• Title/Summary/Keyword: cell microstructure

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Effects of electrode fabrication conditions on performance characteristics of phosphoric acid fuel cell (인산형 연료전지 성능 특성에 미치는 전극 제조 조건의 영향)

  • 송락현;김창수;신동렬
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.45 no.2
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    • pp.224-229
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    • 1996
  • Performance characteristics of single cell in phosphoric acid fuel cell were studied for various electrode fabrication parameters such as teflon content, electrode structure, thickness of electrocatalyst layer, platinum content and electrode area. The performance of single cell was decided from the measured voltage-current through a load change. The electrode of 40wt.% teflon exhibited high initial performance of single cell, but in the long term operation, the cell performance of 45 wt.% teflon was better. Also the single cell appeared good performance in case of electrodes with duplicate structure, thin electrocatalyst in thickness, more platinum content, and small area. These results of cell performance were discussed as related to the electrolyte flooding, formation of 3 phase boundary area, internal resistance of electrode, and microstructure of electrode.

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Optimum Design of a Compact Heat Exchanger with Foam Metal Insertion (발포금속을 삽입한 밀집형 열교환기 최적 설계)

  • 이대영;진재식;강병하
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.7
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    • pp.612-620
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    • 2001
  • The optimum design of a heat exchanger with porous media insertion is studied in this paper. It is considered that the aluminum foam metal is inserted in a flat plate channel and air flows through it. The influence of the microstructure of the foam metal on the pressure drop and heat transfer is investigated utilizing previous analytical results and existing correlation equations. Design parameters are identified as the unit-cell size and the ligament thickness of the porous medium, and their effects are examined. The results show that there exists optimum microstructure of the porous media maximizing heat transfer with a constant pressure drop. When the increase in the pressure drop is within a practically acceptable range, the increase in the heat transfer is dominated by the increase in the heat transfer area due to the porous medium insertion. Consequently, among the porous media with a constant pressure drop, the heat transfer is maximized with a microstructure with maximum specific surface area.

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The Effect of Trace Metallic Additives on Microstructure, Surface Appearance and Hardness of Zn Electrodeposits (아연도금층의 조직, 외관, 및 경도에 미치는 미량 금속첨가의 영향)

  • 예길촌;김대영;안덕수
    • Journal of the Korean institute of surface engineering
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    • v.37 no.1
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    • pp.28-39
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    • 2004
  • The effect of trace metallic additives on microstructure, surface appearance and hardness of zinc electrodeposits was investigated by using sulfate bath and flow cell system. The preferred orientation of Zn deposit with Fe additive was (103)(104)+(002) mixed texture and that of Zn deposits with both Fe-Ni and Fe-Co additives was (10 1), while Zn deposits with Fe-Cr additives had (002) preferred orientation. The surface morphology of the zinc deposits was closely related to the preferred orientation of the deposits. The glossiness of Zn deposit with Fe-Ni additives was higher than that of pure Zn deposit, while the glossiness of Zn deposits with both Fe-Co and Fe-Cr additives was lower than that of pure Zn deposit. The hardness of Zn deposits with both Fe-Ni and Fe-Co additives was noticeably higher than that of Zn-Fe deposit, while that of Zn deposit with Fe-Cr additives was similar to that of Zn-Fe deposit.

Microstructure of Lupin Seed;a Comparative Study With Soybean (루핀콩과 대두의 미세구조에 관한 비교 연구)

  • Lee, Cherl-Ho;Kim, Jeong-Kyo
    • Korean Journal of Food Science and Technology
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    • v.17 no.6
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    • pp.454-459
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    • 1985
  • The structure of the seed of Lupinue angustifolius was studied in order to investigate the Food quality of lupin seed in comparision with soybean. The cotyledonary cells of lupinseed was in egg-like shape and much (more than 4 times) larger than those of soybean. The microstructure of cotyledonary cells of lupinseed was characterized with thick cell wall having distinct pit-pairs. The protein bodies in lupinseed cotyledon cell contained numerous crystaloids, which was absent in soybean. The middle lamella of soybean cell was partially disintegrated by excessive heat treatment ($120^{\circ}C$, 20 min), whereas those of lupinseed did not change much by heting at $120^{\circ}C$ for 130 min.

