• Title/Summary/Keyword: carbonate water

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Compositional and Morphological Analyses of Black Precipitate Formed on the Surface of Heating Appliance (수돗물 가열시 형성되는 흑색 침전물의 성분 분석)

  • Baek, Mi-Hwa;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.184-187
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    • 2007
  • The compositional and morphological analyses have been carried out by employing XRD, EPMA, and SEM for the black-colored precipitate which is formed on the surface of heating appliances by heating tap water. XRD analysis has showed that the precipitate was mainly composed of calcium carbonate with a crystal structure of calcite. Also, small amounts of precipitate by SEM showed that the microscopic shape of the precipitate was usually angular spherical.

Effect of Physical, Chemical Properties and of Pelleting Solid Materials on the Germination in Pelleted Carrot Seeds (펠렛 피복물질의 물리, 화학적 특성이 당근 펠렛종자의 발아력에 미치는 영향)

  • Kang, Jum-Soon;Son, Beung-Gu;Choi, Young-Whan;Lee, Yong-Jae;Park, Young-Hoon;Choi, In-Soo
    • Journal of Life Science
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    • v.17 no.12
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    • pp.1701-1708
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    • 2007
  • Seed pelleting is generally conducted in order to save the labor for sowing and thinning by enabling the precision mechanical planting. In the present study, the influence of physical and chemical properties of pelleting solid materials was investigated on carrot seed germination. Among the pelleting solid materials evaluated, dialite, kaolin, and talc showed low bulk density and high porosity. Bentonite and dialite carried high water holding capacities of 184% and 173%, respectively, while calcium carbonate, calcium oxide, and fly ash showed relatively low water holding capacity. The pH of kaolin (6.8) and dialite (7.4) were close to neutral, while limestone (12.8), calcium oxide (13.0), and bentonite (10.0) were highly basic. High electro-conductivity was shown in limestone and calcium oxide. EDS analysis revealed that the main elemental compositions of talc were Si (71.0%) and Mg (29.0%), and those of calcium carbonate were Ca (66.6%), Si (22.9%), and Mg (10.5%). High granulation capacity was observed from talc and the mixture of talc and calcium carbonate. Seeds pelleted with bentonite showed the highest hardness. The dissolving type of the pellet layer after imbibition was split type in talc, limestone, zeolite, and fly ash, melt type in calcium carbonate and calcium oxide, and swell type in bentonite and vermiculite. The shortest dissolving time of pellet layer was observed from calcium carbonate and kaolin. The germination speed $(T_{50})$ was delayed as the size of pelleted seeds increased. The optimum size of pelleting was 19 ratio in carrot.

Development of Corrosion Evaluation Index Calculation Program of Raw Water and Evaluation on Corrosivity of Tap Water using the Calcium Carbonate Saturation Index (상수원수의 부식평가 지수 산정 프로그램 개발 및 탄산칼슘 포화지수에 의한 수돗물의 부식성 평가)

  • Hwang, Byung-Gi;Woo, Dal-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.1
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    • pp.177-185
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    • 2009
  • In this study, we developed the program to calculate the corrosion evaluation index for examining the corrosivity of raw water. When it was applied to the Han river and Nakdong river system, sulfuric acid ion, which accelerated corrosion, was higher in Nakdong river system than Han river system while calcium and hardness, which restrained corrosion, was the same way. Summarization of the LI and CCPP calculation result by the developed corrosion evaluation model showed that water quality of Han river system had strong tendency to corrode (is strongly corrosive). Moreover, this study evaluated the corrosivity of calcium carbonate saturation index by adding the chemicals to tap water. Saturation status was maintained in the order of $Ca(OH)_2$ > NaOH > ${Na_2}{CO_3}$ > $CaCO_3$ in the case of LI and RI.

