• Title/Summary/Keyword: chemical acidification

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Biological Hydrogen Production from Mixed Waste of Food and Activated Sludge (음식물쓰레기와 폐활성슬러지의 혼합물로부터 혐기성 바이오 수소 생산)

  • Chung, Chong Min;Hong, Seok Won;Park, Chul Hee;Kim, Young O;Lee, Sang Hyup
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.5
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    • pp.571-580
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    • 2008
  • The influence of bacterial stress on anaerobic hydrogen-producing microorganisms was investigated in batch tests using serum bottles. Several physical and chemical stresses (i.e., heating, adding methane producing inhibitor and chemical acidification) were adapted as a pretreament of the seed sludge. In this experiment, the cultivation temperature were set at mesophilic ($35^{\circ}C$) and thermophilic conditions ($55^{\circ}C$) with adjusting pH at 5, 6, and 7 when using the mixture of food waste and activated sludge as a substrate. In conjunction with the pretreatment, hydrogen production was significantly enhanced as compared with that from untreated sludge. However, less biogas (hydrogen and methane) was produced without the pH control, resulted from the decrease of pH to below 4, mainly due to the formation of VFAs. Hydrogen and carbon dioxide gas were analyzed as main components of the biogas while methane not detected. With an application of chemical acidification, the highest hydrogen production value of 248 ml/l/day achieved at pH 7 and $35^{\circ}C$. In addition, more hydrogen gas produced when the ratio of butyric/acetic acid ratio increased. The optimum pH and temperature for hydrogen production were found to be 7 and $35^{\circ}C$, respectively.

The Effects of Reactive Nitrogen (Nr) Compounds on the Acidification in Soil and Water Environment Ecosystems and the Mitigation Strategy (반응성 질소화합물로 인한 토양 및 물 환경 생태계의 산성화 영향 및 대응방안)

  • Cho, Youngil;Kang, Hyesoon;Jeon, Eui-Chan
    • Korean Journal of Ecology and Environment
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    • v.49 no.1
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    • pp.1-10
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    • 2016
  • The increases of industrial and technological development and human activities have disturbed the balance of natural nitrogen (N) circulation. These phenomena have induced that large amounts of N are to be present in excess in air, soil and water environment. We investigated the effects of excess of reactive nitrogen ($N_r$) compounds on soil and water environment ecosystems through literature and case studies, and suggested the strategy of mitigating the acidification in soil and water ecosystems. $N_r$ moves to air, soil and water media, can be converted to different types, and interacts with other chemical compounds. As an efficient N management plan, the evaluation (application of monitoring and safety index) and the chemical restoration (research and development) of the acidification in soil and water environment ecosystems are required to minimize the effects of $N_r$ as well as policies to regulate the various emission sources and amounts of $N_r$.

Effect of Washing Treatment of Aged Paper Materials for Better Conservation (열화된 종이자료의 보존성 개선을 위한 세척처리 특성)

  • Lee, Kwi-Bok;Seo, Yung-Bum;Park, So-Yeon;Jeon, Yang;Shin, Jong-Soon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.4 s.117
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    • pp.53-60
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    • 2006
  • Paper materials for long term conservation suffer slowly mechanical and chemical deterioration, the extent of which may depend upon their conservation environment. Those deterioration includes discoloring, low moisture content, acidification, and brittleness. To slow deterioration, washing treatment, deacidification, and polymer reinforcement on paper materials are usually used. One easy and simple method of fixing low moisture content and acidification was an washing method, and we used both distilled and alkali water in washing method in this study. Alkali water is electrolyzed cathode water of high pH, and has no alkali metal ions in it. Experiment showed that washing treatment with both distilled and alkali water gave improvement in raising moisture content, pH, and mechanical strength of paper materials even after severe accelerated aging test. Advantageous effect of alkali water over distilled water on preventing deterioation was also shown clearly.

Perspectives of Utilization and Function of Antioxidants in Sesame (참깨 항산화물질의 기능과 함량 및 이용 전망)

