• Title/Summary/Keyword: carbon effect

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Study on Direct Dipolar Effect of Neighboring Protons in Proton Coupled $^{13}C$ Relaxation Experiment

  • NamGung, Hyeon;Lee, Im Pyo;Lee, Jo Ung
    • Bulletin of the Korean Chemical Society
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    • v.21 no.11
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    • pp.1077-1084
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    • 2000
  • The dipolar effect of neighboring protons that are not directly bonded to the carbon of interest on coupled carbon-13 relaxation in a simple organic molecule has been studied by comparing the relaxation behaviors of labeled carbon-13 in $Br13CH_2COOH$ with those in $BrCH_213COOH.$ Various pulse sequences, such as coupled inversion recovery pulse sequence, J-negative and J-positive pulse sequence, and nonselective and selective proton ${\pi}pulse$ sequence, were employed to perform the required coupled spin relaxation experiments. To gain information on various spectral densities, including that of dipolar-CSA cross correlation, the experiments were performed on two different spectrometers, operating, respectively, at 50.31 and 125.51MHz for 13C. The magnitude of CH dipolar spectral densities for $BrCH_213COOH$ was found to be about 8% of those for $Br13CH_2COOH$, which means the effect due to the protons not directly bonded to the carbon of interest is small but not completely negligible.

Development of the Forest Carbon Sink Index on Afforestation and Reforestation Activities (신규조림·재조림 활동의 산림탄소흡수원 지수 개발)

  • Song, Minkyung;Bae, Jae Soo;Seol, Mi Hyun
    • Journal of Korean Society of Forest Science
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    • v.103 no.1
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    • pp.137-146
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    • 2014
  • We have developed the Forest Carbon Sink Index on afforestation and reforestation activities, a regulation stated in article 26 of the 'Law on the maintenance and enhancement of carbon sink (Carbon Sink Law)', which took effect on March, 2013. According to the legal purpose to evaluate the performance of individual forest carbon offset projects and to compare each other at a certain point, values of the forest carbon sink index were calculated by the scoring method. Three criteria were established based on the Carbon Sink Law: 'Carbon' (real greenhouse gas reduction), 'Human' (socio-economic effect) and 'Nature' (environmental effect). Continuously, 9 indicators from the three criteria were selected by top-down approach; the adequacy of each criteria and indicators were reviewed through on-line Delphi survey; and finally weighted value of each criteria and indicators were assigned. To reflect the characteristics of the domestic forest carbon offset projects, which focus on corporate social responsibility-typed projects, we applied the score weighting method to minimize gaps among criteria and ones among indicators. After applying our newly developed forest carbon sink index to five domestic forest carbon offset projects, we could confirm that the criteria of 'Human' and 'Nature', which criteria are in relatively low weight, can play a role as an actual incentive to reduce negative socio-economic and environmental impacts. Based on performance evaluation of the five forest carbon offset project by the forest carbon sink index, the best or good performance project developers could be rewarded, and further the performance evaluation would work as an incentive to stimulate the involvement of domestic project developers in the field of forest carbon offset project.

Modification of C/C Composite Bipolar Plate by Addition of Electro-Conductive Carbon Black

  • Ryu, Seung-Kon;Hwang, Taek-Sung;Lee, Seung-Goo;Lee, Sun-A;Kim, Chang-Soo
    • Carbon letters
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    • v.2 no.3_4
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    • pp.165-169
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    • 2001
  • Modification of C/C composite bipolar plate for improving electrical conductivity was carried out by addition of electroconductive carbon black (EC-CB). Carbon black was carefully mixed to methanol-containing phenolic resin, impregnated into 2D-carbon fabrics, hot pressed and then carbonized to obtain composite plate. Inclusion of electro-conductive carbon black enhanced the electrical conductivity of the C/C composites by increasing the conduction path. Addition of 10 vol% carbon black increased the electrical conductivity from 5.5/${\Omega}cm$ to 32/${\Omega}cm$ and reduced the crack formation by filling effect, resulting in the increase of flexural properties of composite plate. However, at carbon black content over 10 vol%, flexural properties decreased by delaminating role of excess carbon black at the interface in C/C composites.

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Effect of Graphite on Rice Growth (흑연(GRAPHITE)의 벼 생육에 미치는 영향)

  • Hwang, Cher-Won
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.2
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    • pp.86-91
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    • 2003
  • Carbon material such as graphite and activated charcoal can promote the growth of some formsog bacteria. We examined whether this bacterial growth promoting effect can have a positive influence on field crops. Refined graphite was mixed into the standard soil used in rice cultivation. Varying soil graphite mixtures of 0.1%, 0.5% and 1% were used to cultivate rice seedling for 3 weeks. After transplanting in the filed, rice plants were cultivated for 4 months. To observe the effect of graphite(carbon material) during the cultivation of rice, we examined various different growth components in this research. During the transplanting stage, growth promoting effect of carbon was observed in the 0.1% carbon added soil. However, there were not much difference between graphite added soil and standard soil in the other stages. Rice yield was highest in the soil with 0.1% graphite.

