• Journal of Sericultural and Entomological Science
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• v.37 no.2
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• pp.154-160
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• 1995

Dyeing behavior of Silk/Cationic dyeable polyester(CDP) mixed filament was investigated by using a cationic dye. The effect of pH, temperature and additives such as carrier, levelling agent and salt were examined for each silk and CDP component of mixed filament in order to find out the optimum dyeing condition. Based on these results, the dyeing behavior was investigated for Silk/CDP mixed filaments concering various dyeing parameters. The dye adsorption was significantly changed on the dyeing temperature, carrier addition and pH of the dyebath. Specially, the dye migration phynomena were observed for a mixed filament, showing that the dyes initially observed on the surface of silk fiber migrate to the CDP component during a dyeing process. The dyeing of Silk/CDP mixed filaments accompanied by dye migration and as a result, dye adsorption can be developed only for a CDP component. Therefore, the control of dyeing temperature is most important for a Silk/CDP mixed filament, in order that both silk and CDP component are able to be dyed by a cationic dye simultaneously in one bath/one dye system.

• Textile Coloration and Finishing
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• v.17 no.3 s.82
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• pp.1-7
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• 2005

Cationic dyeable polyester(CDP) was produced through melt blending of cationic chips having $2mol\%$ of sodium salt of dimethyl ester of 5-sulfoisophthalic acid(DMS salt) and normal polyester chips in different proportions to obtain yarns having varying amount of comonomer in the fiber. The modified polyesters showed increased moisture regain, decreased viscosity, lower softening point and improved antistatic characteristics, according to the amount of modifier. In dyeing at $100^{\circ}C$ the dyeing rate of cationic dyes with CDP fiber increased slowly than that of disperse dyes. In dyeing at $120^{\circ}C$ cationic dyes reached to equilibrium at 30min and disperse dyes at 10min. Cationic dyes in dyeing of CDP fabric have a better wash fastness compared with disperse dyes, also rubbing fastness of cationic dyes is better than that of disperse dyes. The light fastness of CDP fabric for cationic and disperse dyes is not good. The fastness of 75d/36f CDP fabric is higher than 75d/72f fabric. Solvent wicking fastness of CDP with cationic dyes is better than that of disperse dyes.

• Textile Coloration and Finishing
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• v.17 no.5 s.84
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• pp.1-12
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• 2005

Polyester fibers can be modified into cationic dyeable polyester fibers(CDP) by the copolymerization of terephthalic acid and 5-sodium sulphoisophthalic acid with ethylene glycol. The advantage of CDP on most cationic dyes is the conspicuous brilliance due to a narrow steep absorption band and the wash fastness and etc. Weight reduction by alkali hydrolysis, dyeing and solvent wicking properties of fabrics with cationic dyes, and change of fine structure were investigated. To obtain optimum splitting process parameters for dyeing and physical properties of micro CDP fiber, splitting method under various conditions was carried out. By means of SEM, it was confirmed that the splitting process of the micro CDP fiber be achieved at the weight reduction. A comparatively greater quantity of dye is necessary to dye microfiber than conventional fiber. The fastness and solvent wicking of regular CDP fiber is higher than that of micro CDP fiber.

• Textile Coloration and Finishing
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• v.17 no.3 s.82
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• pp.8-15
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• 2005

Cationic dyeable polyester(CDP) fabric was annealed at varying temperatures range from $120^{\circ}C$ to $220^{\circ}C$ for 1, 3, and 5 min under tension. Dyeing rates of CDP fabrics were measured with cationic and disperse dyes at $100^{\circ}C$ and $120^{\circ}C$ in water system. Also X-ray diffraction pattern, DSC thermograms and dyeability of fabric with cationic and disperse dyes were investigated. The intensities of X-ray diffraction peaks of annealed fabric were increased with increasing in annealed temperature, and peak became sharp with heat setting temperature. The apparent color depth (K/S) of CDP fabric initially decreased with increase of heat-setting temperature up to $160\~180^{\circ}C$ and then increased at higher temperature. The shearing modulus(G) and surface roughness were increased with annealing temperature.

• Textile Coloration and Finishing
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• v.26 no.2
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• pp.79-87
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• 2014

Dyeing fabric weaved with two or more kinds of fiber in different section has various dyeing interactions caused by different material properties of them. Newly developed knit fabric was used in this study. It composited by two different blocks, each block is included PET fiber and CDP fiber separately. Build-up properties with cation dyes and disperse dyes were good having average 83% of dyeing exhaustion yield on 5% o.w.f. dye concentration. As depending on dyeing methods, there were not showed direct interaction between cation dyes and disperse dyes. This result could be considered their different dyeing mechanism. Compatibility was best in S-type disperse dyes investigated their critical absorption range as $120^{\circ}C{\sim}130^{\circ}C$. Wash fastness was generally good in most dye.