• 대한화학회지
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• 제50권6호
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• pp.440-446
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• 2006

액체상태에 분산된 ZnO 분말을 레이저 ablation 시켜 ZnO 나노입자를 생성하였고, 계면활성제에 따른 생성된 나노입자의 특성을 비교하였다. 생성된 나노 입자는 UV-VIS 흡광 스펙트럼과 X-ray 회절 스펙트럼으로 순수한 ZnO 결정 상태를 나타냄을 확인하였으며, 전자투과 현미경 사진으로 나노입자의 크기, 크기 분포 및 모양을 관찰하였다. 순수한 물에서 얻어진 ZnO 나노입자의 밴드 갭 에너지는 3.35 eV로 bulk ZnO와 비슷한 값을 나타내었으며, 평균 크기는 27 nm로 막대모양의 입자들이 주로 생성되었다. SDS 용액에서 얻어진 ZnO 나노입자는 입자 크기가 평균 28 nm인 주로 구형에 가까운 형태를 가졌으며 CTAB 용액에서 나노입자는 막대 모양의 형태가 많으며 평균 크기가 40 nm 이었다. CTAB 용액에서 만들어진 ZnO 나노입자는 SDS 용액에서 만들어진 ZnO 나노입자 보다 더 안정하였다. 이러한 계면활성제에 따른 ZnO 나노입자의 크기 및 모양, 그리고 안정성의 차이는 ZnO와 계면활성제 사이의 전하 극성 차이로 인한 정정기적 인력과 용매화 차이로 설명할 수 있었다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2005년도 제24회 춘계학술대회논문집
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• pp.119-122
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• 2005

고온과 고속의 열악한 환경 속에서 발생하는 비행체의 삭마현상은 일반적으로 상변화를 수반하는 유체의 유동, 에너지 전달, 질량전달, 화학반응이 수반되기 때문에 해석과정이 복잡하다. 본 연구에서는 액체로켓엔진의 흑연노즐에 대하여 1차원적으로 삭마현상을 수치해석하고, 실험을 통하여 이를 비교 검토하였다. 낮은 연소압력과 산화제/연료비에서는 삭마가 거의 이루어지지 않았으며, 연소압력과 혼합비가 낮은 경우에는 해석결과의 신뢰도는 낮고 정상작동 구간에서의 해석결과와 실험결과가 차이가 많은 것으로 보아 화학적 삭마 외에 기계적 삭마도 상당하다.

• The Korean Journal of Pain
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• 제37권3호
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• pp.275-279
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• 2024

• Bulletin of the Korean Chemical Society
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• 제26권12호
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• pp.1991-1995
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• 2005

Sensitivity factors of elements by a glow discharge mass spectrometry (GD-MS) were intensively investigated and compared with a laser ablation inductively coupled plasma-mass spectrometry (ICP-MS). In case of copper matrix, the sensitivity factor by GD-MS generally decreases with the increase of the mass number of element. The details are a little different between each data measured by Faraday and multiplier detectors. The factor by a multiplier detector drastically decreases with the mass increase in the region of low mass as in Faraday detector’s case, but slowly in the high mass region. On the contrast, the sensitivity factor of solution standard by a conventional ICP-MS slowly increases with the increase of elemental mass number even though there are some exceptions such as gold and also the sensitivity factor by a laser ablation ICP MS generally increases with mass number of element in the specimen of glass type. In case of steel matrix, any definite trends could not be shown in the relationship between the GD-MS’s sensitivity factor and elemental mass.

