• Title/Summary/Keyword: carrier gas

Search Result 629, Processing Time 0.025 seconds

Formation of Ultra fine Particle by the Polonium-218 Ions under Different Humidity Conditions (다른 습도조건하에서 Po-218 이온들의 극소입자형성에 관한 연구)

  • Yoon, Suk-Chul;Ha, Chung-Woo
    • Journal of Radiation Protection and Research
    • /
    • v.17 no.1
    • /
    • pp.1-10
    • /
    • 1992
  • A number of investigators have reported the formation of the radiolytic ultrafine particles produced by the interaction of ionizing radiation with water vapor. Previous studies have suggested that a very high localized concentration of the OH radical produced by the radiolysis of water can react with trace gas like organic vapors and produce lower vapor pressure compounds that can then nucleate. In order to determine water vapor dependence of the active, positively charged, first radon daughter(Po-218), an experiment was conducted using a well-controlled radon chamber. The activity size distribution of the radon daughter in the range of 0.5-100nm was measured using the parallel graded wire screens system. Measurements were taken for different relative humidity. The resultant activity size distributions were analyzed. The addition of water vapor to the radon carrier gases resulted in the formation of ultrafine particles by OH radicals formed by radon radiolysis. It may be due to the neutralization of charged Po-218 ion with water vapor through the radio lysis.

  • PDF

Mechanical and Thermal Characteristics of Polyurethane Foam with Two Different Reinforcements and the Effects of Ultrasonic Dispersion in Manufacturing (이종 강화재를 첨가한 폴리우레탄 폼의 기계적 및 열적 특성과 제작 시 초음파 분산의 영향)

  • Kim, Jin-Yeon;Kim, Jeong-Dae;Lee, Jae-Myung
    • Journal of the Society of Naval Architects of Korea
    • /
    • v.56 no.6
    • /
    • pp.515-522
    • /
    • 2019
  • Since Liquefied Natural Gas (LNG) is normally carried at 1.1 bar pressure and at -163℃, special Cargo Containment System (CCS) are used. As LNG carrier is becoming larger, typical LNG insulation systems adopt a method to increase the thickness of insulation panel to reduce sloshing load and Boil-off Rate (BOR). However, this will decrease LNG cargo volume and increase insulation material costs. In this paper, silica aerogel, glass bubble were synthesized in polyurethane foam to increase volumetric efficiency by improving mechanical and thermal performance of insulation. In order to increase dispersibility of particles, ultrasonic dispersion was used. Dynamic impact test, quasi-static compression test at room temperature (20℃) and cryogenic temperature (-163℃) was evaluated. To evaluate the thermal performance, the thermal conductivity at room temperature (20℃) was measured. As a result, specimens without ultrasonic dispersion have a little effect on strength under the compressive load, although they show high mechanical performance under the impact load. In contrast, specimens with ultrasonic dispersion have significantly increased impact strength and compressive strength. Recently, as the density of Polyurethane foam (PUF) has been increasing, these results can be a method for improving the mechanical and thermal performance of insulation panel.

Characterization of Alpha-Ga2O3 Template Grown by Halide Vapor Phase Epitaxy (HVPE 방법으로 성장한 Alpha-Ga2O3의 특성 분석)

  • Son, Hoki;Ra, Yong-Ho;Lee, Young-Jin;Lee, Mi-Jai;Kim, Jin-Ho;Hwang, Jonghee;Kim, Sun Woog;Lim, Tae-Young;Jeon, Dae-Woo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.31 no.6
    • /
    • pp.357-361
    • /
    • 2018
  • We demonstrated a crack-free ${\alpha}-Ga_2O_3$ on sapphire substrate by horizontal halide vapor phase epitaxy (HVPE). Oxygen-and gallium chloride-synthesized Ga metal and HCl were used as the precursors, and $N_2$ was used as the carrier gas. The HCl flow and growth temperature were controlled in the ranges of 10~30 sccm and $450{\sim}490^{\circ}C$, respectively. The surface of ${\alpha}-Ga_2O_3$ template grown at $470^{\circ}C$ was flat and the root-mean-square (RMS) roughness was ~2 nm. The full width at half maximum (FWHM) values for the symmetric-plane diffractions, were as small as 50 arcsec and those for the asymmetric-plane diffractions were as high as 1,800 arcsec. The crystal quality of ${\alpha}-Ga_2O_3$ on sapphire can be controlled by varying the HCl flow rate and growth temperature.

