• Title/Summary/Keyword: cellulose I

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Dyeing Properties Resin Treatment Effects of the Lyocell Fabrics (리오셀 직물 수지가공 효과와 염색성)

  • Yoo, Hye-Ja;Lee, Hye-Ja
    • Journal of the Korean Society of Clothing and Textiles
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    • v.32 no.7
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    • pp.1095-1103
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    • 2008
  • The effects of resin finish and dyeabilities of four kinds of Iyocell fabrics that were manufactured by four kinds of pulps were investigated. The dyeabilities of Iyocell fabrics were similar, but differed from cotton fabric. In early stage of 30 minutes, cotton fabric was shown higher dye exhaustion ratio than Iyocell fabrics, however after then cotton fabric did not increase dye exhaustion, Iyocell fabrics increased continuously. At last, the dye exhaustion ratio of Iyocell fabrics were about 75% and that of cotton fabric was 65%. Two kinds of experimental procedures were applied for Iyocell fabrics. One was what the fabrics were treated with resins and washed with cellulase, and then dyed with reactive dyes. The other procedure was the fabrics were dyed with reactive dyes, and then applied the resin treatments and cellulase washing. After fibrillation and washing the undyed Iyocell fabric and the Iyocell fabric that was dyed with C.I.Reactive Red 120, their weight loss ratios were 3.5% and 2.8%, respectively. Dyeing with reactive dyes caused the crosslinking between cellulose and dyes and the crosslinking decreased fibrillation. The weight loss by enzyme washing of Iyocell fabrics decreased by the glyoxal and melamine resin treatments. The reduction of weight loss can be caused by fibrillation decrease. Dyeing and resin treating can be showed the synergic effect on the reduction of fibrillation. The effect of glyoxal resin on the reduction of fibrillation was a little better than that of melamine resin.

Properties of Cellulase Produced from Cellulomonas sp. YE-5 (Cellulomonas sp. YE-5가 생산하는 Cellulase의 특성)

  • 최동철;김동섭;오두환;유주현
    • Microbiology and Biotechnology Letters
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    • v.20 no.2
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    • pp.164-168
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    • 1992
  • Enzymatic properties of avicelase, carboxymethyl cellulase (CMCase) and P-glucosidase produced by Cellulomonas sp. YE-5 were studied. Optimal temperature and pH of avicelase were 40t and 6.0, and those of CMCase and P-glucosidase were $45^{\circ}C$ and 6.5. Avicelase and CMCase were stable between pH 5.0 and 9.5, and &glucosidase was stable between pH 5.5 and 8.0. Avicelase and P-glucosidase were inactivated when incubated at $35^{\circ}C$ for 6 hrs, and CMCase was at $40^{\circ}C$ for 6 hrs. All cellulases were strongly inhibited by $Cu^{2+} \; and \; Zn^{2+}. K_m$ values of avicelase for avicel, CMCase I and CMCase II for CM-cellulose, and ($\beta$-glucosidase for p-nitrophenyl-$\beta$-D-glucoside (PNPG) were 4.76, 16.4, 16.4 $\mu g$/ml and 3.51 mM, respectively.

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Mechanical Properties and Fabric Handle of kansan Bamie (Part I) (한산 모시의 역학적 특성 및 태에 관한 연구(제1보))

