• Title/Summary/Keyword: chemical additive

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Synthesis and Electrochemical Characteristics of Silicon/Carbon Anode Composite with Binders and Additives (Silicon/Carbon 음극소재 제조 및 바인더와 첨가제에 따른 전기화학적 특성)

  • Park, Ji Yong;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.303-308
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    • 2018
  • Silicon/Carbon (Si/C) composite as anode materials for lithium-ion batteries was synthesized to find the effect of binders and an electrolyte additive. Si/C composites were prepared by two step method, including magnesiothermic reduction of SBA-15 (Santa Barbara Amorphous material No. 15) and carbonization of phenol resin. The electrochemical performances of Si/C composites were investigated by charge/discharge, cyclic voltammetry and impedance tests. The anode electrode of Si/C composite with PAA binder appeared better capacity (1,899 mAh/g) and the capacity retention ratio (92%) than that of other composition coin cells during 40 cycles. Then, Vinylene carbonate (VC) was tested as an electrolyte additive. The influence of this additive on the behavior of Si/C anodes was very positive (3,049 mAh/g), since the VC additive is formed passivation films on Si/C surfaces and suppresses irreversible changes.

Development of Pulping Methods of Rice-straw Chemical Pulp with Higher Yield and Lower Kappa Number (고수율 및 저카파가의 볏짚화학펄프 제조방법 개발)

  • 강진하;박성종
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.2
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    • pp.58-67
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    • 2000
  • This study was carried out to acquire basic data necessary for the use of non-wood pulp. Various chemical pulping methods for rice straw to achieve higher yield, lower Kappa No. were investigated and then the physical properties of various pulps were tested. The results of this study were as follows: When various chemical pulps (Soda, Soda-AQ, Soda-$H_2O_2$, Soda-$Na_2S_2$, AS, AS-AQ, AS-$Na_2S_2O_3$, AS-$Na_2S_2O_4$, Kraft) were produced with rice-straw, the pulps with the highest yield and lowest Kappa No. were obtained with Soda-$Na_2S_2$and AS-$Na_2S_2O_4$pulps. For the breaking length, Soda and Soda-additive pulps(7.5~9.2km) were better than AS and AS-additive pulps(6.2~8.1km). Similarly, for the burst index, Soda and Soda-additive pulps(6.0~7.0 kPa.$m^2$/g) were better than AS and AS-additive pulps(4.5~6.3 kPa.m$^2$/g). But the tear index was showed 21.8-30.9 mN.$m^2$/g with a little different between pulping methods.

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Synthesis and Lubricant Additive Properties of Succinimidyl-type Compounds (숙신이미드계 화합물의 합성 및 그의 윤활특성)

  • Park, Chan-gu;Kang, Hocheol;Park, Jong-mok;Lee, Byung Min;Kim, Dong-Pyo
    • Applied Chemistry for Engineering
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    • v.17 no.5
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    • pp.498-503
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    • 2006
  • i-(2',5'-Diketotetrahydrofuranyl)octadecenyl acid (OSA), an intermediate for the lubricating oil additive, was prepared by the ene-reaction of oleic acid with maleic anhydride. The reaction progress was monitored by gas chromatography by analyzing the amount of OSA. The series of succinimidyl compounds were synthesized by the reaction of alkyl amines and OSA. As a kind of lubricant additives, demulsibility, anti-wear, and anti-corrosion properties of these succinimidyl compounds were measured. The derivative of octadecylamine which has relatively long-chained alkyl group has showed good properties.

