• 제목/요약/키워드: charge transport

검색결과 473건 처리시간 0.025초

고에너지 볼 밀링이 Skutterudite계 CoSb3의 열전 및 전하 전송 특성에 미치는 영향 (Effect of High-Energy Ball Milling on Thermoelectric Transport Properties in CoSb3 Skutterudite)

  • 남우현;맹은지;임영수;이순일;서원선;이정용
    • 한국전기전자재료학회논문지
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    • 제28권12호
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    • pp.852-856
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    • 2015
  • In this study, we investigate the effect of high-energy ball milling on thermoelectric transport properties in double-filled $CoSb_3$ skutterudite ($In_{0.2}Yb_{0.1}Co_4Sb_{12}$). $In_{0.2}Yb_{0.1}Co_4Sb_{12}$ powders are milled using high-energy ball milling for different periods of time (0, 5, 10, and 20 min), and the milled powders are consolidated into bulk samples by spark plasma sintering. Microstructure analysis shows that the high-energy ball milled bulk samples are composed of nano- and micro-grains. Because the filling fractions are reduced in the bulk samples due to the kinetic energy of the high-energy ball milling, the carrier concentration of the bulk samples decreases with the ball milling time. Furthermore, the mobility of the bulk samples also decreases with the ball milling time due to enhanced grain boundary scattering of electrons. Reduction of electrical conductivity by ball milling has a decisive effect on thermoelectric transport in the bulk samples, power factor decreases with the ball milling time.

에이전트들 간의 밀접한 협력을 지원하기 위한 다중 에이전트 메시지 전송 구조 (A Multi-Agent Message Transport Architecture for Supporting Close Collaboration among Agents)

  • 장혜진
    • 정보처리학회논문지:소프트웨어 및 데이터공학
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    • 제3권3호
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    • pp.125-134
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    • 2014
  • 본 논문은 에이전트들 간의 긴밀한 협력을 위해 신속한 메시지 통신을 필요로 하는 응용 분야들을 지원하기 위한 다중 에이전트 메시지 전송 구조를 제안한다. 제안하는 구조는 FIPA(Foundation of Intelligent Physical Agents) 표준 에이전트 플랫폼 규격에서 에이전트들에게 메시지 전송 서비스를 제공하는 요소인 ACC(Agent Communication Channel)를 MTSA(Message Transfer Service Agent)라는 에이전트들의 집합으로 표현한다. MTSA는 비동기 메시지 통신을 지원하며, 메시지 수신을 효율적으로 처리하기 위해 반응자 패턴(reactor pattern)을 사용하며, 메시지 송신 에이전트와 수신 에이전트의 상대적 위치 관계에 따라 에이전트들 간에 최적의 통신 수단을 선택하여 메시지를 전송하여 에이전트들 간의 긴밀한 협력이 가능하도록 한다. 제안된 메시지 전송 구조에 따라 구현된 다중 에이전트 프레임워크 SMAF(Small Multi-Agent Framework)는 잘 알려진 에이전트 프레임워크 JADE(Java Agent Development Environment)와 비교하였을 때 향상된 메시지 전송 능력을 보인다. 다중 에이전트 구조의 메시지 통신 속도가 고속화되면 될수록 그 다중 에이전트 구조는 더 다양한 응용 분야들에 적용될 수 있을 것이다.

신선식품 콜드체인 EPS 패키징 시스템의 택배 유통환경 계측 (Measurement of Delivery Service Environment for Cold Chain EPS Packaging System of Fresh Food)

  • ;김수연;신양재;정현모;박종민
    • 한국포장학회지
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    • 제28권1호
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    • pp.67-73
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    • 2022
  • The food cold chain refers to a technology and distribution supply chain applied to maintain a constant temperature suitable for the product from production (harvest) to delivery to consumers. In particular, in Korea, the insulation material used in the food cold chain is mostly EPS (Expanded Polystyrene), which is used as a transport container for various food cold chains. However, according to the government's eco-friendly policy, companies charge environmental contributions to the use of EPS, but due to its low price and convenience of handling, it is still used as a container for delivering food. In this study, in order to measure the domestic delivery environment of general refrigerated foods, changes in impact, temperature, and humidity during transport of the EPS packaging system containing foods and ice pack refrigerants were measured. As a result, there were 2?3 sections in which a high impact force of 40 G or more was generated during transport. This can cause damage to the product and EPS container. The difference in temperature and humidity changes by parcel transport routes is more than 30%, so it is necessary to present accurate standards for the domestic cold chain distribution environment. As a result of microbial experiments. the transportation period had a dominant effect on the increase in total viable count and E. coli count.