  • 홍지명;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.8
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    • pp.1315-1322
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    • 1997
  • Ramie is one of the traditional fabrics in Korea, and very comfortable fabric for summer clothes because it has a high moisture-absorbing and transporting property. Futhermore ramie is very popular and Koreans prefer its handle for summer clothes. The kansan ramie has better quality as fibers and can be weaved as fine fabrics which are famous as kansan Fine ramie. Even though the good quality of kansan ramie has known widely, very few research work have been carried out on kansan ramie in the field of textile science. In this study, the analysis of the physical and chemical characteristics of Hansan ramie was conducted by using two different kinds of Hansan ramie: Hansan Fine ramie and kansan Coarse ramie. In addition, the same experiment was held on the one kind of chinese ramie to be compared with those of Hansan ramie. The following results were obtained from this experimental study. By the analysis of chemical composition of ramie, the similar chemical composition (a -cellulose: 83∼85%, pectin substances: 2.81∼ 3.01%) were found from all of the ramie fabrics used in this study. It has shown that Hansan coarse ramie has the highest toughness value and wrinkle recovery angle among the samples used in this study. From the result of KES-F system, it was found that Hansan Coarse ramie which is composed with the thicker yarns has the highest value on the bending properties, 2HG and surface properties. The primary hand value was also calculated by KN-203 LDY and value of Koshi was shown as the order of kansan coarse ramie> Chinese ramie> kansan fine ramie, and Hansan fine ramie had shown the highest Numeri and Fukurami value among the 3 samples used in this study.

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Effect of Red Ginseng Water Extract on Trypsin Activity (홍삼 물추출물이 Trypsin 활성에 미치는 영향)

  • Lee, Jong-Won;Kim, Na-Mi;Do, Jae-Ho
    • Journal of Ginseng Research
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    • v.28 no.3
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    • pp.127-131
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    • 2004
  • This study was carried out to investigate the effect of red ginseng water extract (RGWE) on trypsin activity. After extraction of fat soluble and saponin component from red ginseng powder by methyl alcohol, the residue was extracted with distilled water, and manufactured to water extract. The extract was dialyzed with different molecular cut off membrane. Trypsin activity demonstrated the highest level at the RGWE concentration of 9${\times}$10$\^$-2/% in reaction mixture, and also increased to 15% at 2.9${\times}$10$\^$-3/%. Km value was decreased and Vmax was increased in the present of red ginseng water extract. Red ginseng water extract was partially purified by dialysis, Bio-Gel P-I0 and DEAE-cellulose column chromatography. The active fraction demonstrated positive reaction to ninhydrin, DNS and folin reaction.

Study on Solid-liquid Mixture Flow in Inclined Annulus (경사 환형관내 고-액 혼합 유동특성에 관한 연구)

  • Kim, Young-Ju;Kim, Young-Hun;Woo, Nam-Sub
    • Journal of Ocean Engineering and Technology
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    • v.25 no.5
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    • pp.15-20
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    • 2011
  • This study carried out a series of experiments involving impact tests (Drop Weight type & Charpy type with a standard specimen and newly designed I-type specimen), hardness tests, and fracture surface observations of French-made roll shell steel (F), abnormal roll shell steel (M), reheated roll shell steel (R), and S25C steel under heat treatment conditiAn experimental study was carried out to study the solid-liquid mixture upward hydraulic transport of solid particles in vertical and inclined annuli with a rotating inner cylinder. The lift forces acting on a fluidized particle play a central role in many important applications such as the removal of drill cuttings in horizontal drill holes, sand transport in fractured reservoirs, sediment transport, the cleaning of particles from surfaces, etc. In this study a clear acrylic pipe was used to observe the movement of solid particles. Annular velocities varied from 0.4 to 1.2 m/s. The effect of the annulus inclination and drill pipe rotation on the carrying capacity of a drilling fluid, particle rising velocity, and pressure drop in a slim hole annulus were measured for fully-developed flows of water and aqueous solutions of CMC (sodium carboxymethyl cellulose) and bentonite. The rotation of the inner cylinder was efficient at carrying particles to some degree. For a higher particle volume concentration, the hydraulic pressure loss of the mixture flow increased because of the friction between the wall and solids or between solids.