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The Relationship Between Hydrogen Trapping Behavior and SSCC Suceptibility of API X60/65 Grade Steels

  • Lee, Jae Myung;Kim, Jin Suk;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • v.2 no.3
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    • pp.109-116
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    • 2003
  • It is well known that SSCC (sulfide stress corrosion cracking) is caused by drastic ingression of hydrogen during the service and accumulation of hydrogen near the potential crack initiation site in the material. It is important to characterize the hydrogen trapping behavior to evaluate the service performance of the high strength pipeline steels. In this study. the relationship between the hydrogen trapping behavior and SSCC susceptibility is evaluated in terms of alloy composition, microstructure and carbide behavior. The hydrogen trapping behavior was measured by electrochemical hydrogen permeation test cell (Devanathan cell). The SSCC susceptibility is evaluated by constant extension rate test and constant strain lest method. The hydrogen trapping behavior is affected greatly by microstructure and nature of carbide particles. The fine TiC, and NbC in the matrix of ferritic structure acts as strong irreversible trap sites whereas the bainitic structure acts as reversible trap site. The SSCC susceptibility is closely related to not only the hydrogen trapping behavior but also the loading condition. As the activity of reversible trap site increases, SSCC susceptibility decreases under static loading condition below yield strength, whereas SSCC susceptibility increases under dynamic loading condition or above yield strength. As the activity of irreversible trap site increases. SSCC susceptibility increases regardless of loading condition. It is cased by the mixed effect of dislocation on hydrogen diffusion and trapping behavior.

Evaluation of Cell-Wall Microstructure and Anti-Swelling Effectiveness of Heat-Treated Larch Wood (낙엽송 열처리재의 세포벽 미세구조 및 항팽윤효율 평가)

  • PARK, Yonggun;JEON, Woo-Seok;YOON, Sae-Min;LEE, Hyun Mi;HWANG, Won-Joung
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.6
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    • pp.780-790
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    • 2020
  • In this study, the cell-wall microstructure and anti-swelling effectiveness (ASE) of heat-treated larch wood were evaluated and the correlation between them was analyzed. For this purpose, some larch lumbers were heat-treated for 12, 18, and 24 hours at temperatures of 190℃ and 220℃. By observing the scanning electron microscopy cross-sectional image of the heat-treated larch, it was confirmed that the shape of heat-treated wood cell changed, the cut-section of the wood cell wall was rough, and the intercellular space has become wide as the intercellular bonds had broken because of heat-treatment. In addition, the evaluation of the swelling for each treatment condition revealed that, as the heat-treatment temperature and duration increased, the amount of absorbed water and swelling decreased and the ASE increased. The decrease in the amount of absorbed water is thought to be affected by the chemical change in the cell wall by heat-treatment. On the contrary, the decrease in the swelling and the increase in the ASE are thought to be due to a combination of chemical changes and physical changes such as structural changes in the cell wall.

Microstructure Observation of the Grain Boundary Phases in ATF UO2 Pellet with Fission Gas Capture-ability (핵분열 기체 포획 기능을 갖는 사고저항성 UO2 펠렛에서 형성되는 입계상의 미세구조 관찰)