Channel geometry-dependent characteristics in silicon nano-ribbon and nanowire FET for sensing applications

  • 최창용;황민영;김상식;구상모
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.33-33
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    • 2009
  • Silicon nano-structures have great potential in bionic sensor applications. Atomic force microscopy (AFM) anodic oxidation have many advantages for the nanostructure fabrication, such as simple process in atmosphere at room temperature, compatibility with conventional Si process. In this work, we fabricated simple FET structures with channel width W~ 10nm (nanowire) and $1{\mu}m$ (nano-ribbon) on ~10, 20 and 100nm-thinned silicon-on-insulator (SOI) wafers in order to investigate the surface effect on the transport characteristics of nano-channel. For further quantitative analysis, we carried out the 2D numerical simulations to investigate the effect of channel surface states on the carrier distribution behavior inside the channel. The simulated 2D cross-sectional structures of fabricated devices had channel heights of H ~ 10, 20, and 100nm, widths of L ~ $1{\mu}m$ and 10nm respectively, where we simultaneously varied the channel surface charge density from $1{\times}10^{-9}$ to $1{\times}10^{-7}C/cm2$. It has been shown that the side-wall charge of nanowire channel mainly affect the I-V characteristics and this was confirmed by the 2D numerical simulations.

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저온에서 La2/3+xTiO3-δ (x = 0, 0.13)세라믹스의 전자전도특성 (Low-Temperature Electron Transport Properties of La2/3+xTiO3-δ (x = 0, 0.13))

  • 정우환
    • 한국재료학회지
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    • 제24권11호
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    • pp.604-609
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    • 2014
  • The thermoelectric power and dc conductivity of $La_{2/3+x}TiO_{3-{\delta}}$ (x = 0, 0.13) were investigated. The thermoelectric power was negative between 80K and 300K. The measured thermoelectric power of x = 0.13 increased linearly with increased temperatures and was represented by $S_0+BT$. The x = 0 sample exhibited insulating behavior, while the x = 0.13 sample showed metallic behavior. The electric resistivity of x = 0.13 had a linear temperature dependence at high temperatures and a T3/2 dependence below about 100K. On the other hand, the electric resistivity of x = 0 has a linear relation between $ln{\rho}/T$ and 1/T in the range of 200 to 300K, and the activation energy for small polaron hopping was 0.23 eV. The temperature dependence of thermoelectric power and the resistivity of x = 0 suggests that the charge carriers responsible for conduction are strongly localized. This temperature dependence indicates that the charge carrier (x = 0) is an adiabatic small polaron. These experimental results are interpreted in terms of spin (x = 0.13) and small polaron (x = 0) hopping of almost localized Ti 3d electrons.

SPECTRAL DIAGNOSTICS OF NON-THERMAL PARTICLES IN THE SOLAR CHROMOSPHERE

  • FANG C.;XU Z.;DING M. D.
    • 천문학회지
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    • 제36권spc1호
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    • pp.55-61
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    • 2003
  • There are at least three effects of the non-thermal particle bombardment on the solar atmosphere: (1) non-thermal ionization and excitation; (2) proton-hydrogen charge exchange; (3) impact line polarization. Due to the non-thermal ionization and excitation effects of electron bombardments in flares, H$\alpha$ line is widely broadened and shows a strong central reversal. Significant enhancements at the line wings of Ly$\alpha$ and Ly$\beta$ are also predicted. In the case of proton bombardment, less strong broadening and no large central reversal are expected. However, due to proton-hydrogen charge exchange, the enhancements at the red wings of Ly$\alpha$ and especially of Ly$\beta$ lines at the early impulsive phase of flares are significant. Electron beam can also in some cases generates visible and UV continuum emission in white-light flares. However, at the onset phase, a negative 'black' flare may appear in several seconds, due to the increase of the $H^-$ opacity. The impact polarization of atomic lines can provide complementary information on the energetic particles, the energy transport and deposit in the solar chromosphere. New results of spectropolarimetric analysis for the major flare on July 23, 2002 are also given in the paper.