Controlling the pore size of macroporous membranes by adding non-solvent

  • Shin, Se-Jong;Im, Se-Jun;Park, Seung-Ryul;Lee, Seung-Yun;Min, Byoung-Ryul
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.107-114
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    • 2003
  • This study investigated the effect of 2-methoxy ethanol (2-Me) non-solvent as additive included in casting solution. Macroporous polymer membranes were prepared by using polyethersufone (PES)/N-methyl-2-pyrrolidone (NMP)/2-Me casting solution and water coagulant. The phase separation co-process of the vapor-induced phase separation (VIPS) and liquid-induced phase separation (LIPS) were used by means of membrane preparation method. The pore size and pore size distribution were controlled with additive (non-solvent), and measured with Automated Perm Porometer. By increasing additive (non-solvent) in the casting solution, the membranes produced changed from finger structure to sponge structure. That is due to the different diffusion rates. At slow diffusion process, sponge-like structure was formed and at fast diffusion process, finger-like structure was formed. Also relative humidity, evaporation time, temperature of casting solution and coagulation bath etc. had effects on the pore size distribution and the porosity of the membrane.

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The Micro Coil Production through Research on the Additive Conditions of Electrochemical Metal 3D Printer (전기화학적 금속 3D 프린터의 적층 조건 연구를 통한 마이크로 코일 제작)

  • Kim, Young-Kuk;Kang, Donghwa;Kim, Sung-Bin;Yoo, Bongyoung
    • Journal of the Korean institute of surface engineering
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    • v.53 no.4
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    • pp.138-143
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    • 2020
  • In this study, we produced a coil of micro-pattern that can be used for electromagnetic wave absorber, heating material, wireless charging, sensor, antenna, etc. by using electrochemical additive manufacturing method. Currently, it contains research contents for manufacturing a micro pattern coil having practicality through control of process control variables such as applied voltage, distance between electrode, and nozzle injection. Circulation of the electrolyte through the nozzle injection control can significantly contribute to improving the surface characteristics of the coil because of minimizing voltage fluctuations that may occur during the additive manufacturing process. In addition, by applying the pulse method in the application of voltage, the lamination characteristics of the plated body were improved, which showed that the formation of a fine line width plays an important role in the production of a micro pattern coil. By applying the pulse signal to the voltage application, the additive manufacturing characteristics of the produced product were improved, and it was shown that the formation of a fine line width plays an important role in the production of a micro pattern coil.

Effect of Process Parameters and Kraft Lignin Additive on The Mechanical Properties of Miscanthus Pellets

  • Min, Chang Ha;Um, Byung Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.6
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    • pp.703-719
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    • 2017
  • Miscanthus had a higher lignin content (19.5 wt%) and carbohydrate (67.6 wt%) than other herbaceous crops, resulting in higher pellet strength and positive effect on combustion. However, miscanthus also contains a high amount of hydrophobic waxes on its outer surface, cuticula, which limits the pellet quality. The glass transition of lignin and cuticula were related to forming inter-particle bonding, which determined mechanical properties of pellet. To determine the effects of surface waxes, both on the pelletizing process and the pellet strength were compared with raw and extracted samples through solvent extraction. In addition, to clarify the relationship between pellet process parameters and bonding mechanisms, the particle size and temperature are varied while maintaining the moisture content of the materials and the die pressure at constant values. Furthermore, kraft lignin was employed to determine the effect of kraft lignin as an additive in the pellets. As results, the removal of cuticula through ethanol extractions improved the mechanical properties of the pellet by the formation of strong inter-particle interactions. Interestingly, the presence of lignin in miscanthus improves its mechanical properties and decreases friction against the inner die at temperatures above the glass transition temperature ($T_g$) of lignin. Consequently, it could found that the use of kraft lignin as an additive in pellet reduced friction in the inner die upon reaching its glass transition temperature.

RUNNING-IN OF DLC COATED STEEL IN BOUNDARY LUBRICATION

  • Stavlid, N.;Wiklund, U.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.137-138
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    • 2002
  • The benefits of using DLC coatings on steel in dry sliding are well known. The present study has investigated the effects of using the same materials but in a boundary lubricated environment. Tribological tests were performed using a load-scanning device and a lubricant with an extreme-pressure (EP) additive. XPS and grazing incidence XRD are used for chemical analysis. The chemical composition of the resulting tribofilm is correlated to different friction behaviors and contact loads, and indicates that high loads are beneficial for formation of low friction tribofilm.