  • Jeon, Sang-Chae;Kim, Dong-Joo;Kim, Dong Seok;Kim, Keon Sik;Kim, Jong Hun
    • Journal of Powder Materials
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    • v.27 no.2
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    • pp.119-125
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    • 2020
  • One of the promising candidates for accident-tolerant fuel (ATF), a ceramic microcell fuel, which can be distinguished by an unusual cell-like microstructure (UO2 grain cell surrounded by a doped oxide cell wall), is being developed. This study deals with the microstructural observation of the constituent phases and the wetting behaviors of the cell wall materials in three kinds of ceramic microcell UO2 pellets: Si-Ti-O (STO), Si-Cr-O (SCO), and Al-Si-Ti-O (ASTO). The chemical and physical states of the cell wall materials are estimated by HSC Chemistry and confirmed by experiment to be mixtures of Si-O and Ti-O for the STO; Si-O and Cr-O for SCO; and Si-O, Ti-O, and Al-Si-O for the ASTO. From their morphology at triple junctions, UO2 grains appear to be wet by the Si-O or Al-Si-O rather than other oxides, providing a benefit on the capture-ability of the ceramic microcell cell wall. The wetting behavior can be explained by the relationships between the interface energy and the contact angle.

The Changes of Hardness and Microstructure of Dongchimi according to Different Kinds of Sugar (당의 종류를 달리한 동치미의 경도 변화 및 세포벽 관찰)

  • Ahn, Gee-Jung
    • Culinary science and hospitality research
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    • v.12 no.4 s.31
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    • pp.299-319
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    • 2006
  • The purpose of this study was to investigate the changes of hardness and microstructure of Dongchimi cooked with various sources of sugar(xylitol, xylose, sugar, pear juice). It was fermented at $10^{\circ}C$ for 60 days. The changes of pH in Dongchimi used different kinds of sugar decreased in all samples during the fermentation period, and then showed a slow decrease after 12 days of fermentation. The total acidity of Dongchimi using xylitol arrived slowly at the best tasting condition($0.3\sim0.4$ point) compared with other conditions. The changes of salt content were showed high as compared with other test conditions in 0 day, the day of fermentation. At the early stage of fermentation, the changes of turbidity of Dongchimi using sugar, pear juice were showed high as compared with those of Dongchimi using xylitol, xylose for $5\sim15$ days of fermentation. The maximum cutting force of Chinese radish Dongchimi showed the highest value among al at the 25 th day of ripening and then decreased gradually. The maximum cutting force of Dongchimi using sugar showed the lowest. The calcium and magnesium contents of Dongchimi juice and Chinese radish Dongchimi juice using xylitol were observed high at the early stage of fermentation and showed the highest value during the fermentation period. The microstructure showed disintegration appearance of middle lamella and cell wall during the fermentation period.

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Phase Identification of Nano-Phase Materials using Convergent Beam Electron Diffraction (CBED) Technique

  • Kim, Gyeung-Ho;Ahn, Jae-Pyoung
    • Applied Microscopy
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    • v.36 no.spc1
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    • pp.47-56
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    • 2006
  • Improvements are made to existing primitive cell volume measurement method to provide a real-time analysis capability for the phase analysis of nanocrystalline materials. Simplification is introduced in the primitive cell volume calculation leading to fast and reliable method for nano-phase identification and is applied to the phase analysis of Mo-Si-N nanocoating layer. In addition, comparison is made between real-time and film measurements for their accuracy of calculated primitive cell volume values and factors governing the accuracy of the method are determined. About 5% accuracy in primitive cell determination is obtained from camera length calibration and this technique is used to investigate the cell volume variation in WC-TiC core-shell microstructure. In addition to chemical compositional variation in core-shell type structure, primitive cell volume variation reveals additional information on lattice coherency strain across the interface.

Unit Cell Analysis of Satin Weave Composites Using Macroelements (수자직 복합재료 단위구조의 마크로요소해석)

  • 우경식
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 1997.10a
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    • pp.35-41
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    • 1997
  • Unit cell analyses were peformed to study the engineering properties of satin weave textile composites. Two 5-harness satin weave layers with fiber tow shifts were modeled by unit cells and repeating boundary conditions were applied at the outer surface of the unit cells. Multi-field macroelements were employed to consider the microstructure details and to effectively reduce computer memory requirements. Preliminary results indicated that the engineering properties of 5-harness satin weave textile composites can vary significantly according to the manner how the adjacent fiber tows were arranged in stacking.

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