• Journal of Korean Society of Environmental Engineers
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• v.34 no.1
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• pp.55-62
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• 2012

The present paper investigates the performance of the KOH aqueous solution as an absorbent to capture carbon dioxide ($CO_2$). The chemical absorption was carried out according to consecutive reactions that are generated in the order of $K_2CO_3$ and $KHCO_3$. The overall absorption was completed with following the physical absorption. When the absorption was conducted with the KOH as the limiting reactants in batch a reactor, $K_2CO_3$ production rate was the 1st order reaction for $OH^-$. However, $KHCO_3$ generation reaction was independent of the $CO_3^{2-}$ concentration and the rate was calculated to be $0.18gCO_2/min$ for all KOH absorbents, which is the same value of the reaction rate using $K_2CO_3$ aqueous solution as the absorbents. The overall $CO_2$ capture ratio of the 5% KOH absorbent was estimated to be 19% and the individual value in section 1 and 2 was 57 and 12%, respectively. The amount of $CO_2$ absorbed in the solution was very slightly less than the theoretical value, which was ascribed to the side reaction that produces $K_2CO_3{\cdot}KHCO_3{\cdot}1.5H_2O$ during the reaction and the consequent diminish in $CO_2$ absorption in the KOH solution.

• Journal of Environmental Health Sciences
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• v.39 no.4
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• pp.360-368
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• 2013

Objectives: Phthalates are used in a large variety of products including as coatings of pharmaceutical tablets, film formers, stabilizers, dispersants, emulsifying agents, and suspending agents. They have been the subject of great public concern in recent years. The extensive uses of this material have attracted attention and issues regarding its safety have been raised. Methods: In this study, three types of phthalate skin permeation were studied using matrixes such as ointments, creams and lotions in vitro. The absorption of phthalate diesters [Dimethyl phthalate (DMP), Di-n-propyl phthalate (DPP) and Di-n-pentyl phthalate (DNPP)] using film former has been measured in vitro through rat skin. Epidermal membranes were set up in Franz diffusion cells and their permeability to PBS measured in order to establish the integrity of the skin before the phthalates were applied to the epidermal surface. Results: Absorption rates for each phthalate ester were determined and permeability assessment made to quantify any irreversible alterations in barrier function due to contact with the esters. Types of phthalate in vitro experimental results quickly appeared in the following order DMP > DPP ${\geq}$ DNPP. Conclusions: In the experimental results, lotion> cream> ointment, and the permeation rate of lotion with a great amount of moisture was the fastest. Skin permeation rate is generally influenced by the chemical characteristics of a given chemical, such as molecular weight and lipophilicity. As the esters became more lipophilic and less hydrophilic, the rate of absorption decreased.

• Korean Chemical Engineering Research
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• v.43 no.2
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• pp.294-298
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• 2005

Absorption and regeneration characteristics of sorbent used in a fluidized-bed process to capture $CO_2$ from flue gas have been measured in a thermo gravimetric analyzer. A sorbent Sorb NH prepared for fluidized-bed process was faster than pure $Na_2CO_3$ in absorption and regeneration reaction rate. Activation energy of apparent absorption reaction of sorbent Sorb NH was estimated as -10,100 cal/g mol and that of pure $Na_2CO_3$ as -12,200 cal/g mol. Activation energy of apparent regeneration reaction of sorbent Sorb NH was estimated as about 12,050 cal/g mol and that of pure $Na_2CO_3$ as about 11,320 cal/g mol.

• Journal of the Korean Wood Science and Technology
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• v.48 no.4
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• pp.488-502
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• 2020

In this study, the moisture absorption and desorption properties presented by the Health-Friendly Housing Construction Standards of South Korea were compared using the wood of three tree species (Douglas-fir, Hinoki, Larch) and two types of wood-based materials(Plywood, WML Board^Ⓡ). The national standards for functional building materials present that the amounts of moisture absorption and desorption should be at least 65g/㎡ on average, respectively according to the test method under KS F 2611:2009. Therefore, in this study, the moisture absorption/desorption properties of materials with no treatment (Control), with punching, and with surface stain finishing and the moisture absorption/desorption property improvement effects of the treatments were compared and analyzed. According to the results of this study, it was evaluated that all five types of wood and wood-based materials tested did not satisfy the amount of moisture absorption/desorption of at least 65g/㎡, which is the performance standard for moisture absorption/desorption functional building materials, indicating that untreated wood and wood-based materials cannot be applied as functional finishing materials according to the Health-Friendly Housing Construction Standards. The surface stain finishing greatly reduced the moisture absorption and desorption rates of the materials, and the amounts of moisture absorbed and desorbed were also shown to decrease by at least two times on average. When the surfaces of the materials were punched with Ø4mm holes at intervals of 20 mm, the moisture absorption/desorption areas increased from 18% to 51%, and this increase was shown to be capable of increasing the amounts of moisture absorbed/desorbed by 29% on average at the minimum, and 81% on average at the maximum. The effects of punching were shown to be identical even in cases where the materials were stain finished. For the application of wood or wood-based materials as eco-friendly, health-friendly, and moisture absorption/desorption functional building materials hereafter, it is judged that new physical and chemical improvement studies should be conducted, and treatment methods should be developed.

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.705-708
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• 2011

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.713-715
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• 2011

• Journal of the Korean Chemical Society
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• v.58 no.6
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• pp.681-685
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• 2014

• Proceedings of the Korean Vacuum Society Conference
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• 1997.02a
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• pp.178-178
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• 1997

• Journal of the Korean Chemical Society
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• v.34 no.3
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• pp.310-312
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• 1990

• Bulletin of the Korean Chemical Society
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• v.34 no.5
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• pp.1329-1330
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• 2013