Development of a University-Based Simplified H2O2/PE Hybrid Sounding Rocket at KAIST

  • Huh, Jeongmoo;Ahn, Byeonguk;Kim, Youngil;Song, Hyunki;Yoon, Hosung;Kwon, Sejin
    • International Journal of Aeronautical and Space Sciences
    • /
    • v.18 no.3
    • /
    • pp.512-521
    • /
    • 2017
  • This paper reports development process of a university-based sounding rocket using simplified hybrid rocket propulsion system for low-altitude flight application. A hybrid propulsion system was tried to be designed with as few components as possible for more economical, simpler and safer propulsion system, which is essential for the small scale sounding rocket operation as a CanSat carrier. Using blow-down feeding system and catalytic ignition as combustion starter, 250 N class hybrid rocket system was composed of three components: a composite tank, valves, and a thruster. With a composite tank filled with both hydrogen peroxide($H_2O_2$) as an oxidizer and nitrogen gas($N_2$) as a pressurant, the feeding pressure was operated in blowdown mode during thruster operation. The $MnO_2/Al_2O_3$ catalyst was fabricated for propellant decomposition, and ground test of propulsion system showed the almost theoretical temperature of decomposed $H_2O_2$ at the catalyst reactor, indicating sufficient catalyst efficiency for propellant decomposition. Auto-ignition of the high density polyethylene(HDPE) fuel grain successfully occurred by the decomposed $H_2O_2$ product without additional installation of any ignition devices. Performance test result was well matched with numerical internal ballistics conducted prior to the experimental propulsion system ground test. A sounding rocket using the developed hybrid rocket was designed, fabricated, flight simulated and launch tested. Six degree-of-freedom trajectory estimation code was developed and the comparison result between expected and experimental trajectory validated the accuracy of the developed trajectory estimation code. The fabricated sounding rocket was successfully launched showing the effectiveness of the simplified hybrid rocket propulsion system.

Properies of ZrO2 thin films by Atomic Layer Deposition with Carrier Gas Assistant System (수송가스 도움 전구체 공급 장치를 이용한 ZrO2 박막의 원자층 증착 기술)

  • Shin, Woong-Chul;Ryu, Sang-Ouk;Seong, Nak-Jin;Yoon, Soon-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.11a
    • /
    • pp.342-342
    • /
    • 2007
  • 원자층 증착(Atomic Layer Deposition: ALD) 방법은 반응물질들을 펄스형태로 챔버에 공급하여 기판 표면에 반응물질의 표면 포화반응에 의한 화학적 흡착과 탈착을 이용한 박막증착기술이다. ALD법은 박막의 조성 정밀제어가 쉽고, 파티클 발생이 없으며, 대면적의 박막 증착시 균일성이 우수하고, 박막 두께의 정밀 조절이 용이한 장점이 있다. 원자층 증착 공정에서 짧은 시간 안에 소스를 충분히 공급하기 위한 방법으로는 소스 온도를 증가시켜 전구체의 증기압을 높여 반응기로의 유입량을 증가시키는 방법, 전구체의 공급시간을 늘리는 방법 등을 들 수 있다. 그러나 전구체 온도를 상승시키는 경우, 공정 조건의 변화가 요구되며 전구체의 변질에 의하여 형성된 막이 의도하는 막 특성을 만족시키지 못하게 되는 문제점이 발생될 우려가 있다. 그리고 전구체를 충분히 공급하기 위하여 전구체의 공급시간을 늘이는 방법을 사용하면, 원하는 두께의 막을 형성하기 위하여 소요되는 공정시간이 증가된다. 이를 해결하기 위해 수송가스를 이용한 버블러 형태의 전구체 공급 장치를 사용하지만 이 또한 전구체의 수명을 단축시키는 단점을 가지고 있다. 본 논문에서는 위의 문제점을 극복할 수 있는 새로운 개념의 수송가스 도움 전구체 공급 장치를 소개한다. 본 연구에서 사용된 수송가스 도움 전구체 공급 장치를 가지는 ALD 장비는 Lucida-D200 (NCD Technology사)이며 기판으로는 8인치 실리콘 웨이퍼를 사용하였으며 (TEMA)Zr을 사용하여 ZrO2 박막을 성장하였다. 수송가스 도움 전구체 공급 장치를 사용한 경우, 그렇지 않은 경우 보다 $30^{\circ}C$ 이상 전구체 온도를 낮출 수 있으며, 또한 증착 속도를 약 2배정도 증가시킬 수 있었다. 이들 박막들은 XRD, XPS, AFM 등을 이용하여 결정구조, 결합에너지, 표면 거칠기 등의 특성을 관찰하였다. 그리고 C-V, I-V 측정을 이용해 정전용량, 유전율, 누설전류 등의 전기적 특성을 평가하였다.