  • Ryu Su Noh;Kang Chul Whan;Lee Jung Il;Lee Seung Tack;Kim Kwan Su;Ahn Byung Og
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.spc1
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    • pp.94-109
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    • 1996
  • Antioxidants of sesame have been reported to cure and prevent various diseases by means of diverse physiological activities, prevention of acidification in organisms, prevention of acidification and decay of lipids, cholesterol depression, preventive effects on chemical breast cancer, skin beauty and senescence inhibition, and so on. Recognizing their significance to health and disease prevention, researchers in Japan and America have given so much importance to study antioxidants in the last decade. In addition, they are actively pursuing studies on production, processing for food use and development of new varieties that have high antioxidant content. Recently, researchers in Korea have shown the same interest and have conducted similar studies, however, the importance of the following basic issues must be recognized to guide in future activites : First, improvement of sesame quality must be done to raise the contents of not only the fat and fatty acid but also sesamin, sesamolin and sesaminol glucoside. For the use of these components it is necessary to study the gentic pattern and individual selections developed from minimum sample size and fast lipid analysis techniques. Second, sesaminol of sesame has a remarkable function in preventing acidification and so sesame can be utilized as a food that prevents or delays aging caused by automatic acidification of fat. Therefore, for maximum medicinal benefit from sesame oil there is a need to develop food materials having new medicinal functions. Third, the sesamin and sesamolin content of sesame germplasms collected in Korea showed lower ranges of $0.04\~0.68$ percent and $0.08\~0.68$ percent respectively, while Japanese germ-plasm showed 1.9 percent maximum content of seasmin. Thus, germplasm collection and analysis of worldwide genetic resources are urgently needed.

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Short-term Effect of Phosphogypsum on Soil Chemical Properties

  • Chung, Jong-Bae;Kang, Sun-Chul;Park, Shin
    • Korean Journal of Environmental Agriculture
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    • v.20 no.5
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    • pp.317-324
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    • 2001
  • Short-term effect of phosphogypsum on soil properties including acidification, salinity and metal availability were investigated under laboratory and field conditions. Phosphogypsum and mixtures of phosphogypsum and compost were added to soil and incubated in a laboratory condition with 15% moisture content. Phosphogypsum treatments were 2.5 and 5.0 g/kg soil and in the treatments of phosphogypsum and compost mixture 10 g of compost was added additionally. After the 30 days of incubation, an additional phosphogypsum and/or compost were added to the remaining soils at the same rates of the first treatments. pH, electrical conductivity, and available hazardous elements were measured periodically during the incubation. Field experiment was conducted in a plastic film house of mellon with four treatments of phosphogypsum and compost mixtures - 25+125, 50+125, 50+250 and 100+250 kg/165 $m^2$. pH, electrical conductivity, and hazardous elements in soil and total hazardous elements in leaf were measured. In the laboratory experiment, after 30 days of the first phosphogypsum application, soil pHs were lowered by 0.7-0.8 units. After the second treatment of phosphogypsum 0.2 units of additional acidification occurred. However, acidification was not observed in the soils treated with mixtures of phosphogypsum and compost. In the laboratory experiment, phosphogypsum treatments increased electrical conductivity very significantly. In field experiment, pH and electrical conductivity of soils treated with phosphogypsum were nearly the same as those of soil not treated with phosphogypsum. Since soil condition in the field study was an open system, the free acids and salts derived from phosphogypsum could be diffused down with water leaching through the soil profile and then any significant acidification or salt accumulation in the topsoil could not be observed. In both laboratory and field experiments, levels of available hazardous elements in soils treated with phosphogypsum were quite low and not different from the levels found in the control soil. Results obtained from this study suggest that application of phosphogypsum at appropriate rates on agricultural land appears of no concern in terms of acidity, salinity and hazardous element content of soil.

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Investigating production parameters and impacts of potential emissions from soybean biodiesel stored under different conditions

  • Ayoola, Ayodeji Ayodele;Adeniyi, David Olalekan;Sanni, Samuel Eshorame;Osakwe, Kamsiyonna Ikenna;Jato, Jennifer Doom
    • Environmental Engineering Research
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    • v.23 no.1
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    • pp.54-61
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    • 2018
  • Biodiesel production parameters and the impact analysis of the potential emissions from both soybean biodiesel and washing water stored in three different environmental conditions were investigated. The effects of the reaction temperature, methanol/oil mole ratio and catalyst concentration on biodiesel yield were considered. And the results showed optimum biodiesel yield of 99% obtained at $54^{\circ}C$, 7 methanol/oil mole ratio and 0.4 wt/wt % catalyst concentration. The potential emissions from both the biodiesel produced and washing water stored (for six weeks) in refrigerator (${\leq}10^{\circ}C$), vacuum (50 kPa) and direct exposure to atmosphere were identified and quantified. Impact analysis of the emissions involved their categorization into: terrestrial acidification, freshwater eutrophication, human toxicity, terrestrial ecotoxicity, climate change and freshwater ecotoxicity. Freshwater ecotoxicity category had the most pronounced negative impact of the potential emissions with $5.237710^{-2}kg\;1,4-DB\;eq$. emissions in Atmosphere, $4.702610^{-2}kg\;1,4-DB\;eq$. emissions in Refrigerator and $3.966110^{-2}kg\;1,4-DB\;eq$. emissions in Vacuum. Climate change had the least effect of the emissions with $6.214106^{-6}kg\;CO_2\;eq$. in Atmosphere, $3.9310^{-6}kg\;CO_2\;eq$. in Refrigerator and $1.6710^{-6}kg\;CO_2\;eq$. in Vacuum. The study showed that the order of preference of the storage environments of biodiesel is vacuum environment, refrigerated condition and exposure to atmosphere.

