• 제목/요약/키워드: cationic starch

검색결과 60건 처리시간 0.017초

음이온성 PAM과 양이온성 전분으로 도포된 경질탄산칼슘에 의한 종이 강도 향상 (Paper Strength Improvement by Anionic PAM and Cationic Starch Adsorbed PCC)

  • 최도침;최은연;원종명;조병욱
    • 펄프종이기술
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    • 제45권1호
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    • pp.59-66
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    • 2013
  • Fillers have been used for printing paper to improve printability, sheet formation and optical properties and to reduce production costs by replacing expensive wood pulps. However, an increased filler content will decrease paper strength because filler particles interfere with fiber-fiber bonding. In order to increase filler content without sacrificing too much paper strength in high filler content papers, the surface of precipitated calcium carbonate (PCC) has been modified by adsorbing anionic polyacrylamide and cationic starch in series. The adsorbed polymer layers would enhance interactions between the filler surface and the fiber surface, improving internal bonding. It was found that the modified PCC increased paper strength at a given filler content compared to the coventional method. Negligible differences in optical properties and formation of paper, filler and fines retention and drainage on the wire section were observed between the modified and the conventional PCC. However, the decreased bulk of paper was observed when the modified PCC was used.

탈묵펄프와 열기계펄프에 대한 양성전분 흡착 거동 (Adsorption Behavior of Cationic Starches onto Deinked Pulp and Thermomechnical Pulp)

  • 허동명;이학래
    • 펄프종이기술
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    • 제31권2호
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    • pp.42-49
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    • 1999
  • Although many researches have been made on the adsorption of cationic starches onto chemical pulp fibers, only limited studies have been reported for deinked pulp(DIP) and thermomechanical pulpI(TMP). In this experiment, the adsorption behavior of the cationic starches onto DIP and TMP fibers investigated. Almost complete adsorption of cationic starches onto the pulp fibers were observed when the addition rate of starch was low. Adsorption ratio decreased abruptly when 3.5% and 4.0% of cationic starches were adsorbed onto deinked pulp and thermomechanical pulp, respectively. Adsorption of cationic starches increased as the degree of substitution decreased and as the pH of the pulp slurry increased. TMP fibers adsorbed more cationic starches than DIP because of its greater charge density, and this led to greater improvement in strength properties for the TMP sheets.

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원지특성에 따른 Microflute의 골 성형성(제2보) -Microflute 골 성형성에 영향하는 스트프니스와 섬유간 결합의 중요성 비교 - (Effect of Corrugating Medium's Properties on Microflute Formation (part2) -Relative importance of stiffness and fiber bonding on microflute formation-)

  • 민경은;박종문
    • 펄프종이기술
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    • 제37권2호
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    • pp.64-69
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    • 2005
  • Suitability of corrugating medium for microflute shape formation was analyzed in terms of fiber bonding strength and paper stiffness. Cationic starch and oxidized starch were applied to corrugating medium's surface by bar coater in order to compare the relative importance of stiffness and fiber bonding on microflute formation. It was found that cationic starch was beneficial for better stiffness and oxidized starch was beneficial for better fiber bonding. The results of the decreasing ratio of length by flute formation, the calculated conditioning effect, and the flute height before and after conditioning treatment were obtained. For better microflute shape formation and its preservation it was found that fiber bonding strength should be increased, proper stiffness was required, and resistance to water absorption from surroundings should be increased.

종이의 강도향상을 위한 경질탄산칼슘(PCC) 전처리에 대한 연구 (Improvement of Paper Strength using Pretreated Precipitated Calcium Carbonate (PCC))

  • 김철환;이지영;곽혜정;정호경;백경길;이희진;김성호;강하륜
    • 펄프종이기술
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    • 제42권1호
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    • pp.41-47
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    • 2010
  • Increasing ash content of the paper is one of the most effective methods for saving raw materials and steam consumption and improving optical properties and better print quality. However, the increase of filler loading or filler content using a conventional wet end system is limited due to severe loss in strength properties, affecting runnability and product quality. This is because the filler has no ability to make bonding with cellulosic fibers. Therefore, if the technology to give filler the bonding ability is developed, the ash content of the paper can be increased more than ever. This study was carried out to modify PCC by coating its surface with starch contributing to better bonding with fibers. To prepare the modified PCC, cationic starch was selected as a polymer and then pretreatment was done by mixing PCC and cationic starch. Consequently, the pretreated PCC contributed to higher tensile strength, stiffness and opacity than the conventional filler, such as GCC and untreated PCC. However, CIE whiteness and ISO brightness decreased slightly compared to conventional fillers.