The Comparison of Analytical Methods for Gypsum and Gypsum Slurry (석고 및 석고 슬러리에 대한 분석방법의 비교)

  • Kim, Kyeongsook;Yang, Seugran;Park, Hyunjoo;Lim, Chunsik
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.158-165
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    • 2000
  • The purity of gypsum and quantitation of impurities of flue gas gypsum will not only play an important role in deciding of the optimal condition during a trial run of FGD (flue gas desulfurization), but also can be utilized in quality control of gypsum. The purity of gypsum can be determined from combined water, sulfur trioxide and calcium concentration. We found that the thermal analysis by TGA (thermogravimetric analysis) was the most accurate and convenient method to determine the purity of gypsum. This method will be done in a hour and the results were reproducible. On the other hand, the best way of the analysis of impurities in gypsum was fusion method using $LiBO_2$ as a fusion agent. We also determined the amount of $CO_2$ gas to analyze magnesium carbonate and calcium carbonate contents. The analyses of combined water by TGA, fusion method followed by ICP-AES (inductively coupled plasmaatomic emission spectroscopy) and determination of $CO_2$ amount can lead to more accurate and convenient method for gypsum analysis.

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Sruvey of Raw Silk Reeling Water in Korea (우리나라 제사용수의 실태 조사)

  • Sung, J. C.;Lee, D.;Lee, D. S.;Kho, C. S.;Choi, K. S.;Jou, W. H.
    • Journal of Sericultural and Entomological Science
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    • v.29 no.2
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    • pp.73-81
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    • 1987
  • This investigation was carried cut to obtain the reeling water conditions in Korea. The analyzed items of water were pH, colority, turbidity, acidity, alkalinity, solids electric conductibity hardness and heavy metal ions. About 40% of the reeling water were found to be agreeable, 30% were acceptable provided with some quality control and the others were out of acceptable range mainly based on the M-alkalinity, acidity, pH and total hardness. It was found that there was a following relationship between total hardness and electric conductibity with the relative correlation coefficient r=0.9145. y=15.967+0.22774x Where x, y are electric conductivity and total hardness respectively.

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Durability of High Performance Polymer Concrete Composites (Focusing on Chemical Resistance and Hot Water Resistance) (고성능 폴리머 콘크리트 복합재료의 내구성(내약품성 및 내열성을 중심으로))

  • Hwang, Eui-Hwan;Kim, Yong-Yeon;Song, Min-Kyu
    • Applied Chemistry for Engineering
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    • v.28 no.3
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    • pp.360-368
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    • 2017
  • In order to investigate the durability of high performance polymer concrete composites, polymer concrete specimens were prepared using the ortho-type unsaturated polyester resin (UPR) and iso-type UPR as a polymer binder and the calcium carbonate and silica fine powder as a filler. The durability of polymer concrete specimens was measured by hot water resistance, chemical resistance, pore analysis and SEM observation. The compressive strength of the specimen using the iso-type UPR was higher than that of using the ortho-type UPR, and the compressive strength of the specimen using the silica fine powder was higher than that of using the calcium carbonate filler. From hot water resistance results, it was found that the specimen using the iso-type UPR was superior to that of using the ortho-type UPR and the specimen using the calcium carbonate filler was superior to that of using the silica fine powder. The compressive strength reduction rate was measured after the chemical resistance test and the sodium hydroxide solution showed the highest reduction rate, followed by sulfuric acid, hydrochloric acid and calcium chloride solutions. When using the alkaline solution of sodium hydroxide, the weight reduction rate of the specimen using calcium carbonate was lower than that of using silica fine powder, while for the acidic solutions of sulfuric acid and hydrochloric acid, the weight reduction rate of the specimen using the silica fine powder was lower than that of using calcium carbonate.