An Experimental Study on the Chemical Soundness of Recycled Aggregate Concrete (재생골재 콘크리트의 화학안정성에 관한 실험적 연구)

  • 김무한;김규용;박선규;이정율
    • Journal of the Korea Concrete Institute
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    • v.11 no.4
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    • pp.13-20
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    • 1999
  • Recently, the study for practical construction application no recycled aggregate concrete is actively being proceeded, on the purpose of technical development for recycling on the construction waste concrete occurred at the time of destruction of building construction by the rapid increase of building wastes and exhaustion of natural aggregates. But, the durability of investigation with all sorts of fluidity and engineering property for application recycled aggregate concrete to practical construction must be done at the same time. Especially, because of the real condition for chemical attack of concrete construction by the acid rain, acidification of soil, deepening of air pollution and dirty water etc. being come to the fore a serious problem, the study on the chemical soundness of concrete durability must be accompanied. This study is composed as: I series: Analysis for chemical soundness of aggregates. II series: Analysis for chemical soundness of natural and recycled aggregate concrete against $Na_2$$SO_4$ solution in drying and wet curing condition ($at20~80^{\circ}C$).

Growth Decline of Pitch Pine Caused by Soil Acidification in Seoul Metropolitan Area (首都圈地域에서 土壤의 酸性化에 의한 리기다소나무의 生長 減少)

  • Rhyu, Tae-Cheol;Kim, Kee-Dae;Kim, Joon-Ho
    • The Korean Journal of Ecology
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    • v.17 no.3
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    • pp.287-297
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    • 1994
  • To elucidate the cause of growth decline of pitch pine (Pinus rigida) in Seoul, tree density, tree age and physico-chemical properties of soils were investigated at 33 sites of pitch pine forests in metropolitan Seoul, its vicinity and rural areas. The physical properties of soils except for soil texture in Seoul did not differ from those in rural areas. pH values, base saturation, and Ca and Mg contents of soils in Seoul, however, were significantly lower than those in suburbs and rural areas. In contrast, soluble Al and $S0_4^{2-}-S$ contents in Seoul were higher than those in rural areas. Low pH of forest soils in Seoul and suburbs seems to be caused by acid deposition. According to multiple regression analysis, growth of pitch pine in Seoul was affected by several factors in the following order: soil bulk density < Al content of soils < tree density < Mg contents of soil < tree age. We concluded that the acidification of forest soil can be a predisposing factor for the growth decline of pitch pine in metropolitan areas.

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The Effect of Acidification on Membrane Distillation Process for Strong Nitrogenous Wastewater (산화 전처리가 고강도 질소폐수의 막증류 공정에 미치는 영향)

  • Tun, Lat Lat;Jeong, Dawoon;Bae, Hyokwan
    • Journal of Korean Society on Water Environment
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    • v.36 no.2
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    • pp.137-147
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    • 2020
  • A direct contact membrane distillation (DCMD) was applied to treat strong nitrogenous wastewater of anaerobic digestion supernatant (ADS) and human urine (HU). The ammonia transfer was evaluated in terms of specific ammonia transfer (SAT) value, which is the ratio of total ammoniacal nitrogen divided by the amount of water transferred. The acidification resulted in low SAT values and high quality of produced water. The ammonia transfer control in the acidic condition was stronger for HU than ADS due to higher alkalinity (pH 8.8) and ammonia concentration (5700 mg-N/L) of HU. Acidified HU at pH 4 exhibited a SAT value of 1.64 × 10-5, which was significantly smaller than the SAT value of 3.00 × 10-3 for the original HU. The low pH enhanced the water flux for ADS, but HU showed a steep decrease in water flux due to enhanced fouling. It was considered that the fouling intensity in acidic conditions depends on the characteristics of the wastewater source. The major foulants on the MD membrane were NaCl, CaCO3 and CuSO4 as recognized by the SEM-EDS. Acidified ADS and HU at pH 4 showed relatively high N content of 8.18 % and 28.03 %, respectively, as organic fouling.

A Study on the Environmental Improvement with Resources of Livestock Wastes (축산분뇨 자원화로 환경오염 개선에 대한연구)

  • 연찬흠
    • Journal of the Korean Professional Engineers Association
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    • v.34 no.2
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    • pp.46-51
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    • 2001
  • It Is not uncommon to see some reports that livestock wastes are discharged into land, streams or seas without any treatment in the protective area of water resource. This study reports the development of the technique of protecting water resources through making use of treated livestock in organic farming after the procedures of collecting livestock wastes in 100% water tight PDF tanks, mixing Pedac, etc and fermenting. This techinque makes organic farming products possible without experiencing soil acidification caused by chemical fertilizer.

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