• 한국염색가공학회지
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• 제11권6호
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• pp.36-42
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• 1999

The antimicrobial activities of the copolymer of N,N'-dimethyl- N,N'-diallyl ammonium chloride(DMDAAC) and diallyl amino(DA) were investigated. The copolymer of DMDAAC and DA was prepared by free radical Polymerization through an intra-intermolecular propagation mechanism ie, cyclopolymerization. The copolymer was, then, reacted with cyanuric chloride for reactivity with hydroxyl group of cellulose. Cotton fabrics were finished by synthesized polymer, and their antimicrobial activities and fastness to launderings were tested. Dichlorotriazinyl DMDAAC-DA copolymer has MIC value of 1ppm against S. aureus and 10ppm against K pneumoniae. The antimicrobial fastness of the finished cotton to launderings were good enough to show colony reduction above 70% against S. aureus and K pneumoniae after 50 repeated laundering in anionic commercial detergent. Optimum treatment concentrations of the polymer were 0.5% in cold pad-batch method, and 0.1% in pad-dry method.

• 한국염색가공학회지
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• 제15권4호
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• pp.43-50
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• 2003

N-methylmorpholine-N-oxide(NMMO) is recently hewn as a solvent dissolving cellulose to produce a new regenerated cellulosic fiber, lyocell. In this study, four kinds of cellulosic fibers (lyocell, regular cotton, treated cotton with 50% and 75% NMMO aqueous solution) was examined and compared in terms of mechanical properties and dyeability. The swelling of cotton treated with NMMO aqueous solution is higher than that of cotton treated with water. In dyeing rate, the cotton treated with NMMO was faster than regular cotton. NMMO treatment decreased the crystallinity of cotton fabrics and improved their softness and smoothness.

• 한국염색가공학회지
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• 제10권6호
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• pp.49-54
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• 1998

The antimicrobial activities of the copolymer of N,N'-dimethyl-N,N'-diallyl ammonium chloride (DMDAAC) and acrylamide(AA) were investigated. A series of copolymers with various ratios of DMDAAC and AA were prepared by free radical initiation via an intra-intermolecular propagation mechanism, ie, cyclopolymerization, and the antimicrobial activities of the prepared copolymers were measured by minimum inhibitory concentration(MIC) test. The copolymers were, then, methylolated under basic condition for reactivity with hydroxyl group of cellulose. Both antimicrobial activity and fastness to laundering of the cotton fabrics finished using the methylolated copolymers were evaluated. From the results it was shown that the copolymers with different ratios of DMDAAC and AA have MIC values in the range of 1∼100ppm. As the ratio of AA in the copolymers increases, the anitmicrobial activity decreases. The fastness of the cotton fabric finished by the methyolated copolymers to 10 repeated launderings in anionic commercial detergent is good enough to show colony reduction above 90％ regardless of DMDAAC and AA ratios.

• 한국염색가공학회지
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• 제21권5호
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• pp.10-15
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• 2009

A mixed bi-functional reactive dye has been applied to the cotton and the cotton/hemp blend and their dyeing and fastness properties were compared. The cotton/hemp blend exhibited higher exhaustion values and better build-up property than cotton, presumably due to the lower crystallinity. Hence, the reproducibility of dyeing of hemp is expected to be excellent. Fastness properties of reactive dyes on cotton and cotton/hemp blend are found to be almost identical. The results obtained suggest that hemp in cellulosic fabric could be used as an important alternative to universal cotton in cellulose fabrics.

• 한국염색가공학회지
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• 제11권1호
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• pp.48-60
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• 1999

In this paper, a new regenerated celluosic fiber, "Tencel" was treated with cellulase enzyme. Also Tencel fabrics were pretreated with NaOH and dyed with various reactive dyes, and subsequently finished with DMDHEU. $\Delta{E}^*_{ab}$ value was calculated by measuring color difference before and after wet abrasion test to rubbing. The fibrillation propensity was estimated on Tencel by means of weight loss, $\Delta{E}^*_{ab}$ value, and SEM observation. Weight loss of NaOH pretreated Tencel fabric is more lower than that of original fabric. The cellulase treatment decreased tensile strength but improved wet abrasion strength, wrinkle recovery, and bending properties. Tendency of fibrillation for Tencel fabric was reduced by NaOH-pretreatment, dyeing with multifunctional reactive dyes, and afterfinishing by DMDHEU.by DMDHEU.

• 한국의류학회지
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• 제20권5호
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• pp.841-851
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• 1996

The purpose of this study is to investigate the backstaining generated during cellulase treatment for indigo-dyed denim. The results were as follows. 1. High generating conditions of the backstaining were as same as best conditions for cellulose activity (temperature at 6$0^{\circ}C$, pH at about 4.5~5.5, treatment time at 40 min. and enzyme concentration at 2g/l). And also, liquor ratio, sample weight and repeated-use cycle of liquor had influenced on the backstaining. 2. The backstaining was decreased about 30~40% when various additives, that is, surfactant, anti-backstaining agent (C.M.C) and softners were added. 3. A application of image processing on the backstaining evaluation was more effective than method by reflectance, particullarly in out of level fabrics. In image analysis, the backstainings were measured by histogram between 256 gray levels.

