• Title/Summary/Keyword: carbonate mineral

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Optical Characteristics of Eco-friendly In-situ Recycled Paper with Limestone as Filler (석회석을 원료로 사용한 재생용지의 친환경 In-situ Filler로서의 광학적 특성 연구)

  • Lee, Hyun-Jae;Lee, Lown;Kim, Chun-Sik;Nam, Seong-Young;Seo, Yung-Bum;Ahn, Ji-Whan
    • Journal of the Korean Ceramic Society
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    • v.51 no.2
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    • pp.132-137
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    • 2014
  • The study was performed with low-grade limestone, which is used to make cement or is disposed of due to its low CaO content. In this study, the optimal condition of limestone with which to manufacture precipitated calcium carbonate (PCC) and limestone in fiber was determined through in-situ reactions. The best firing condition is with slaked lime with rapid cooling after 2 h of firing at $1000^{\circ}C$. In addition, the content of CaO can be increased by sorting the low-grade limestone using a 200 mesh filter, and the optical quality of old newspaper (ONP) was similar when using both low-grade and high-grade limestone. Also, controlling the particle size of PCC is an important factor pertaining to the optical characteristics of paper.

The Quantitative Analysis by Digital Subtraction Radiography on the Effect of Platelet Rich Plasma Combined with Synthetic Bone Graft on Grade II Furcation Involvement (2급 치근 이개부 치료 시 합성골 이식 및 혈소판 농축 혈장의 골재생 효과에 대한 디지털 공제술의 정량적 분석)

  • Oh, Ji-Soo;Lim, Sung-Bin;Chung, Chin-Hyung
    • Journal of Periodontal and Implant Science
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    • v.31 no.2
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    • pp.465-475
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    • 2001
  • The purpose of this study was to evaluate effect of platelet rich plasma on the treatment of Grade II furcation involvement, with and without porous resorbable calcium carbonate($Biocoral^{(R)}$)in humans by digital subtraction radiography. 15 teeth(control group) were treated with porous resorbable calcium carbonate($Biocoral^{\(R)}$), and 15 teeth(test group) were treated with porous resorbable calcium carbonate($Biocoral^{(R)}$) and Platelet Rich Plasma. The change of bone density was assessed by digital subtraction radiography in this study. The change of mineral content by as much as 5%(vol) could be perceived in the subtracted images. The change of mineral content was assessed in the method that two radiographs are put into computer program to be overlapped and the previous image is subtracted by the later one. Both groups were statistically analyzed by Wilcoxon signed Ranks Test and Mann-whitney Test using SPSS program(5% significance level). The results were as follows: 1. In test group, the radiolucency in 3 months after surgry were significantly increased than 1 month after surgery(p<0.05). 2. In test group, there were no significant difference between 1 month after surgery and 6 months after surgery(p>0.05). 3. In test group, the radiopacity in 6 months after surgery were significantly increased than 3 months after surgery(p<0.05). 4. In control group, the radiolucency in 3 months and 6 months after surgery were significantly increased than 1 month after surgery(p<0.05). 5. In control group, the radiopacity in 6 months after surgery were significantly increased than 3 months after surgery(p<0.05). 6. There were no significant difference between test group and control group at 1 month, 3 months after surgery, but radiopacity in test group were significantly increased than control group at 6 months after surgery(p<0.05). In conclusion, Platelet Rich Plasma can enhance bone density.

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Production of SrCO3 from SrSO4 through the Black Ash Process (Black Ash법을 이용한 SrSO4로부터 SrCO3 제조)

  • Kang, Jungshin;Lee, Jin-Young
    • Resources Recycling
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    • v.30 no.5
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    • pp.49-56
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    • 2021
  • In this study, using strontium sulfate (SrSO4) recovered from magnetite ore in Hongcheon, the Black Ash process was used to produce strontium carbonate (SrCO3). In the carbothermic reaction step, SrSO4 was reacted with carbon (C) at 1273 K under Ar gas atmosphere using a gas-tight quartz reactor to produce strontium sulfide (SrS). Afterward, water leaching of the residues produced from the carbothermic reaction at 353 K and carbonation of the leaching solution using sodium carbonate (Na2CO3) at 298 K were conducted to produce SrCO3. The results of this study demonstrate the feasibility of the production of SrCO3 via the Black Ash process using domestic magnetite ore containing strontium (Sr).