태양열 반응로용 나트륨 히트파이프의 열이송 특성에 관한 실험적 연구 (An Experimental Study on the Heat Transport Characteristics of a Sodium Heat Pipe for a Solar Furnace)

  • 부준홍;박철민;김진수;강용혁
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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    • pp.178-181
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    • 2008
  • Cylindrical stainless-steel/sodium heat pipe for a high-temperature application was manufactured and tested for transient and steady-state operations. The container material was made of stainless-steel 316, and the working fluid was sodium. Stainless-steel 316 mesh screen was inserted as a capillary structure. The working fluid fill charge ratio was approximately 64 $\sim$ 181% based on the pore space of the wick. The outer diameter of the heat pipe was 12.7 mm and the total length was 250 mm. The evaporator part was 150 mm and the condenser 80 mm. The performance test of the heat pipe has been conducted in the furnace with up to 800 W. The variation of the average heat transfer coefficient was investigated as a function of heat flux and vapor temperature. As input thermal load increased, it was showed that difference of temperatures in evaporator and condenser decreased and that operating section and heat transfer characteristics at the heat pipe increased.

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Polypyrrole-Glucose Oxidase 효소전극의 전기화학적 특서: 1. 효소전극의 산화환원에 대한 Glucose Oxidase의 영향 (Electrochemical Properties of Polypyrrole-Glucose Oxidase Enzyme Electrode: 1. An Influence of Glucose Oxidase on Redox Behavior of Enzyme Electrode)

  • 김현철;구할본;사공건
    • 한국전기전자재료학회논문지
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    • 제13권6호
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    • pp.520-525
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    • 2000
  • Glucose oxidase was immobilized in polypyrrole by electrosynthesis. The enzyme had an influence on the redox properties of a complex enzyme electrode. In the cyclic voltammograms of the enazyme electrode new peaks were appeared at the potential around 0.7V vs. Ag/AgCl in additional to the typical peaks for polypyrrole. The more immobilized the stronger the peaks became. During the cycling the pH of electrolyte solution was decreased to about 4.4 The reason for that is to be the proton released from the carboxyl in the glucose oxidase in order to keep on a charge neutrality of the oxidized enzyme. This fact suggests that the new peaks in the voltammograms are caused by the redox of glucose oxidase. In the AC impedance spectrum analysis of the electrode the diffusion of electrolyte anion was limited because of chained structure of the enzyme. The faradic impedance was large since the glucose oxidase is an insulator. Therefore when glucose oxidase is entrapped the enzyme should be limited in amount. Because the growth of the polypyrrole is accompanied both charge transfer and mass transport. For the traditional electrosynthesis that means amount of enzyme present in the electrode is limited to as much as film growable.

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Electronic transport properties of linear carbon chains encapsulated inside single-walled carbon nanotubes

  • Tojo, Tomohiro;Kang, Cheon Soo;Hayashi, Takuya;Kim, Yoong Ahm
    • Carbon letters
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    • 제28권
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    • pp.60-65
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    • 2018
  • Linear carbon chains (LCCs) encapsulated inside the hollow cores of carbon nanotubes (CNTs) have been experimentally synthesized and structurally characterized by Raman spectroscopy and transmission electron microscopy. However, in terms of electronic conductivity, their transportation mechanism has not been investigated theoretically or experimentally. In this study, the density of states and quantum conductance spectra were simulated through density functional theory combined with the non-equilibrium Green function method. The encapsulated LCCs inside (5,5), (6,4), and (9,0) single-walled carbon nanotubes (SWCNTs) exhibited a drastic change from metallic to semiconducting or from semiconducting to metallic due to the strong charge transfer between them. On the other hand, the electronic change in the conductance value of LCCs encapsulated inside the (7,4) SWCNT were in good agreement with the superposition of the individual SWCNTs and the isolated LCCs owing to the weak charge transfer.

Preparation and Photoelectrochemical Behavior of Cu2O/TiO2 Inverse Opal Heterojunction Arrays

  • Kim, Hyun-Sik;Lee, Sang-Kwon;Kang, Soon-Hyung
    • 전기화학회지
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    • 제15권3호
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    • pp.149-153
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    • 2012
  • The $Cu_2O/TiO_2$ inverse opal heterojunction arrays were developed by electrochemical deposition of $Cu_2O$ nanoparticles on $TiO_2$ inverse opal arrays. The $Cu_2O$ nanoparticles completely filled the inner pores of $TiO_2$ inverse opal film (prepared by liquid phase deposition with an average thickness of 400 nm) and covered the entire area; exhibiting high crystalline properties of anatase and cubic phase from $TiO_2$ and $Cu_2O$, respectively. From asymmetric current-voltage profile, it was noticeable that a heterojunction was well formed for charge transport from $Cu_2O$ to $TiO_2$ film resulting from the enhanced charge separation yield. In addition, increased photocurrent of 0.19 $mA/cm^2$ (versus 0.08 $mA/cm^2$ under dark condition) was obtained at -0.35 V from the heterojunction structure in the 0.5M $Na_2SO_4$ solution.