• 자원환경지질
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• 제1권1호
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• pp.9-34
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• 1968

Manganese ore deposits of the Samhan Changgun Properties are located at the valley of west-lope-side of Changgun-bong (1132m) occupied over the Myon border between Sochon-myon and Jaesan-myon Pongwha-gun, Kyongsang-Pukdo. Geology of the more property and it's vicinity consists of Wonnan formation and Yulri formation of pre-Cambrain and Changgun limestone formation, Mica-schist formation, quartizite formation and Jaesan formation (containing coal bearing zone the unknown age. And granites and dykes were intruded into the above formation later. 1. Management deposits is embedded the formation of Janggun limestone especially Contact zone in the contact zone to of Chunyang Granite limestone enclosed by Granite, and Maginal zone of fault line in the limestone. Therefore, Chunyang Granite is Closely related to ore deposit. Pegmatite which is near by ore deposit was intruded before mineralization and it seems to be a channelway of ore solution. The most important ore deposits of property grouped into south deposit, east deposit, east-Gachon deposit, South-Gachon deposit, Durimgok deposit and West deposit, out-crops at several place. Besides these deposits there also are several prospects on outcrop scathered. Hydrothermal alteration take place strongly in the well rock and it's sequence are Characterized as following; 1) Dolomitization 2) Carbonization 3) Mamgamotozation 4) Pyritization 5) Silicification 6) Oxidation 2. The grade of manganese dioxide is up to Mn 45% in Maximum, but generally, averaging Mn 30~35% of high grade ore and averaging Mn 30~32% of manganese carbonates are mined in his property.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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• pp.334-337
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• 2004

Groundwater chemistry in Namwon area, Korea, was investigated to understand the contribution of geochemical processes on groundwater chemistry. For this study, a total of 279 groundwater samples were collected from 93 wells distributed over the study area. Higher concentrations of major ions are generally encountered in the shallow alluvial wells, suggesting that these chemicals are originated from the surface contamination sources. Mass balance analysis based on reaction stoichiometry reveals that the water chemistry is regulated by three major chemical processes: weathering of silicate/ carbonate minerals, input of C1/SO$_4$ salts, and nitrate generating processes. The results show that mineral weathering is the most dominating factor regulating the groundwater chemistry. However, the groundwaters with the higher salt concentration indicate the larger mineral weathering effect, suggesting that some part of the mineral weathering effect is also associated with the anthropogenic activities such as limes applied to the cultivated lands, carbonates (CaCO$_3$) in the cement materials.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2004년도 임시총회 및 추계학술발표회
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• pp.219-222
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• 2004

Removal characteristics of Mn and Co was studied from the contaminated solutions via surface reaction with various calcium carbonate (calcite). Synthetic calcium carbonates which has different surface morphology as well as surface areas were prepared by a spontaneous precipitation method and used. Mn and Co removal behavior by the different solid surface demonstrate characteristic sorption behaviors depend on the type of calcite used, such as surface area or surface morphology. Calcium carbonate crystals (mostly calcite) which exhibit complicated surface morphology (c-type) shows strong sorption affinity for Mn and Co removal via sorption than on the a-type or b-type calcite crystals of less complicated surfaces. The applicability of two kinetic models, the pseudo-first-order kinetic equation and the Elovich kinetic model was examined on these sorption behavior. Elovich kinetic model was found more suitable to explain the very early stage adsorption kinetics, while the pseudo-first-order kinetic equation was successfully fitted for the adsorption kinetics after 50 hours.

• 분석과학
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• 제13권2호
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• pp.215-221
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• 2000

생활폐기물 소각처리시설에서 발생하는 비산재의 pH와 입자분포 상태 등 물성치를 측정하였으며, XRF와 ICP-AES 및 ICP-MS를 이용하여 성분원소를 분석하였다. XRF 분석결과 비산재의 주성분 원소는 Ca, K, Na, Si, Al, Cl, S 및 O로 확인되었으며, XRD 분석결과 이들 원소는 염화물과 수산화물, carbonate, 산화물 및 복합화합물의 형태로 존재하는 것으로 나타났다. 미량원소로 함유된 중금속류의 정량을 위하여 시료의 전처리 없이 XRF를 이용한 직접분석과 마이크로파 분해장치를 사용하여 시료를 분해시킨 뒤 ICP-AES 및 ICP-MS를 이용한 분석결과를 비교하여 보았는데 두 가지 분석방법의 곁과가 잘 일치하였으며, Zn, Pb, Cu, Cr, Cd의 순으로 함량이 높게 나타났다.

• 펄프종이기술
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• 제44권1호
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• pp.16-23
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• 2012

Use of security papers for monetary papers, gift certificates, and lottery tickets increases every year. As the use of security papers increase, there are more possibility of counterfeits. In this study, we used unique fibers from the sea to increase the difficulties against counterfeiting. The red algae fibers give opacity as much as calcium carbonates, and have unique shape in length ($500{\sim}900\;{\mu}m$) and width ($1{\sim}4\;{\mu}m$) to be discerned from other natural fibers such as wood and cotton fibers. We mixed red algae fibers to wood fibers in a series of fixed ratios to make single and multiply papers for making security papers. Paper with dyed red algae fibers were also used. Paper made without fillers gave enough opacity for printing when red algae fibers were used more than 20% of the fiber furnish. Those properties may allow red algae fibers to be a potential candidate for fiber raw materials of security paper.