Working partial pressure of $CO_2$ gas in aqueous solution

  • Kim Dong-Su
    • Resources Recycling
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    • v.14 no.4 s.66
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    • pp.47-52
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    • 2005
  • Carbonate species in aqueous solution play an important role in the determination of chemical properties of water in relation with alkalinity, buffer capacity, biological productivity, and so on. These compounds also have reactive characteristics such as interphasal reactions between solid, liquid, and gas phases. In the absence of solid materials, the total amount and relative abundance of each carbonate species are directly influenced by the partial pressure of $CO_2$ gas in the atmosphere, which in turn significantly affects the properties of aquatic system. In the water/wastewater treatment process along with the wastes treatment and recycling process which occurring in aquatic environment, it is essential to figure out its characteristics for their optimization and one of its most influential features upon these processes is determined by carbonate species. To understand the fundamental aspect of the relationship between the partial pressure of $CO_2$ gas and chemical features of water, especially pH, the working partial pressure of pure $CO_2$ gas that produced by contacting the dry ice with water has been estimated based on equilibrium calculation. The equilibrium constants for the dissociation ot carbonic acid were determined using van't Hoff equation and the distribution diagram of carbonate species according to the pH has been constructed to substantiate the results of equilibrium calculation. The estimated working partial pressure of pure $CO_2$ gas was found to be a function of the concentration of carbonates in solution, which suggesting that Prior evaluation of the working partial pressure of gas is essential for a better understanding of aquatic interactions.

Effect of Rotary Drum on the Speciation of Heavy Metals during Water Hyacinth Composting

  • Singh, Jiwan;Kalamdhad, Ajay S.
    • Environmental Engineering Research
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    • v.18 no.3
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    • pp.177-189
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    • 2013
  • Studies were carried out on the speciation of heavy metals (Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr) during rotary drum composting of water hyacinth (Eichhornia crassipes) for a period of 20 days. Five different proportions of cattle manure, water hyacinth and sawdust were prepared for composting. This study concluded that, rotary drum was very efficient for the degradation of organic matter as well as for the reduction of mobility and bioavailability of heavy metals during water hyacinth composting. The results from the sequential extraction procedure of heavy metals shows that rotary drum composting changed the distribution of five fractions of Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr. The highest reduction in the bioavailability factors of Pb and Cd was observed during the process. The total concentration of Cu, Cr, and Cd was very low compared to the other metals (Zn, Mn, Fe, Ni, and Pb); however, the percentage of exchangeable and carbonate fractions of these metals was similar to other metals. These results confirmed that the bioavailability of metals does not depend on the total concentration of metals. From this study, it can be concluded that the addition of an appropriate proportion of cattle manure significantly reduced the mobile and easily available fractions (exchangeable and carbonate fractions) during water hyacinth composting in rotary drum.

Evaluation of Calcium Carbonate Saturation Indices in Water (상수 원수 수질의 탄산칼슘 포화지수 평가)

  • Hwang, Byung-Gi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.8 no.1
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    • pp.130-135
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    • 2007
  • In order to examine the corrosiveness of tap water, we studied methods calculating various indices including calcium carbonate saturation indices, using RTW model and LPLWIN model. Indices such as LI, RI and AI could be computed using the RTW model, whereas the LPLWIN model could find indices as LI, LR and CCPP. With water quality data obtained from tap water of Han River and Nak-Dong River watersheds, based on the indices found from the models, the water quality of the Nak-Dong River is better than that of Han River in the point of resisting corrosiveness. Further, the water quality of winter is highly corrosive than that of summer, as long as the temperature rises up, the corrosiveness is reduced.

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Slope Sedimentation and Organic Carbon Content in the Late Quaternary West Florida Slope Sediments

  • Lee, Eun-Il;Park, Soo-Chul
    • Journal of the korean society of oceanography
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    • v.34 no.3
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    • pp.144-150
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    • 1999
  • Slope sedimentation on the modern west Florida continental margin is controlled by pelagic carbonate accumulation and off-shelf sedimentation of neritic carbonates and terrigenous fines. Production and deposition of pelagic carbonates by planktonic foraminifera and coccoliths have played a significant role in the total slope sedimentation and are mainly promoted by sea-surface productivity. Organic carbon data reflect the relatively high biological productivity in surface waters, indicating high accumulation of biogenic calcareous sediments. The surface-water productivity in the study area is supported by the relation among microfossil assemblages, carbonate mineralogy and sedimentary organic carbon.

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