Development of Recycled Paper Properties using In-Situ Process (In-Situ 공정(工程)을 이용한 재활용(再活用) 펄프의 물성특성(物性特性) 향상 연구(硏究))

  • Lee, Jong-Kyu;Yoo, Kwang-Suk;Nam, Seong-Yong;Ah, Ji-Whan
    • Resources Recycling
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    • v.19 no.3
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    • pp.62-70
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    • 2010
  • As the demand for paper continues to grow and the importance of recycled paper, white ledgar(WL) and old newspaper pulp(ONP), continuously increase. In addition, usage of recycled paper is essential in terms of forest conservation and environmental protection issues. However, optical and mechanical properties of recycled paper have some drawbacks than regular paper's properties that is indispensable. In order to complement these problems of recycled paper, precipitated calcium carbonate (PCC) was synthesized by the In-situ process with a recycled pulp. Depending on the size of PCC is divided into 2 types, $0.01{\mu}m{\sim}0.09{\mu}m$ colloid type ultra-fine particle and $0.1{\mu}m{\sim}0.9{\mu}m$ cubic type particles. In this study, we analyze how the different shape and size of precipitated calcium carbonate affects in the optical and mechanical properties of the recycled paper used as a filler. Furthermore, we mixed with chemical pulp for overcome reduce of mechanical properties, without using other chemicals, when we use PCC as a filler. The results has the possibility to meet in GR excellent recycling certification mark, standard was proposed.

Carbonation of a few of Common materials which can fix CO2 (상용 CO2고정재료의 탄산화에 관한 문헌적 연구)

  • Chen, zheng-xin;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.47-48
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    • 2016
  • Mineral carbonation technology is a process whereby CO2 is chemically reacted with calcium-and/or magnesium-containing minerals to form stable carbonate materials. Add the Materials that could fix CO2 as mineral admixture to concrete can improve the anti-carbonation properties of concrete. This paper has carried on the literature research on the carbonated mechanism of Material that could fix carbon dioxide. Such as Brucite, 𝜞-C2S, Mg2SiO4, MgO, Ca3MgSi2O8. And summarizes the development of the development of this field.

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Evaluation of the Utilization of Carbon Dioxide Microbubble Mixing Water for Mineral Carbonation of Cement Materials (시멘트 재료의 광물탄산화를 위한 이산화탄소 마이크로버블 배합수 활용성 평가)

  • Nam, Min-Seok;Park, Dong-Cheon
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.205-206
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    • 2023
  • In this study, the characteristics of cement were analyzed using carbon dioxide microbubble water as a mixed water for mineral carbonation of cement materials. Carbon dioxide reacts with the calcium compound of cement to produce calcium carbonate and affects the initial strength improvement. Therefore, in this study, temperature, air content, thermal analysis, and compressive strength tests were conducted to confirm the reaction between cement materials and carbon dioxide. As a result of the measurement, the reaction between cement and carbon dioxide was confirmed in a specimen using carbon dioxide microbubble water as a mixed water, which affected the initial strength improvement.

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A Feasibility Study on the Utilization of by-Product Sludge Generated from Waste Concrete Recycling Process (폐 콘크리트 재생순환자원 부산물 슬러지의 활용 기초연구)

  • Shin, Hee-young;Ji, Sangwoo;Woo, Jeong-youn;Ahn, Gi-oh;An, Sang-ho
    • Resources Recycling
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    • v.25 no.3
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    • pp.29-36
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    • 2016
  • The characteristics analysis and pH neutralization test were carried out to use of slurry generated from recycling processes of construction wastes. D (5.0) of raw sludge was $42.4{\mu}m$ and over 60 % of sludge distribute under 45 um (-325 mesh). Muscovite and carbonate minerals were main minerals of fine particles, and the portion of carbonate minerals increased as particle size decreased. Although the more heavy metals were observed in the finer particle size, the contents was found to be less than Korean contaminated soil regulation (area 2). The effects of flocculants addition for accelerating solid-liquid separation were negligible because the slurry already contains excess of coagulant added in the waste concrete recycling process. It was difficult to neutralize the sludge supernatant due to high pH (about 12) by adding acids, but the introduction of $CO_2$ decreased the pH to 8.5, The precipitate recovered during $CO_2$ introduction was determined to be $CaCO_3$ with XRD, and it indicates that high pure $CaCO_3$ could be obtained during the process.