• 한국동물위생학회지
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• 제26권2호
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• pp.145-149
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• 2003

To explore the most sensitive and useful method for simultaneous determination of 8 carbamate pesticides in livestock productions, the mixture of 8 carbonates was determined by HPLC with scanning fluorescence detector. For mobile phase water, acetonitrile and methanol program gradient showed more applicable sensitivity than water and acetonitrile program gradient used ExW 339 nm and EmW 445 nm for fluorescence detector. On using carbamate columns, the retention time was within 4 to 20 minutes. And this made it possible to separate and detect simultaneously. therefore we could analyze it exactly and efficiently and reduce time. The preparation process of MSPD method showed that the high recovery rate was more than 88.5% in most of the carbamate pesticides. Therefore we could say that it was an efficient and fast method analyzing out of lots of samples.

• 한국물환경학회지
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• 제30권1호
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• pp.25-30
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• 2014

This study is done to prove the premise that both alkalinity and hardness affect on the dissolved phosphorus concentration so that the growth of algae is also affected in water bodies like rivers and lakes. Statistical analysis of the water quality data of 13 reservoirs collected for the last decade shows the relations between alkalinity and chlorophyll-${\alpha}$ and between hardness and chlorophyll-${\alpha}$ are not linear but follow second order equation. This relation seems to be due to two antagonistic effects accompanying a simultaneous increase in alkalinity and hardness. The increase stimulates the growth of algae by supplying carbonates and $Ca^{2+}$ to algae and at same time it causes a decrease in soluble phosphorus which retards algae to grow. These opposing tendencies are confirmed by theoretical calculations with the MINTEQ model. There seems to be ranges of alkalinity and hardness that are in favor of algae growth; the ranges are less than 44 mg/L as $CaCO_3$ in alkalinity and also less than 63 mg/L as $CaCO_3$ in hardness. This finding will provide a solid base to develop an effective water quality management of water bodies.

• 한국해양학회지:바다
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• 제4권1호
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• pp.25-32
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• 1999

발전소 가동에 따른 퇴적물내 중금속원소의 오염 가능성을 알아보기 위하여 삼천포화력발전소와 영광원자력 발전소 주변해역의 표층퇴적물을 대상으로 중금속 함량 분석을 실시하였으며 선정된 일부 퇴적물에 대해서는 화학적 존재형태를 파악하기 위해 연속추출분석을 실시하였다. 퇴적불 중의 금속원소 함량 분포는 대체적으로 평균입도에 의해 조절되고 있으며 탄산염 함량 및 유기불 함량에 의해서도 영향을 받고 있는 것으로 나타났다. 또한 화학적 존재형태별 분석에서도 Mn을 제외한 대부분의 중금속이 잔류상으로 존재하고 있어 인위적인 오염에 의해서라기 보다는 자연적인 분산에 의해 존재하고 있는 것으로 나타났다.

• 한국분말재료학회지
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• 제14권2호
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• pp.145-149
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• 2007

Nanocrystalline transient aluminas (${\gamma}$-alumina) were coated on core particles (${\gamma}$-alumina) by a carbonate precipitation and thermal-assisted combustion, which is environmentally friend. The ammonium aluminum carbonate hydroxide (AACH) as a precursor for coating of transient aluminas was produced from precipitation reaction of ammonium aluminum sulfate and ammonium hydrogen carbonate. The crystalline size and morphology of the synthetic, AACH, were greatly dependent on pH and temperature. AACH with a size of 5 nm was coated on the core alumina particle at pH 9. whereas rod shape and large agglomerates were coated at pH 8 and 11, respectively. The AACH was tightly bonded coated on the core particle due to formation of surface complexes by the adsorption of carbonates, hydroxyl and ammonia groups on the surface of the core alumina powder. The synthetic precursor successfully converted to amorphous- and ${\gamma}$-alumina phase at low temperature through decomposition of surface complexes and thermal-assisted phase transformation.

• 자원환경지질
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• 제20권2호
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• pp.107-118
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• 1987

The south ore deposits of the Dunjeon gold mine is a fissure-filling vein emplaced in the granitoids, skarnized and hornfelsified rocks of Ordovician Dumudong formation. The vein mineral paragenesis is complicated by repeated fracturing but three distinct depositional stages can be recognized; (1) base metal sulfides stage, (2) base metal sulfides, antimony-bismuthsulfosalts and native metals stage, (3) barren carbonates stage. Gold was mainly deposited in stage II. Fluid inclusion data indicate that fluid temperatures were from $310^{\circ}C$ to $402^{\circ}C$ during stage I and then declined steadily to $148^{\circ}C$ in the closing late stage III. Salinities were in the range of 0.4 to 5.0 equivalent weight percent NaCl and do not reveals any systematic trend through stag I, II and III. Ore mineralogy suggests that temperatures and sulfur fugacities in the earlier stage II were in the range of $340^{\circ}C$ to $360^{\circ}C$, $10^{-8}$ to $10^{-9}$ atm. respectively and then declined steadily to the range of $185^{\circ}C$ to $200^{\circ}C$ and $10^{-17}$ to $10^{-19}$atm. in the later stage II.