• 대한기계학회논문집B
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• 제23권9호
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• pp.1201-1212
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• 1999

A numerical analysis is performed to predict the thermal response and ablation rate for charring or non-charring material which is designed to be used as thermal protection system (TPS). The numerical program composed of in-depth energy balance equation and the aerotherm chemical equilibrium (ACE) program. The ACE program calculates various thermochemical state from ablation products. The developed numerical program is verified by comparing the reported results from literature. The sensitivity tests for input parameters are performed. The thermal behavior of ablating material is mainly affected by density of ablating material, convective heat transfer coefficient and recovery enthalpy of flow field.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2006년도 제26회 춘계학술대회논문집
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• pp.141-143
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• 2006

추진기관 노즐 삭마에 대한 연구 결과를 보면 이 삭마라 불리는 현상에는 융삭(Ablation), 기계적 침식(Erosion), 그리고 화학적 부식(Corrosion)의 3가지 형태로 일어난다고 알려져 있다. 또 이 3가지 현상은 각각 작동 원으로 열전달 계수, 전단력, 화학적 농도 구배 등을 사용하여 표현 할 수 있다. 이 3가지 현상에 대하여 상관관계를 상사 해석 방법을 채택하고, 노즐 내벽의 가스 유속 즉 마하수를 노즐 형상(위치)의 함수로 표시하고 보면 총 삭마 현상을 각각의 현상의 크기를 비교해 볼 수 있다. 이 비교를 통하여 상호 크기를 비교해 본다.

• Nuclear Engineering and Technology
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• 제44권3호
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• pp.261-272
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• 2012

Molten Core Concrete Interaction (MCCI) is a complex process characterized by concrete ablation and volatile generation; Thermal and solutal convection in a bubble-agitated melt; Physico-chemical evolution of the corium pool with a wide solidification range (of the order of 1000 K). Twelve experiments have been carried out in the VULCANO facility with prototypic corium and sustained heating. The dry oxidic corium tests have contributed to show that silica-rich concrete experience an anisotropic ablation. This unexpected ablation pattern is quite reproducible and can be recalculated, provided an empirical anisotropy factor is assumed. Dry tests with oxide and metal liquid phases have also yielded unexpected results: a larger than expected steel oxidation and unexpected topology of the metallic phase (at the bottom of the cavity and also on the vertical concrete walls). Finally, VULCANO has proved its interest for the study of mitigation solutions such as the COMET bottom flooding core catcher.

• Design & Manufacturing
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• 제2권4호
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• pp.1-4
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• 2008

Micro pattern is applied to the light guiding plate(LGP) to enhance the uniformity of the brightness of the LCD. The micro cones are molded in intaglio on the surface of the LGP. The surface roughness of each cone was 40nm and 38nm in negative and positive die for laser ablation. In chemical etching, the surface roughness was 25nm, 24nm in negative and positive. And the surface roughness of negative and positive dies were 4nm and 5nm for LIGA-reflow process.

• Bulletin of the Korean Chemical Society
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• 제34권11호
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• pp.3274-3278
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• 2013

$CF_2Cl{\cdots}Cl$, an elusive photo-isomer of $CF_2Cl_2$, has been observed in matrix IR spectra from the precursors exposed to radiation from laser ablation of transition-metals. Other plausible products, $CFCl_2{\cdots}F$ and $FClC{\cdots}F-Cl$ are not detected due to their considerably higher energies. Parallel to its previously reported analogues, the C-X bonds are considerably stronger than those of the reactant, and particularly the Cl atom that is weakly bound to the residual Cl atom forms an unusually strong carbon-halogen bond. NBO analysis reveals that the C-Cl bond is a true double bond, and the weak $Cl{\cdots}Cl$ bond is largely ionic, $F_2C=Cl^{\delta+}{\cdots}Cl^{\delta-}$. IRC computation reproduces smooth inter-conversion between the reactant and product, and the transition state is energetically close to the product, consistent with its prompt disappearance in the early stage of photolysis.

• Bulletin of the Korean Chemical Society
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• 제31권4호
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• pp.798-802
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• 2010

From time-resolved optical emission spectra, we have investigated the effects of a transverse magnetic field on the expansion of a plasma plume produced by laser ablation of a ZnO:$P_2O_5$ ceramic target in oxygen active atmosphere. The emission spectra of $Zn^{+*}$, $P^{+*}$, and $Zn^*$ neutrals in the presence of magnetic field turn out to be considerably different from those without magnetic field. The characteristics of the deposited films grown on amorphous fused silica substrates by pulsed laser deposition (PLD) are examined by analyzing their photoluminescence (PL), X-ray diffraction (XRD), and UV-visible spectra.