Assessment of Ductility for the RC Piers with Transverse Reinforcement and Application of Carbon-Fiber Red (횡방향 구속철근의 배근방법에 따른 철근콘크리트 교각의 연성 평가 및 탄소섬유 ROD의 적용)

  • 이영호;이학은
    • Journal of the Korea Concrete Institute
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    • v.14 no.1
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    • pp.8-15
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    • 2002
  • This paper presents a study carried out for the seismic capacity in reinforced concrete(RC) piers by the confinement effect of transverse reinforcement as such a hooked-tied, welded-tied and spiral reinforcement. In order to assess the seismic capacity with transverse reinforcement, experiment리 and analytical methods were adopted. A RC column survey was conducted based on eight one-fourth scale single circular column specimens designed and tested under slow horizontal cyclic loads. Two cases were analyzed. The confinement effect of concrete by transverse reinforcement is considered not in Case 1 but in Case 2. Also, we studied the propriety of making use of the method in which a carbon fiber rod replace spiral reinforcement in RC piers. In experimental tests, a welded-tied and spiral reinforcement has a good seismic capacity, but a carbon fiber rod presents low ductility in comparison with a hooked-tied reinforcement. In an analytical study, displacement ductility is approximate to the experimental result because of considering the confinement effect of the transverse reinforcement. Even if the confinement effect of the transverse reinforcement is considered, the analytical results for ductility of the specimens with welded-tied and spiral reinforcement show an excessive underestimation of the experimental results.

Effect of Organic Material, Active Carbon and Magnesium on the Growth of Zoysia koreana (잔디생육에 대한 유기물, 활성탄소 및 마그네슘의 효과)

  • Choi, Byung-Ju;Shim, Jai-Sung;Park, Hoon
    • Asian Journal of Turfgrass Science
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    • v.8 no.3
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    • pp.193-199
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    • 1994
  • Effect pf rape seed oil cake compast (OM) active carbon(C) compound fertilizer (NPK) and magnesium sulfate (Mg) application on Zoysia koreana growth by lysimeter of 50cm soil column filled with a low fertility loam. Effect on growth was in order of OM>OM . NPK interaction> NPK . active carbon and Mg were not effective OM . NPK interaction effect was negative on leaf width and root dry matter yield. OM and OM . NPK interaction were most effective on rhizome growth. Their effect did not change the ratio of growth rates between aerial part and rhizome but change that between aerial part and root. Leaf width was most sensitive to the treatments.

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Effect of Pre-strain on the Bauschinger Phenomenon of Micro-Alloying Forging Steel (비조질강의 바우싱거 효과에 미치는 변형율 영향)

  • Kwon Y.-N.;Lee Y. S.;Kim S. W.;Lee J. H.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.313-316
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    • 2005
  • In the present study, Bauschinger effect was investigated for the micro-alloying forging steel which has been developed for about 30 years ago to save energy consumption by eliminating the heat treatment processes in the forging industry. The micro-alloying steels used fur cold forging industry mainly aim to replace the usual carbon steel. With the conventional carbon steels, all the deformation history can be eliminated after the final heat treatment(quenching and tempering). In the case of micro-alloying forging steels, however, the prior deformation history should be taken into consideration to meet the mechanical property requirement since the microstructure of micro-alloying steels might exhibit the Bauschinger effect, which was not needed to consider in the case of conventional carbon steel having quenching and tempering treatment. In the present study, the reverse loading tests were carried out to determine the Bauschinger effect of micro-alloying steel which composed of ferrite and cementite phases.

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Confining Effect of CFS on Concrete Compressive Members under Load Actions (하중이력에 따른 콘크리트 압축부재의 CFS 보강효과에 관한 연구)

  • 배주성;김경수;김재욱;고영표
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.705-708
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    • 1999
  • Advanced composite materials such as carbon fiber, aramid, and glass fiber sheet, are widely used recently to strengthening existing reinforced concrete structures. The purpose of this paper was to investigate the mechanical characteristics of concrete compressive members confined with carbon fiber sheet and evaluate the efficiency of the strengthening under load actions. Uniaxal compression tests of concrete compressive members confined with carbon fiber sheet were experimentally used to develop a relationship between the axial stresses and the lateral stresses. The resulting axial and lateral strains were used to determine the confinement effect of concrete compressive members.

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Effect of Additives on the Strength Characteristics of MDF Cement Composites (MDF 시멘트 복합재료의 강도 특성에 미치는 첨가재의 영향)

  • 김태현;최상흘
    • Journal of the Korean Ceramic Society
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    • v.29 no.11
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    • pp.893-899
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    • 1992
  • Composite specimens, which are composed MDF cement of HAC-PVA system were prepared by adding carbon fiber, hydrated silica and SiC powder, and we studied effect of additives on the flexural strength of the composites. All of additives is effective in the improvement of flexural strength of the composite specimens. The size of average pore diameter in the specimens which have high flexural strength property was small. Specimen mixed with hydrated silica was effective in the particle compact property. Flexural strength of carbon fiber reinforced MDF cement composites were improved because of crack deflection of carbon fiber in cementitious matrix.

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Plasma Process Effect and Selectivity Characteristics of Carbon Nanotube Film Humidity Sensor (CNT 습도센서의 플라즈마처리 효과와 선택성 특성)

  • Park, Chan-Won
    • Journal of Industrial Technology
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    • v.33 no.A
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    • pp.67-72
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    • 2013
  • CNT(carbon nanotube) humidity sensors with plasma treated electrodes exhibit a much faster response time and a higher sensitivity to humidity, compared to untreated CNT and porous Cr electrodes. These results may be partially due to their percolated pore structure being more accessible for water molecules and for expending the diffusion of moisture to the polyimide sensing film, and partially due to the oxygenated surface of CNT films. This paper shows a plasma process effect and selectivity characteristics of CNT film humidity sensor.

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