스페이서 사용에 의한 OCC 압착공정의 고형분 증대 (II) (Application of wood flour spacers for increasing OCC solid content in wet pressing process (II))

  • 정재권;지성길;서영범
    • 펄프종이기술
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    • 제47권3호
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    • pp.24-33
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    • 2015
  • Linerboards containing wood flours were developed to increase solid contents in wet pressing process. Presence of wood flours in recycled fibers allowed passage of pressurized water at high wet pressing pressure, and increased solid contents while keeping the bulk of the board. The amount of wood flour addition should be controlled based on the intensity of the wet pressing pressure and the properties of the wood flours. Addition of cationic starch to the wood flour containing OCC furnish showed synergic increase of solid content and strength properties. Shapes of the wood flours such as spherical and rod type added to OCC furnish affected largely their solid content, drainage, and board physical properties.

고농도 지료에서의 PCC 충전이 종이 물성에 미치는 영향 (Effects of PCC Loading at Thick Stock on the Paper Properties)

  • 원종명;조병욱;이용규
    • 펄프종이기술
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    • 제44권4호
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    • pp.62-68
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    • 2012
  • This study was carried out to evaluate the effect of PCC loading at thick stock on the physical properties of paper. The effect of starch addition(2, 4 and 6%) and mixing time(5, 10 and 20 min.) on the filler retention and paper properties were investigated. Optimum dosage of cationic starch as a fixing agent was 4%, and mixing time did not showed any significant effect on the filler retention. PCC loading at thick stock was more effective to improve bulk and opacity than PCC loading at thin stock, although their improvement was not so significant. It was also found that the strength properties could be improved by the loading at thick stock. PCC loading method at thick stock could be considered as one of potential approaches for further improving of paper properties, although further research works are required in order to apply the PCC loading at thick stock in the paper mill.

양이온성 계면활성제 거품 지속성 증진방법 연구 (Enhancement in Stability of Foam Generated with Cationic Surfactant Solutions)

  • 김홍열;정승우
    • 대한환경공학회지
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    • 제34권11호
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    • pp.735-742
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    • 2012
  • 계면활성제 거품(foam)을 아예 형성하지 못하거나 foam 지속도가 매우 낮은 양이온성 계면활성제의 foam 지속성을 높이는 방법에 대해 연구하였다. 음이온성 계면활성제를 보조제로 첨가하는 방법, 콜로이드를 혼합하는 방법, 수용성 수지인 폴리비닐알콜을 첨가하는 방법 등 다양한 시도를 평가하였다. 각 5% 양이온성 계면활성제 용액의 foam 지속도를 평가한 결과, Cationic starch (CA-ST)는 foam이 전혀 발생되지 않았지만, Methyl triethanol ammonium methyl sulfate distearyl ester (CEQ90)의 foam 지속시간은 평균 46초, Cetyl trimethyl ammonium chloride (CM29)는 평균 31초로서 매우 낮았다. 음이온성 계면활성제 Sodium dodecyl sulfate (SDS) 첨가는 양이온성 계면활성제의 종류에 따라 지속도가 매우 다르게 나타났다. Cationic starch (CA-ST)의 foam 지속도는 매우 크게 증가된 반면 CEQ90와 CM29는 오히려 감소되었다. 콜로이드($SiO_2$, kaolin) 혼합이 양이온성 계면활성제 foam 지속도에 미치는 영향을 평가한 결과, CA-ST는 콜로이드 혼합시 foam이 전혀 발생되지 않았고, CEQ90과 CM29는 콜로이드를 주입하였을 경우 주입을 하지 않았을 때보다 지속도가 높아졌다. 수용성수지인 polyvinyl alcohol (PVA)첨가가 양이온성 계면활성제 foam 지속도에 미치는 영향을 평가한 결과, CA-ST는 PVA혼합에서도 foam이 전혀 발생 되지 않았지만, CEQ90과 CM29는 PVA의 농도가 높을수록 foam 지속도가 증가하였다. 양이온성 계면활성제에 음이온성 계면활성제 SDS와 콜로이드를 동시에 첨가한 결과 콜로이드보다 음이온성 계면활성제에 의해 양이온성 계면활성제 foam 지속도가 결정되었다. 음이온성 계면활성제 SDS와 PVA를 동시에 첨가하여 평가한 결과 PVA보다 역시 음이온성 계면활성제에 의해 양이온성 계면활성제의 foam 지속도가 결정되었다. Foam을 전혀 형성하지 못했던 양이온성 계면활성제인 CA-ST는 음이온성 계면활성제 SDS 0.14%, PVA 2.5% 첨가 조건에서 foam 지속시간이 평균 8,780초로 획기적으로 증가하였고 타 양이온성 계면활성제 CEQ90 보다 약 8배 이상의 지속시간을 보여주었다. 본 연구결과 foam이 형성되지 않거나 지속시간이 매우 짧은 양이온성 계면활성제는 음이온성 계면활성제를 첨가할 경우 foam형성에 도움을 받을 수 있고 colloid 및 PVA 등의 보조를 통해 양이온성 계면활성제의 지속도를 혁신적으로 증가시킬 수 있는 것으로 확인되었다. 그리고 양이온 계면활성제의 foam 지속도는 음이온성 계면활성제의 첨가농도에 의해 가장 큰 영향을 받는 것으로 보인다.