Evaluation of geochemical processes affecting groundwater chemistry in Namwon, Korea

  • Kim, Kang-Joo;Natarajan Rajmohan;Kim, Hyung-Jung;Kim, Suk-Hwi;Hwang, Gab-Soo;Cho, Min-Joe;Lee, Sang-Ho
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.334-337
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    • 2004
  • Groundwater chemistry in Namwon area, Korea, was investigated to understand the contribution of geochemical processes on groundwater chemistry. For this study, a total of 279 groundwater samples were collected from 93 wells distributed over the study area. Higher concentrations of major ions are generally encountered in the shallow alluvial wells, suggesting that these chemicals are originated from the surface contamination sources. Mass balance analysis based on reaction stoichiometry reveals that the water chemistry is regulated by three major chemical processes: weathering of silicate/ carbonate minerals, input of C1/SO$_4$ salts, and nitrate generating processes. The results show that mineral weathering is the most dominating factor regulating the groundwater chemistry. However, the groundwaters with the higher salt concentration indicate the larger mineral weathering effect, suggesting that some part of the mineral weathering effect is also associated with the anthropogenic activities such as limes applied to the cultivated lands, carbonates (CaCO$_3$) in the cement materials.

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Principle and Application of 'Image-mapping' in-situ U-Pb Carbonate Age-dating ('Image-mapping' in-situ U-Pb 탄산염광물 연대측정법의 원리 및 적용)

  • Ha Kim;Seongsik Hong;Chaewon Park;Jihye Oh;Jonguk Kim;Yungoo Song
    • Economic and Environmental Geology
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    • v.56 no.2
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    • pp.115-123
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    • 2023
  • We introduce a new 'image-mapping' in-situ U-Pb dating method using LA-ICP-MS, proposed by Drost et al. (2018), and show the characteristics and usability of this method through several examples of absolute age results determined by first applying it to samples from the Joseon Supergroup of the Early Paleozoic Era in Korea. Unlike the previous in-situ spot analysis, this in-situ U-Pb dating method for carbonate minerals can determine the absolute age with high reliability by applying the 'image-mapping' method of micro-sized domains based on micro-textural observation, as well as determine the absolute age of multiple geological 'events' that occurred after deposition. This was confirmed in the case of determining the syn-depositional age and the multiple post-depositional ages from carbonate minerals of the Makgol and the Daegi Formations. Therefore, if the 'image-mapping' in-situ U-Pb dating method is applied to determine the absolute age of various types of carbonate minerals that exist in various geological environments throughout the geologic era, it will be possible to secure new geological age information.

The Mineralogy and Geochemistry of the Uppermost Sediments of the Lake Hovsgol, North Mongolia : It's Implication to the Paleoenvironmental Changes

  • Tumurhuu, D.;Narantsetseg, Ts.;Ouynchimeg, Ts.
    • The Korean Journal of Quaternary Research
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    • v.18 no.2 s.23
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    • pp.3-3
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    • 2004
  • One short core with length of 146cm(HB-107, at coordinates of $N51^{\circ}$11'37.5";$E100^{\circ}$24'45.6", from 229m water depth was subject of the present study. The sub-samples of the core were analyzed for the water contents (WC%), biogenic silica, identification of the main phases, grain size distribution, geochemistry and some physical properties of sediment(Wet density and Magnetic susceptibility) with aims of recording palaeo-environmental changes in Northem Mongolia. The evaluation of the geochemical and mineralogical proxies on palaeo-climated and palaeo-environmental changes are based on comparison to the behvior of biogenic silica through core, as later one had been showed itself, as good indicator of the climate and environmental fluctuation. Age model of the investigating core based on previously C 14 dated core HB105 taken from the central part of the Hobsgol Lake and the result had been published elsewhere. The core consists of two litological varieties : upper diatomaceous silt, lower clay. According to the age model the upper diatomaceous silt formed during the Holocene, lower caly-during the late Pleistocene glacial period. The geochemistry and phase identification analysis on the core samples are resulted in determining main minerals that form the bottom sediments and their geochemistry. The main include quartz, felspar, muscovite, clinochlore, amphibole and carbonate phase(dolomite and calcite). Through the core not only occur the relative quantitative changes of the main phases, but also happen that the carbonate phase completely disappear in diatomaceous silt. This is believed to be related to the lake water salinity changes, which occurred during the trassition period from Pleistocene glacial-to the Holocene interglacial. These abrupt changes of the mineralogy have been clearly traced in geochemistry of sediments, specially in calcium concentration, which is high in lower clay and low in upper diatomaceous silt. That means, geochemistry and mineralogy of the bottom sediments can be used as proxy data on palaeo-climate and palaeo-environmental changes.

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