• Title/Summary/Keyword: carbonaceous

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Charge Distribution in a capacitor observed by PEA Method (PEA법에 의한 캐패시터내 전하분포 측정)

  • Endrowednes, Kuantama;Han, Deok-Woo;Kwak, Dong-Joo;Sung, Youl-Moon
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1156-1157
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    • 2008
  • The use of the pulsed electro acoustic (PEA) method allowed us to perform the direct observations of spatio-temporal charge distributions in Electric double layer capacitors (EDLCs) based on polarizable nanoporous carbonaceous electrode. The negative charge density became the maximum, about 205 $C/m^3$ at the region where was near to collector layer in EDLCs for case $V_{DC}$ = 2.5 V, while the positively charged density became the maximum, about 61.1 $C/m^3$ at the region where it was located around the cathode layer. The PEA measurement used here is a very useful method to quantitively investigates the spatio-temporal charge distribution in EDLCs.

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Characteristics of Carbonaceous Species in the Fine Particles in Seoul Area (미세입자중 탄소성분농도 특성에 관한 연구)

  • 강충민;이학성;강병욱;이상권;선우영
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.83-84
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    • 2003
  • 미국 EPA (Environmental Production Agency)에서는 대기중 입자상 물질을 입경에 따라 두가지 형태인 PM$_{2.5}$와 PM$_{10}$으로 분류하였다. PM$_{2.5}$는 먼지의 입경이 2.5 $\mu\textrm{m}$보다 작거나 같은 입자상 물질로서 미세입자로 정의하고 있으며, PM$_{10}$은 먼지의 입경이 10 $\mu\textrm{m}$보다 작거나 같은 입자상 물질로서 조대입자로 정의하고 있다. 또한 1997년 7월에는 수많은 연구결과에서 PM$_{2.5}$의 인체 유해성을 근거로 새로운 환경기준을 설정하여 미세입자에 대한 관리를 강화하였다. 대기중 PM$_{2.5}$는 도시지역에서 주요 시정장애원인 물질로도 알려져 있다. (중략)있다. (중략)

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Characteristics of PM2.5 in Gyeongsan Using Statistical Analysis (통계분석을 이용한 경산 지역의 초미세먼지(PM2.5) 농도 특성 파악)

  • Li, Kai Chao;Hwang, InJo
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.6
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    • pp.520-529
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    • 2015
  • The ambient $PM_{2.5}$ samples were collected by $PM_{2.5}$ sampler from September 2010 to December 2012 at Daegu University, Gyeongsan. A total of 260 samples were collected and 27 species were analyzed by inductively coupled plasma, ion chromatography, and thermal optical reflectance methods. Factor analysis identified four sources such as biomass burning source/secondary aerosol source, soil source, industry source, and incinerator source/mobile source. Also, backward trajectories were calculated using HYSPLIT 4 (Hybrid single-particle lagrangian integrated trajectory) model and PSCF (Potential source contribution function) model was applied to identify the possible source locations of carbonaceous species and water soluble ions species. PSCF results showed that the possible source locations of most chemical constituents measured in Gyeongsan were the industrial areas in the eastern coast of China, northeast regions of China, the Gobi Desert, and east sea of Korea.

Single Particle Analysis of Atmospheric Aerosol Particles Collected in Seoul, 2001, Using Low-Z Particle Electron Probe X-ray Microanalysis (Low-Z Particle Electron Probe X-ray Microanalysis를 이용한 2001년 서울시 대기 중 입자상 물질 분석)

  • Koo Hee Joon;Kim HyeKyeong;Ro Chul-Un
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.6
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    • pp.823-832
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    • 2004
  • Atmospheric aerosol particles collected in Seoul on four single days, each in every seasons of 2001, were characterized and classified on the basis of their chemical species using low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA). Low-Z particle EPMA technique can analyze both the size and the chemical species of individual aerosol particles of micrometer size and provide detailed information on the size distribution of each chemical species. The major chemical species observed in Seoul aerosol were aluminosilicate, silicon dioxide, calcium carbonate, organic, carbon-rich, marine originated, and ammonium sulfate particles, etc. The soil originated species, such as aluminosilicate, silicon dioxide, and calcium carbonate were the most popular in the coarse fraction, meanwhile, carbonaceous and ammonium sulfate were the dominant species found in the fine fraction. Marine originated species such as sodium nitrate was frequently encountered, up to 30% of the analyzed aerosol particles.

EFFECT OF ADDITIVES ON THE PYROLYSIS AND COMBUSTION OF CELLULOSE (셀룰로오스의 열분해에 대한 첨가제의 영향)

  • 심철호;박영수
    • Journal of the Korean Society of Tobacco Science
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    • v.7 no.2
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    • pp.169-178
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    • 1985
  • In the previous paper, the kinetics of cellulose were described. In this study, the ability of some additives to act as a flame promoter for cellulose was investigated using dynamic thermogravimetry and differential scanning calorimetry. The treated cellulose was thermally decomposed through the two model as previously noted with the untreated cellulose. The first step was associated with the flaming combustion of volatile material released in the fraunentation process and the second was caused by the glowing combustion of carbonaceous residue. The first group of the additives, which could be divided into two groups by the pyrolytic mechanism of cellulose, appeared to catalyze the fragmentation, maximizing the degradation to produce tarry products, with gaseous flammable substrate. The heat evolved in flaming combustion mode was increased significantly by the treatment of the cellulose retained 1-5% of the first group additives.