건조수축 해석을 통한 종이의 벌크 및 강직성 향상 (Improvement of Paper Bulk and Stiffness by Using Drying Shrinkage Analysis)

  • 이진호;박종문
    • 펄프종이기술
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    • 제43권4호
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    • pp.49-58
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    • 2011
  • The maximum drying shrinkage velocity was proposed to verify bulk and stiffness improvement mechanism during drying according to papermaking parameters. It was based on the wet-web shrinkage behavior without the restraint of wet-web during drying, so intact drying impact could be measured. Bulking agent reduced the drying shrinkage and the maximum drying shrinkage velocity, so paper bulk increased and paper strength decreased. When adding cationic starch to stock with the bulking agent for strengthening, the bulk was increased further with additional decreasing of the drying shrinkage and the maximum drying shrinkage velocity. Paper strength also increased except tensile stiffness index with decreasing the drying shrinkage and the maximum drying shrinkage velocity. When using additional strength additives for strengthening of fiber interfaces extended by bulking agent and cationic starch, amphoteric strength additive increased paper stiffness without loss of paper bulk. It was considered that the added amphoteric strength additives were cross-linked to the stretched cationic starch and this cross-linking increased elasticity of fiber-polymer-fiber interfaces without changing the drying behavior. Paper bulk could be increased with decreasing the maximum drying shrinkage velocity. The drying shrinkage of paper also could be controlled by fiber-to-fiber bonding interfaces by the bulking agent. In this case, paper strength including stiffness was decreased by reducing fiber-to-fiber bonding but it could be improved by strengthening fiber-to-fiber interfaces with polymer complex without loss of bulk.

Influence of Several Physicochemical Conditions on the Flocculation of Micro Stickies

  • Kim, Jong-Min;Lee, Hak-Lae
    • 펄프종이기술
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    • 제40권5호
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    • pp.20-26
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    • 2008
  • Behavior of micro stickies was analyzed using model micro stickies prepared with PVAc emulsion adhesive. Flocculation of micro stickies increased with temperature. Acidic state also induced greater flocculation of micro stickies since they became more unstable under these conditions. Flocculation of micro stickies increased as calcium ion concentration increased. But the presence of calcium carbonates made micro stickies dispersed indicating that calcium carbonates cause two different effects on the behavior of micro stickies. Talc increased flocculation of micro stickies because of its hydrophobic nature. Cationic polymer increased flocculation of micro stickies. Especially cationic starch has far greater effect in flocculating sticky particles by forming bridging flocculations.