A Study on Using Gray Color Dyeing from Gallapple (오배자에 의한 회색계열 염색에 관한 연구)

  • Shin, Nam-Hee;Kim, Sung-Yeon;Cho, Kuyung-Rae
    • Fashion & Textile Research Journal
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    • v.7 no.5
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    • pp.547-552
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    • 2005
  • The study has objective in raising value of the gray color as a meaningful color suiting sentiments of modern people by expressing the gray color in various perspective utilizing natural dyes that is natural at the same time having aesthetic color tones. For example, the main ingredient used for coloring black and gray color is the pyrogallol tannin and the gray tone dye can be acquired by combining the tannin with iron. In order to find the suitable condition for processing tannin, UV-Vis part absorption spectrum of Gallapple pyrogallol tannin, dye ability based on temperature and time, reflection rate based on concentration, color changes based on acid treatment and alkali treatment, changes on surface based on concentration or metal mordant condition, and lightfastness were measured. Maximum absorption wavelength (${\lambda}_{max}$) of Gallapple tannin was at around 273 nm, while strong absorption was also observed at below 350 nm. Dye ability of Gallapple tannin is done more easily on silk rather than cellulose fibers such as cotton, while the optimum condition for dyeing was observed to be at $60^{\circ}C$, for 20 minutes. As a result of acid treatment, the color of dye material consist highly of gray tones and showed red tone after the alkali treatment. While it was observed that as dye concentration and metal mordant concentration increased the color changed at counter-clockwise direction on the Y-scale of Munsell's scale of colors. Lightfastness was more on a normal fading. I hope this study opens up possibilities towards presenting gray color expressed from tannin as color with diversity and aesthetic value. In future, comparative study between dye expressed from catechol tannin dye materials will be helpful.

Influence of N-Fertilization on Growth , Yield and Nutrient Quality of Forage Job`s Tears [ Coix lachryma-jobi L. var. mayeur STAPF ] (청예 사초용 율무의 질소시비수준이 생육특성과 사료성분에 미치는 영향)

  • 안계주;권병선;김찬호
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.12 no.2
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    • pp.127-131
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    • 1992
  • To find out the optimum fertilizer levcl for Job's Tears, Seungju local cultivar, experiment with six fertilizer levels was conducted on the experimental field of forage crop in Sunchon National University from Apr. 1989 to Aug. 1990. The results obtained were summarized as follows: I .Raising nitrogen(N) application rate up to 13.5 kg/lOa increased dry matter yield linearly. However, at high N application rate, 18 kg/lOa, plants were too leafy and parts of leaves and lodging were decreased. so that dry matter yield was decreased.2. The optimum application rate of fertilizers turned out to be 13.5-6-6 kg/lOa of $P_2O_5$, $K_2O$. Content of crude protein, yield of fresh and dry matter were the highest and that of crude fiber such as NDF. ADF and cellulose were the lowest at this rate.

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Determination of Airborne Fiber Size and Concentration in RCF Manufacturing and Processing Factories (세라믹 섬유 제조 및 가공 공정에서 발생된 공기중 섬유의 농도 및 크기 분포)

  • 신용철
    • Journal of Environmental Health Sciences
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    • v.26 no.4
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    • pp.21-28
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    • 2000
  • Various man-made mineral fibers(MMMF) including refractory ceramic fiber(RCF) have been used widely in industries as insulation materials. The effect of fibrous dust on human health depends on fiber size, concentration (exposure level), and durability in biological system. Therefore, these parameters should be determined to evaluate accurately the potential risk of fibers on human health. The purpose of this study was to characterize the size of airborne fiber and the workers' exposure to airborne fibers in refractory ceramic fiber manufacturing and processing factories. Airborne fibers were collected on 25-mm mixed cellulose ester membrane filters at personal breathing zones, and analyzed by A and B counting rules of the National Institute for Occupational Safety and Health(NIOSH) Method # 7400. The average ratios of the fiber density by B rule to the fiber density by A rule was 0.84. This result indicates that the proportion of respirable fibers (<3 ${\mu}{\textrm}{m}$ diameter) in air samples was high. The average diameter and length of airborne fibers were 1.05${\mu}{\textrm}{m}$ and 35${\mu}{\textrm}{m}$, respectively. The average fiber concentrations (GM) of all personal samples was 0.26f/cc, and the average concentration was highest at blanket cutting and packing processes. The fifty seven percent of personal air samples was exceeded the proposed American Conference of Governmental Industrial Hygienists(ACGIH) Threshold Limit Value(TLV), i.e. 0.2 f/cc. It was concluded that the RCF industrial workers had the higher potential health risk due to small fiber diameter, long fiber length, and high exposure level to the airborne fibers.