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Electrodeposition of Cobalt Nanowires

  • Ahn, Sungbok;Hong, Kimin
    • Bulletin of the Korean Chemical Society
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    • v.34 no.3
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    • pp.927-930
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    • 2013
  • We developed an electroplating process of cobalt nanowires of which line-widths were between 70 and 200 nm. The plating electrolyte was made of $CoSO_4$ and an organic additive, dimethyldithiocarbamic acid ester sodium salt (DAESA). DAESA in plating electrolytes had an accelerating effect and reduced the surface roughness of plated cobalt thin films. We obtained void-free cobalt nanowires when the plating current density was 6.25 mA/$cm^2$ and DAESA concentration was 1 mL/L.

Synthesis and Luminescence Enhancement of Strontium Aluminate Green Phosphor via Spray Pyrolysis (분무열분해 공정을 이용하여 스트론튬 알루미네이트 녹색 형광체의 합성 및 발광 특성 개선)

  • Kim, Mi Na;Jung, Kyeong Youl
    • Korean Chemical Engineering Research
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    • v.49 no.5
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    • pp.594-599
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    • 2011
  • $SrAl_2O_4:Eu$ green phosphor was prepared by spray pyrolysis and its luminescence properties were controlled by replacing the Al sites with boron and using organic modifier or drying control chemical additive. It was clear that the substitution of B into the Al sites was helpful to obtain pure monoclinic $SrAl_2O_4$ phase and greatly enhance the emission intensity. In terms of the emission intensity, the optimal content of boron was about 1 at% with respect to the aluminum element. The luminescence intensity of $Sr_{0.9}Al_{1.98}B_{0.02}O_4:Eu_{0.1}$ phosphor could be improved by the use of 0.2 M organic additives in the spray solution. Futhermore, using 0.5 M dimethylformamide(DMF) as a drying control chemical with organic additives made it possible to improve about 172% the emission intensity of $Sr_{0.9}Al_{1.98}B_{0.02}O_4:Eu_{0.1}$ phosphor. According to XRD analysis, the organic additive and DMF used enhanced the crystallinity without any change in the crystal phase. When used only the organic additive without DMF, the surface area of the prepared $Sr_{0.9}Al_{1.98}B_{0.02}O_4:Eu_{0.1}$ phosphor became enlarged. The use of DMF with the organic additive resulted in significant reduction in the surface area. It was concluded that the increase of the crystallinity as well as the reduction of surface area mainly contribute to the improvement in the luminescence intensity of $Sr_{0.9}Al_{1.98}B_{0.02}O_4:Eu_{0.1}$ phosphor prepared using DMF and organic additives.

Comparison of Removal Capabilities among Several Aqueous Amine Absorbents for Sweeting Acid Gases Contained in Natural Gas (다양한 아민 흡수제를 이용한 천연가스 중에 포함되어 있는 산성가스 제거 성능 비교)

  • Cho, Du-hee;Kim, Dong-sun;Cho, Jung-ho
    • Plant Journal
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    • v.10 no.1
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    • pp.34-39
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    • 2014
  • Simulation works for comparing removal capabilities of acid gases contained in natural gas among several aqueous amine absorbents using commercial process simulator PROMAX(BR&E Co.) were carried out. Amine aqueous solution used in this study were 30 wt% MEA, 30 wt% DEA, 50 wt% MDEA, and 50 wt% MDEA with 3 wt% piperazine as additive. We obtained the simulated results that while MEA aqueous solution is relatively capable of more $CO_2$ gas, but DEA, MDEA, MDEA aqueous solutions with piperazine as additive are capable of more $H_2S$ gas. Also, we found that 30 wt% MDA aqueous solution is the smallest circulate rate of lean amine solution, and 50 wt% MDEA aqueous solution with 3 wt% piperazine as additive is the smallest heat duty in stripping unit. 50 wt% MDEA aqueous solution with 3 wt% piperazine as additive is found less amine circulation rate than 50 wt% MDEA due to the introduction of additive.

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