• Title/Summary/Keyword: carbon distribution

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Influence of Carbon Black Contents and Rubber Compositions on Formation of Wear Debris of Rubber Vulcanizates

  • Choi, Sung-Seen;Yang, Seong Ryong;Chae, Eunji;Son, Chae Eun
    • Elastomers and Composites
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    • v.55 no.2
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    • pp.108-113
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    • 2020
  • Wear particles of the model tread compounds for bus and truck tires were made using a laboratory abrasion tester and characterized based on their size distributions, shapes, and crosslink densities. The influence of the carbon black contents and rubber compositions (NR= 100 and NR/BR= 80/20) on the production of wear particles was investigated. The wear particles were separated according to size using a sieve shaker. The shape properties of the wear particles were analyzed using an image analyzer and scanning electron microscopy (SEM). Their shapes were observed as tiny stick cookies or sausages with bumpy surfaces. The particle size distribution tended to be smaller with increasing carbon black content. Moreover, the particle size distributions of the NR = 100 samples were larger than that of the NR/BR blend samples. There were different filaments in the wear particles. The filament diameters tended to be thinner with increasing carbon black content. The crosslink density increased with increasing carbon black content, and the crosslink densities of the NR= 100 samples were lower than those of the NR/BR blend ones. The particle size distribution tended to be smaller with increasing crosslink density. Based on the experimental results, the wear particles can be produced by detaching debris from the main body through repetitive strain and recovery.

The Effect of Particle Size Distribution of the Nongraphitic Carbon on the Performance of Negative Carbon Electrode in Lithium Ion Secondary Battery (무정형 탄소의 입도분포에 따른 리튬이온이차전지의 탄소부극 특성)

  • Kim, Hyun-Joong;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.781-785
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    • 1998
  • Material and electrochemical characteristics of petroleum coke of the nongraphitic carbon prepated with attrition milling for 6~48 hours and heat-treatment at $700^{\circ}C$ for 1 hour was investigated. The milling condition affects the particle size distribution, BET specific surface area and interlayer distance of petroleum cokes. Carbon electrode with petroleum cokes prepared at the milling time of 12~24 hours and having average particle size of $6{\sim}8{\mu}m$ showed best electrochemical characteristics form the investigation of cyclic voltammogram and charge-discharge characteristics.

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Effect of the Slag Former on the Metal Melting and Radionuclides Distribution in an Electric Arc Furnace

  • Song Song-Pyung;Min Byung-Youn;Choi Wang-Kyu;Chung Chong-Hun;Oh Won-zin
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.11a
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    • pp.32-37
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    • 2005
  • The characteristics of the metal melting and radionuclide distribution of the radioactive has been investigated in a lab-scale arc furnace. The slag former based on the constituents of silica, calcium oxide, aluminum oxide, borate and calcium fluoride additions was used for melting of the stainless and carbon steel. In the melting of the stainless steel, the amount of slag formation increased with an increase of the concentration of the slag former. But the effects of the slag basicity on the amount of stag formation showed a local maximum value of the slag formation with an increase of the basicity index in the melting of the stainless steel as well as in the melting of the carbon steel. With an increase of the amount of slag former addition, the trends of the cobalt distribution into the ingot and the stag depended on the kind of slag former used in the melting of the stainless steel while the effect of the slag basicity on the distribution of the cobalt was not clarified in the melting of carbon steel. Tn the melting of the carbon steel, the strontium was captured at up to $50\%$ into the slag phase. Cesium was completely eliminated from the melt of the stainless steel as well as the carbon steel and distributed to the dust phase.