  • PDF

Effect of Al2O3 Surface Passivation by Thermal Oxidation of Aluminum for AlGaN/GaN Structure (Al의 열산화 방법을 이용한 AlGaN/GaN 구조의 표면 Al2O3 패시베이션 효과)

  • Kim, Jeong-Jin;Ahn, Ho-Kyun;Bae, Seong-Bum;Pak, Young-Rak;Lim, Jong-Won;Moon, Jae-Kyung;Ko, Sang-Chun;Shim, Kyu-Hwan;Yang, Jeon-Wook
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.25 no.11
    • /
    • pp.862-866
    • /
    • 2012
  • Surface passivation of AlGaN/GaN heterojunction structure was examined through the thermal oxidation of evaporated Al. The Al-oxide passivation increased channel conductance of two dimensional electron gas (2DEG) on the AlGaN/GaN interface. The sheet resistance of 463 ohm/${\Box}$ for 2DEG channel before $Al_2O_3$ passivation was decreased to 417 ohm/${\Box}$ after passivation. The oxidation of Al induces tensile stress to the AlGaN/GaN structure and the stress seemed to enhance the sheet carrier density of the 2DEG channel. In addition, the $Al_2O_3$ films formed by thermal oxidation of Al suppressed thermal deterioration by the high temperature annealing.

Study on Basic Properties of Single Crystalline ZnO Nanowire (단결정 산화아연 나노선의 기초 물성 연구)

  • Ra, H.W.;Khan, R.;Kim, J.T.;Yeo, C.H.;Im, Y.H.
    • Journal of the Korean Vacuum Society
    • /
    • v.18 no.4
    • /
    • pp.259-265
    • /
    • 2009
  • We fabricated the field effect transistor using single crystalline ZnO nanowires synthesized by a conventional thermal evaporation method and investigated their basic properties under the various conditions such as ultraviolet irradiation, reducing gas and electrolyte. The typical carrier concentration and mobility of the single crystalline ZnO nanowire with a diameter of 100 nm and length of 5 um were $1.30{\times}10^{18}cm^{-3}$ and $15.6cm^2V^{-1}s^{-1}$, respectively. The current of ZnO nanowire under ultraviolet irradiation significantly increased about 400 times higher as compared to in the darkness. In addition, the ZnO nanowire showed typical sensing characteristics for $H_2$ and CO due to well-known surface reactions and typical current-voltage characteristics under the 0.1 M NaCl electrolyte.