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Form of Molybdenum in the Carbonaceous Black Slates of the Ogcheon Belt (옥천대 탄질 흑색 점판암내 몰리브덴의 존재 형태)

  • 정기영;이석훈
    • Journal of the Mineralogical Society of Korea
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    • v.14 no.1
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    • pp.52-57
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    • 2001
  • 옥천대의 탄질 흑색 점파암에 최대 1000 ppm까지 부화되어 있는 몰리브덴의 광물학적 존재형태를 밝히기 위하여 충청북도 괴산군 덕평지역 흑색점판암에 대하여 박편제작, X선회절분석, 중성자활성화학분석, 주사전자현미경관찰, 에너지분산 X선분석, 파장분산 X선분석 등을 실시하였다. 그결과 몰리브덴은 두께 $1~2\mu$m 정도의 극미립 엽상 휘수연석($MoS_2$)으로 존재함이 판명되었다. 휘수연석은 흔히나이트의 포획물로 산출된다. 탄질흑색 점판암에 우라늄 및 바다듐과 함께 다량의 몰리브덴이 함유되어 있음에도 과거의 연구에서 그 존재형태가 규명되지 않은원인은, 극미립 휘수연석이 불투명한 세립 탄질기질에 분산 분포하기 때문이다.

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Mixed Electrolytes of Organic Solvents and Ionic Liquid for Rechargeable Lithium-Ion Batteries

  • Choi, Ji-Ae;Shim, Eun-Gi;Scrosati, Bruno;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3190-3194
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    • 2010
  • Mixed electrolytes formed by the combination of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide (BMP-TFSI) ionic liquid and standard liquid electrolyte are prepared and characterized. Linear sweep voltammetry measurements demonstrate that these mixed systems exhibit a wide electrochemical stability window, allowing them to be suitable electrolyte for carbonaceous anode-based lithium-ion batteries. Lithium-ion cells composed of graphite anode and $LiCoO_2$ cathode are assembled using the mixed electrolytes, and their cycling performances are evaluated. The cell containing proper content of BMP-TFSI shows good cycling performance comparable to that of a cell assembled with organic electrolyte. The presence of BMP-TFSI in the mixed electrolyte contributes to the reduction of the flammability of electrolyte solution and the improvement of the thermal stability of charged $Li_{1-x}CoO_2$ in the electrolyte solution.

Electromagnetic Interference Shielding Effectiveness of Electroless Nickel-plated MWCNTs/CFs-reinforced HDPE Matrix Composites

  • Choi, Woong-Ki;Hong, Myung-Sun;Lee, Hae-Seong;An, Kay-Hyeok;Bang, Joon-Hyuk;Lee, Young Sil;Kim, Byung-Joo
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.597-600
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    • 2014
  • In this work, the electromagnetic interference shielding effectiveness (EMI-SE) of carbon nanotube/carbon fiber-reinforced HDPE matrix composites are investigated with various preparation conditions, such as the carbon fiber and carbon nanotube content, the presence of metal additives, as well as mixing speed and time. It was found that the EMI-SE of the composites increased with filler contents and metal additives. These results indicate that the content and length of carbonaceous fillers determine the electric networks in the composites, resulting in the control of the EMI-SE of the composites.

The Formation and Deliveries of CO in Reconstituted Tobacco Leaves by Decreasing of Combustion Temperature (제지식 판상엽으로 제조된 권련에서 연소점 온도 내림이 CO의 생성과 이행에 미치는 영향)

  • 김대종;송태원;이문수;제병권
    • Journal of the Korean Society of Tobacco Science
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    • v.19 no.1
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    • pp.64-69
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    • 1997
  • Deliveries of tar, nicotine, CO and $CO_2 in main stream smoke decreased as the potassium salt content of reconstituted tobacco leaves increased. The peak temperatures of the central region of a burning cone during a puff was in the range 940$^{\circ}C$∼430$^{\circ}C$ by IR thermal video system. The exogenous Potassium salt contents influenced the reduction of carbon-monoxide delivery through a decrease in the Peak temperature of the burning cone. Consequently, the amount of CO formed in the combustion Process was reduced by potassium salt. Moreover, the temperature of the burning cone was lowered, and the CO formed from carbonaceous reduction was decreased.

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Hybrid Capacitors Using Organic Electrolytes

  • Morimoto, T.;Che, Y.;Tsushima, M.
    • Journal of the Korean Electrochemical Society
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    • v.6 no.3
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    • pp.174-177
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    • 2003
  • Electric double-layer capacitors based on charge storage at the interface between a high surface area activated carbon electrode and an electrolyte solution are characterized by their long cycle-life and high power density in comparison with batteries. However, energy density of electric double-layer capacitors obtained at present is about 6 Wh/kg at a power density of 500W/kg which is smaller as compared with that of batteries and limits the wide spread use of the capacitors. Therefore, a new capacitor that shows larger energy density than that of electric double-layer capacitors is proposed. The new capacitor is the hybrid capacitor consisting of activated carbon cathode, carbonaceous anode and an organic electrolyte. Maximum voltage applicable to the cell is over 4.2V that is larger than that of the electric double-layer capacitor. As a result, discharged energy density on the basis of stacked volume of electrode, current collector and separator is more than 18Wh/l at a power density of 500W/l.