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The Utility of Measuring Assimiliable Organic Carbon (AOC) as an Indicator of Biostability in Distribution Systems for Finished Water

  • Chang, Young-Cheol;Toyama, Tadashi;Jung, Kweon;Kikuchi, Shitaro
    • Journal of Environmental Health Sciences
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    • v.32 no.6
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    • pp.539-542
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    • 2006
  • The objective of this paper is to compare the applicability of assimilable organic carbon (AOC) or biodegradable dissolved organic carbon (BDOC) for quantifying biodegradable organic material (BOM) and bio-stability in distribution systems for a variety of finished waters. The study the data is derived from was part of an AWWARF and Tampa Bay Water tailored collaboration project to determine the effect of blending different waters on distribution system water quality. Seven different finished waters were produced from surface, ground, or brackish water on site and fed 18 independent pilot distribution systems (PDSs), either as single finished water or as a blend of several finished waters. AOC and BDOC have often been used as indicators of bacterial regrowth potential in distribution systems. In this study, AOC was the more useful assay of the two for the BOM concentrations observed in the PDSs. BDOC did not distinguish BOM while AOC did at the low BOM levels from many of the advanced treatments (e.g. RO, $O^3/BAC$). AOC in contrast allowed much more meaningful calculations of the consumption or production of AOC as the blends passed through the PDSs even for very low BOM blends. In addition, meaningful trends corresponding to changes in heterophic plate count (HPC) were observed for AOC but not for BDOC. Moreover, AOC stability was associated with waters produced from advanced membrane treatment.

The Preparation of PAN-based Activated Carbon Fiber by KOH (KOH 활성화에 의한 PAN계 활성탄소섬유의 제조)

  • 김기원;정승훈;임연수;정윤중
    • Journal of the Korean Ceramic Society
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    • v.36 no.6
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    • pp.577-582
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    • 1999
  • Activated carbon fibers were prepared from stabilized PAN fibers by chemical activation using hydroxide. The variations in specific surface area amount of iodine adsorption micro-structure and pore size distribution in the activated carbon fibers after the activation process were discussed. In the chemical activation using potassium hydroxide specific surface area of about 2545m2/g and amount of iodine adsorption of 2049 mg/g were obtained at the condition of KOH/fiber ratio of 1 and 800$^{\circ}C$ Nitrogen adsorption isotherms for PAN based activated carbon fibers showed the type I in the Brunauer-Deming-Deming-Teller classification indicating the micro-pores consisting the activated fibers.

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Comparison of Surface Characteristics and Adsorption Rate of Benzene Vapor According to Modifications of Activated Carbon (개질에 따른 활성탄의 표면특성과 Benzene 증기의 흡착속도 비교)

  • Lee, Song-Woo;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.17 no.8
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    • pp.919-924
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    • 2008
  • The surface properties and adsorption rates of activated carbon modified with acid and base were compared. The distribution ratio of C and C-H on the surface of activated carbon were decreased by modification with acid and base, but the distribution ratio of C-O, C=O, and O=C-O were increased. Base modification damaged the surface of activated carbon more than acid modification, it caused the effect of 6 percent increments of surface area. Adsorption rate model was more suitable to second order equation than first order equation. Adsorption rate was controlled by adsorption in pore better than in surface.

Effect of Carbon Addition and Sintering Temperature on Densification and Microstructural Evolution of Sinter-Hardening Alloys Steels

  • Verma, N.;Anand, S.;Upadhyaya, A.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.557-558
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    • 2006
  • In all conventional sintered PM products, the pores present are of two types, primary and secondary. Primary pores forming during compaction and latter during sintering, due to penetration of formed liquid through the matrix grain boundary. Effect of carbon addition on diffusion of Cu in SH737-2Cu system was investigated. After compaction and transient liquid phase sintering at $1120^{\circ}C$ and $1180^{\circ}C$, samples were characterized for densification, showing rise in sintering density and reduction in swelling on carbon addition. Quantitative microstructural characterization (shape factor and pore size) revealed bimodal distribution for 0% carbon, more rounded pores for 0.9% carbon and higher sintering temperature, and pore coarsening at higher sintering temperature.

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Mapping of Carbon Flow Distribution in the Central Metabolic Pathways of Clostridium cellulolyticum: Direct Comparison of Bacterial Metabolism with a Soluble versus an Insoluble Carbon Source