Chemical Doping of $TiO_2$ with Nitrogen and Fluorine and Its Support Effect on Catalytic Activity of CO Oxidation

  • Chakravarthy, G. Kalyan;Kim, Sunmi;Kim, Sang Hoon;Park, Jeong Young
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.08a
    • /
    • pp.142.2-142.2
    • /
    • 2013
  • The effect of substrate on catalytic activity of CO oxidation with transition metal Platinum nanoparticles on doped and undoped TiO2 was investigated. Titanium dioxide was doped chemically with non-metal anions including nitrogen and fluorine. Undoped TiO2 was synthesized via simple conventional sol-gel route. Thin films of titania were developed by spin coating technique and the characterization techniques SEM, XRD, UV-Vis Absorption Spectroscopy and XPS were carried out to examine the morphology of films, crystal phase, crystallites, optical properties and elemental composition respectively. XPS analysis from doped TiO2 confirmed that the nitrogen site were interstitial whereas fluorine was doped into TiO2 lattice substitutionally. Catalytic activity systems of Pt/doped-TiO2 and Pt/undoped-TiO2 were fabricated to reveal the strong metal-support interaction effect during catalytic activity of CO oxidation reactions. By arc plasma deposition technique, platinum nanoparticles with mean size of 2.7 nm were deposited on the thin films of doped and undoped titanium dioxide. The CO oxidation was performed with 40 Torr CO and 100 Torr O2 with 620 Torr He carrier gas. Turn over frequency was observed two to three folds enhancement in case of Pt/doped TiO2 as compared to Pt/TiO2. The electronic excitation and the oxygen vacancies that were formed with the doping process were the plausible reasons for the enhancement of catalytic activity.

  • PDF

Visualization of the Combustion-field in Ultrasonically-atomized Slit-jet Flame Using a Thermo-graphic Camera (열화상카메라를 이용한 초음파 무화 슬릿제트화염의 연소장 가시화)

  • Kim, Min Sung;Koo, Jaye;Kim, Heuy Dong;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.20 no.4
    • /
    • pp.1-8
    • /
    • 2016
  • An experimental study was performed for the combustion-field visualization of the burner which burns the liquid hydrocarbon fuel atomized by an ultrasonic oscillator. Configurations of the flame and combustion-field were caught by both high-speed camera and thermo-graphic camera, and those images were analyzed in detail through a post-processing. As a result, the combustion-field grew and reaction-temperature rose due to the strengthening of combustion reaction with the increasing flow-rate of carrier-gas. In addition, a phenomenon of flame flickering was discussed through the comparative analysis of the variational behaviors between the visible flame and IR (Infrared) flame-field.

Object Detection and Post-processing of LNGC CCS Scaffolding System using 3D Point Cloud Based on Deep Learning (딥러닝 기반 LNGC 화물창 스캐닝 점군 데이터의 비계 시스템 객체 탐지 및 후처리)

  • Lee, Dong-Kun;Ji, Seung-Hwan;Park, Bon-Yeong
    • Journal of the Society of Naval Architects of Korea
    • /
    • v.58 no.5
    • /
    • pp.303-313
    • /
    • 2021
  • Recently, quality control of the Liquefied Natural Gas Carrier (LNGC) cargo hold and block-erection interference areas using 3D scanners have been performed, focusing on large shipyards and the international association of classification societies. In this study, as a part of the research on LNGC cargo hold quality management advancement, a study on deep-learning-based scaffolding system 3D point cloud object detection and post-processing were conducted using a LNGC cargo hold 3D point cloud. The scaffolding system point cloud object detection is based on the PointNet deep learning architecture that detects objects using point clouds, achieving 70% prediction accuracy. In addition, the possibility of improving the accuracy of object detection through parameter adjustment is confirmed, and the standard of Intersection over Union (IoU), an index for determining whether the object is the same, is achieved. To avoid the manual post-processing work, the object detection architecture allows automatic task performance and can achieve stable prediction accuracy through supplementation and improvement of learning data. In the future, an improved study will be conducted on not only the flat surface of the LNGC cargo hold but also complex systems such as curved surfaces, and the results are expected to be applicable in process progress automation rate monitoring and ship quality control.