 마찰 금속의 비교 분석 (Comparison study of the wear metal analysis in oil sample by portable and bench-top XRF)

  • 최수정;김종혁;이석근;김동표
    • 분석과학
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    • 제22권5호
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    • pp.422-431
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    • 2009
  • 휴대용 X-선 형광 분석기의 개발을 위한 기초연구로서 휴대용 및 bench-top X-선 형광 분석기를 이용하여 오일 시료 중의 Na, Mg, Al, Si, P, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Mo, Ag, Cd, Sn, Ba, Pb 등 20종의 마찰 금속 원소들을 비교 분석하였다. 마찰 금속 원소의 농도가 10~900 mg/kg으로 함유된 오일 인증표준물질을 구입하여 측정 시간 등에 따른 최적 분석조건을 확립하고, 각 마찰 금속 원소에 대한 검량곡선을 작성하였다. 마찰 금속 원소가 함유된 오일 인증표준물질 및 시판 중인 엔진오일 시료의 주행 전 후의 금속 원소 농도를 empirical 법 및 fundamental parameter 법으로 정량분석하고 그 결과를 비교하였다.

황색종 잎담배의 숙도에 따른 화학성분의 변화연구 (Studies on the Change of Chemical Components of Flue-cured Tobacco with Maturity)

  • 황건중;김정환;김찬호
    • 한국연초학회지
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    • 제3권1호
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    • pp.20-24
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    • 1981
  • This experiment was carried out to determine the relationships between maturity and content of the chemical components in flue-cured tobacco. The results were as follows : 1) Among the chemical components, the contents of total nitrogen, ammonia nitrogen, total alkaloids, nicotine, total volatile base, petroleum-ether extract, crude fiber, crude ash, water soluble ash, and chlorine decreased significantly, and those of total sugar, reducing sugar, and starch increased as leaf maturity progressed until the stage of ripeness, but, afterwards, a reverse tendency appeared. 2) There was a significant relationship between maturity and the contents of chemical components, such as total nitrogen, protein nitrogen, ammonia nitrogen, total volatile base, and the correlation coefficients of them were -0.743, -0.789, -0.797, and -0.642, respectively.

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질량분석기에서 Pesticide Priority Pollutants의 동시분석의 동적 범위 (Dynamic Range in the Simultaneous Analysis of Pesticide Priority Pollutants on Mass Spectrometer)

  • 이승석;이석근
    • 분석과학
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    • 제9권3호
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    • pp.320-324
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    • 1996
  • The dynamic range of mass selected detector, which is very popular recently because of the simplicity and cheap price, was determined by using priority pollutants. The applied priority pollutants were four pesticides, 4,4'-DDE and 4,4'-DDD, which show the sharp peaks, and ${\alpha}$-endosulfan and ${\beta}$-endosulfan, which show the broad peaks in SIM Chromatogram. The dynamic range of the 4,4'-DDE and the 4,4'-DDD was $0.1{\sim}3000{\mu}g/ml$. The broad peaks of the ${\alpha}$-endosulfan and ${\beta}$-endosulfan resulted in $0.25{\sim}3000{\mu}g/ml$ of dynamic range.

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혼합 액체 연료의 화학반응 인자 계측에 관한 실험적 연구 (An Experimental Study on Measurement of Chemical Kinetic Parameters of a Liquid Fuel with Various Components)

  • 최효현;임준석;김철진;손채훈
    • 한국연소학회지
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    • 제16권3호
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    • pp.21-26
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    • 2011
  • Thermal analyses are conducted to measure chemical kinetic parameters of an unknown liquid fuel with various components. Thermal Analyses are divided into two different methods such as TGA(Thermo-Gravimetric Analysis) and DSC(Differential Scanning Calorimety). Non-isothermal experimental results are analyzed by adopting TGA and they are filtered by Freeman-Carroll method. As a results of the analysis, chemical parameters of the activation temperature and the reaction order are measured to be 6128.2 K and 1.4, respectively. Furthermore, the chemical kinetic parameters are obtained by a variety of mathematical processing methods. It has been found that they show a little difference depending on the processing method.

ETC 효과를 고려한 강내탄도의 성능해석 연구 (Study on Performance Analysis of Interior Ballistics According to ETC(Electrothermal chemical) Effect)

  • 성형건;장진성;이상복;노태성;최동환
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2009년도 제33회 추계학술대회논문집
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    • pp.145-148
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    • 2009
  • ETC(Electrothermal chemical) Gun에 대한 연구를 수행하였다. 기존의 강내탄도 전산해석 코드를 ETC 화포에 적용하도록 확장시켰다. 이를 통해 플라즈마 에너지 주입 패턴에 따른 강내탄도 성능해석 연구를 수행하였다.

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