  • DESVAUX, MICKAEL,
    • Journal of Microbiology and Biotechnology
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    • v.14 no.6
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    • pp.1200-1210
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    • 2004
  • Metabolic flux analysis was established by adapting previous stoichiometric model developed during growth with cellulose to cell grown with cellobiose for further direct comparison of the bacterial metabolism. In carbon limitation with cellobiose, a shift from acetate-ethanol fermentation to ethanol-lactate fermentation is observed and the pyruvate overflow is much higher than with cellulose. In nitrogen limitation with cellobiose, the cellodextrin and exopolysaccharide overflows are much higher than on cellulose. In carbon and nitrogen saturation with cellobiose, the cellodextrin, exopolysaccharide, and free amino acids overflows reach the highest levels observed but all remain limited on cellulose. By completely shunting the cellulosome, the use of cellobiose allows to reach much higher carbon consumption rates which, in return, highlights the metabolic limitation of C. cellulolyticum. Therefore, the physical nature of the carbon source has a profound impact on the metabolism of C. cellulolyticum and most probably of other cellulolytic bacteria. For cellulolytic bacteria, the use of soluble carbon substrate must carefully be taken into consideration for the interpretation of results. Direct comparison of metabolic flux analysis from cellobiose and cellulose revealed the importance of cellulosome, phosphoglucomutase and pyruvate-ferredoxin oxidoreductase in the distribution of carbon flow in the central metabolism. In the light of these findings, future directions for improvement of cellulose catabolism by this bacterium are discussed.

Effects of Dislocation Distribution and Carbon Effective Diffusion on Strain Aging Behavior of a Low Carbon Dual Phase Steel (저탄소 Dual Phase강의 가공시효에 미치는 탄소유효확산 및 전위분포의 영향)

  • Yoo, S.H.;Jung, K.C.;Hong, K.H.;Park, KT.
    • Transactions of Materials Processing
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    • v.30 no.5
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    • pp.226-235
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    • 2021
  • The strain aging behavior of a low carbon dual phase steel was examined in two conditions: representing room temperature strain aging (100 ℃ × 1 hr after 7.5 % prestrain) and bake hardening process (170 ℃ × 20 min after 2 % prestrain), basing on carbon effective diffusion and dislocation distribution. The first principle calculations revealed that (Mn or Cr)-vacancy-C complexes exhibit the strongest attractive interaction compared to other complexes, therefore, act as strong trapping sites for carbon. For room temperature strain aging condition, the carbon effective diffusion distance is smaller than the dislocation distance in the high dislocation density region near ferrite/martensite interfaces as well as ferrite interior considering the carbon trapping effect of the (Mn or Cr)-vacancy-C complexes, implying ineffective Cottrell atmosphere formation. Under bake hardening condition, the carbon effective diffusion distance is larger compared to the dislocation distance in both regions. Therefore, formation of the Cottrell atmosphere is relatively easy resulting in to a relatively large increase in yield strength under bake hardening condition.

CO2 Emission Characteristics of Bunker C Fuel Oil by Sulfur Contents (C 중유의 황 함유량에 따른 CO2 배출 특성)

  • Lim, Wan-Gyu;Doe, Jin-Woo;Hwang, In-Ha;Ha, Jong-Han;Lee, Sang-Sup
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.4
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    • pp.368-377
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    • 2015
  • Bunker C fuel oil is a high-viscosity oil obtained from petroleum distillation as a residue. The sulfur content of bunker C fuel oil is limited to 4.0% or even lower to protect the environment. Because bunker C fuel oil is burned in a furnace or boiler for the generation of heat or used in an engine for the generation of power, carbon dioxide is emitted as a result of combustion. The objective of this study is to investigate $CO_2$ emission characteristics of bunker C fuel oil by sulfur contents. Calorific values and carbon contents of the fuels were measured using the oxygen bomb calorimeter method and the CHN elemental analysis method, respectively. Sulfur and hydrogen contents, which were used to calculate the net calorific value, were also measured and then net calorific values and $CO_2$ emission factors were determined. The results showed that hydrogen content increases and carbon content decreases by reducing sulfur contents for bunker C fuel oil with sulfur contents less than 1.0%. For sulfur contents between 1.0% and 4.0%, carbon content increases as sulfur content decreases but there is no evident variation in hydrogen content. Net calorific value increases by reducing sulfur contents. $CO_2$ emission factor, which is calculated by dividing carbon content by net calorific value, decreases as sulfur content decreases for bunker C fuel oil with sulfur contents less than 1.0% but it showed relatively constant values for sulfur contents between 1.0% and 4.0%.