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A Study on the Fabrication of Multi-Walled Nanotubes (MWCNT) Based Thin Film and Chemical Sensor Operation Characteristics (Multi-Walled Carbon Nanotubes (MWCNT) 인쇄박막의 제작과 화학센서 동작 특성에 관한 연구)

  • Noh, Jae Ha;Choi, Junseck;Ko, Dongwan;Seo, Joonyoung;Lee, Sangtae;Jung, Jung-Yeul;Chang, Jiho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.3
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    • pp.181-185
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    • 2020
  • Hazardous and noxious substance (HNS) detection sensors were fabricated using multi-walled carbon nanotubes (MWCNTs) and various binder materials for ion batteries. To obtain uniformly printed films, the printing precision according to the substrate cleaning method was monitored, and the printing paste mixing ratio was investigated. Binders were prepared using styrene butadiene rubber + carboxymethyl cellulose (SBR+CMC), polyvinylidene fluoride + n-methyl-2-pyrrolidene (PVDF+NMP), and mixed with MWCNTs. The surface morphology of the printed films was examined using an optical microscope and a scanning electron microscope, and their electrical properties are investigated using an I-V sourcemeter. Finally, sensing properties of MWCNT printed films were measured according to changes in the concentration of the chemical under the various applied voltages. In conclusion, the MWCNT printed films made of (SBR+CMC) were found to be feasible for application to the detection of hazardous and noxious chemicals spilled in seawater.

Dyeability and Colorfastness of Knitted Fabrics with Natural Dye PinuxTM (Part I)

  • Wang, Geom-Bong;Song, Kyung-Hun
    • Journal of the Korean Society of Clothing and Textiles
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    • v.35 no.12
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    • pp.1477-1485
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    • 2011
  • Dyeability and colorfastness of the blended knits of cotton/rayon (40/60; C/R) and wool/tencel (10/90; W/T) are examined using the natural dyestuff ($Pinux^{TM}$) manufactured from Pinus radiata pine bark extract. In addition, pre-treatments (such as bleaching, mercerization and cationization) are performed to improve dyeability and colorfastness. The $Pinux^{TM}$ powder dyestuffs produced by Pinux Co., Ltd. are used as dyestuffs and their properties are examined for dyeing concentration (0.5-2% (owb)), dyeing time (30-120 minutes) and dyeing temperature (30-$90^{\circ}C$). Dyeability is evaluated with K/S value at 400nm, which is the maximum absorption wavelength for $Pinux^{TM}$. The results show the dyeability of W/T sample containing protein fiber with $Pinux^{TM}$ is superior to all cellulose fiber C/R. A concentration of dyestuff greater than 1.5% (owb), dyeing time 120 minutes and dyeing temperature of $90^{\circ}C$ are the most optimized conditions. It shows that the dyeability of C/R and W/T samples are high in the condition of an acid-dyeing bath and that dyeability highly declined in alkaline bath due to the instability of the proanthocyanidin pigment. After analyzing the effect of bleaching, mercerizing and cationizing (as pre-treatments on dyeability) it was concluded that the dyeability of the C/R sample was enhanced by mercerization but no significant effect by cationization. However, the simultaneous treatment of cationizing and dyeing resulted in far improved dyeability compared to dyeing after cationizing pre-treatment. As for the W/T sample, the effect of cationization was more prominent than the C/R sample. Colorfastness to color changes in the control W/T sample was higher than that of C/R's level 1-2, and it increased to Level 2 when bleaching pre-treatment was given and when a simultaneous cationizing treatment was adopted to the dyeing process. Colorfastness to light in W/T control sample resulted in Level 3 and further increased to an excellent Level of 4 with bleaching and simultaneous cationizing during dyeing process.