• 대한가정학회지
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• 제19권4호
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• pp.9-15
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• 1981

damages of cotton cloth and characteristics of fabroid degradation were studied by Chaetomium globosum and Aspergillus niger which presupposed as powerful erosive fungi to cellulose fiber by means of tensile strength. The results obtained are as follows: 1. the growth(rate) of fungi in malt extract agar was superior to potato agar for two weeks. 2. Chaetomium globosum showed mostly severe damage t the cotton cloth in malt extract agar media at pH 4.5. 3. Tensile strength was reduced with time by Aspergillus niger-coenzyme and Chaetomium globosum-coenzyme reaction. In comparison with Chaetomium globosum and Aspergillus niger, the former weaken tensile strength about 15.8% and the latter enfeebled 10.0% after 124 hours. 4. after 30 days the breeding of fungi in pH 4.5 malt extract agar media, critical damage of cotton cloth was observe, I. e., 92.4% damage by chaetomium globosum and 74.9% lose by aspergillus nige respectively.

• 한국의류학회지
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• 제33권11호
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• pp.1696-1706
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• 2009

Nonwoven fabrics have been widely used in various fields that include household, industrial, agricultural, medical goods, especially in the automobile industry. In this study, eco-friendly fiber materials were developed and investigated as a substitute material for polyester fibers in nonwovens. To make plant fiber bundles, stems of Indian mallow (IM), and Kuzu vine (KV) were retted; in addition, the non-cellulose component was partially removed. Plant fiber bundles and polyester fibers (P) were blended and needle punched to produce nonwovens. Five kinds of nonwovens were manufactured: P100 (Polyester 100%), IM10 (IM 10% and Polyester 90%), IM20 (IM 20% and Polyester 80%), KV10 (KV 10% and Polyester 90%), and KV20 (KV 20% and Polyester 80%). The color values, surface appearance, tensile strength, elongation, tear strength, abrasion strength, flexstiffness, moisture regain, water or oil absorbency, and static electricity of manufactured nonwovens are investigated. As the blended ratios of IM or KV increased, the brightness of nonwovens decreased compared to that of polyester 100%. Tensile strength, tear strength, abrasion strength, and flexstiffness of IM10 as well as KV10 were higher than those of P100, IM20, and KV20, resulting from the influence of the structure and properties of nonwoven fibers. Moisture regain and water or oil absorbency increased, while static electricity decreased in proportion to the amount of plant fibers. IM or KV and polyester blended nonwovens showed improved properties over P100 that could be substituted for P100 as a novel material for textiles.

• 한국염색가공학회지
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• 제11권1호
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• pp.16-24
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• 1999

The effects of two-step fixation of steaming and baking on the dischargeability of cotton fabrics dyed with C.I. Reactive Black 5(Bl-5) were investigated when the concentrations of $K_2CO_3$ and benzaldehyde sodium bisulfite(BASB) were increased over 120/kg. Remarkably increased dischargeability resulted from baking for 3 min or more at 160t after steaming for 8 min or more at $102^\circ{C}$, but 120g/kg or more amounts of $K_2CO_3$ and BASB(50%) had little influence on dischargeability. Therefore the discharge mechanism can be suggested that covalent bonds between cellulose and Bl-5 undergo $S_N2$ attack by hydroxide ion formed by the reaction of $K_2CO_3$ and water in steaming at $102^\circ{C}$ first and then, through transition states they are cleavaged in baking at 160t to yield hydrolyzed Bl-S and compounds of BASB and Bl-5 isolated from fiber, which are undyeable and removed by washing. The effect of urea, one of the hydrotrope agents, on discharge printing was also studied. The result which dischargeability was greatly improved by increasing the steaming time from 8 min to 15 min at $102^\circ{C}$ or by increasing the amount of urea obviously shows that water in steaming and urea in print paste play an important role in discharge printing. And as an increase of the baking time from 5 min to 7 min at $160^\circ{C}$ makes it possible to improve dischargeability, it is once more confirmed that high temperature of about 160t is exactly required to discharge the dyed Bl-5. The colored discharge printing demands a more amount of urea because urea contributes to the putting color fixation as well as the discharge reaction.

• 한국의류산업학회지
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• 제24권6호
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• pp.801-811
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• 2022

In this study, we constructed a database of dyeing concentrations of all reactive dyes used for dyeing linen according to the thickness of the linen fabric and attempted to improve the reproducibility of the dyeing process for the commercialization of linen fabric materials. Linen fabric is a natural cellulose material that is comfortable and suitable for eco-friendly trends. It is a typical summer material with excellent breathability and thermal conductivity, quick moisture absorption and dissipation, and a cool touch. Dyeability and fastness were evaluated depending on the thickness of the linen fabric using a monochlorotriazine (MCT) reactive dye and bifunctional yellow, red, and blue dyes. All three colors of the MCT reactive dye and bifunctional dyes exhibited a darker shade as the fiber thickness of the marker increased. Fastness to washing was excellent at grades 4-5 or higher, regardless of the color of the dye and the number of linen fabrics. Although some color-fastness differences were noted, with the color change occurring most frequently with blue color, the fastness variations with dye type were mostly similar. The results of this study are expected to facilitate the selection of reactive dyes according to the thickness of the linen fabric based on the basic data from the laboratory, which will aid in the mass production of linen fabric and benefit the fashion industry.